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D7-N,N-Dimethylformamide
| Item number | 685131 |
| CAS | 4472-41-7 |
| Formula | C3D7NO |
| Molecular weight | 80,14 g/mol |
| Quantity | 1X100MG |
| storage conditions | 4 °C |
| CoA / MSDS | Retrieve CoA Retrieve MSDS |
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Part of Product groups:
Product Variations:
Product | Catalog No./ CAS No. | Quantity | Price | |
|---|---|---|---|---|
 | 685131 | 1X100MG | Please log in. | |
D7-N,N-Dimethylformamide solution |  | 687633 | 1X5ML | Please log in. |
 | 680119 | 1X5ML | Please log in. | |
N,N-Dimethylformamide solution |  | 688674 | 1X5ML | Please log in. |
| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 20.11.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | D7-N,N-Dimethylformamide |
| Catalog No.: | 685131 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 3), H226 Acute toxicity, Inhalation (Category 4), H332 Acute toxicity, Dermal (Category 4), H312 Eye irritation (Category 2), H319 Reproductive toxicity (Category 1B), H360D |
| Label elements | |
| Pictogram | flamme flamme GHS07 exclam exclam GHS08 silhouete silhouete |
| 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H226 Flammable liquid and vapour. H312 + H332 Harmful in contact with skin or if inhaled. H319 Causes serious eye irritation. H360D May damage the unborn child. Precautionary statement(s) P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : DMF-d7 Heptadeutero-N,N-dimethylformamide Formula : C3D7NO Molecular weight : 80,15 g/mol CAS-No. : 4472-41-7 Component Classification Concentration N,N-Dimethylformamide-d7 Flam. Liq. 3; Acute Tox. 4; Eye Irrit. 2; Repr. 1B; H226, H332, H312, H319, H360D <= 100 % |
| Formula | C3D7NO |
| Molecular Weight (g/mol) | 80.14 |
| CAS-No. | 4472-41-7 |
| FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Dry powder Dry sand Unsuitable extinguishing media Do NOT use water jet. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx) 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 6.4 Reference to other sections For disposal see section 13 |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place. Hygroscopic. Store under inert gas. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters Contains no substances with occupational exposure limit values. 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: colourless b) Odour weakly amine-like c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point Melting point: -60 °C f) Initial boiling point and boiling range 153 °C - lit. g) Flash point 58 °C - DIN 51755 Part 1 h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 16 %(V) Lower explosion limit: 2,2 %(V) k) Vapour pressure 3,77 hPa at 20 °C l) Vapour density 2,51 m) Relative density 1,03 g/mL at 25 °C n) Water solubility soluble o) Partition coefficient: n-octanol/water log Pow: -0,85 - Bioaccumulation is not expected. p) Auto-ignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Relative vapour density 2,51 |
| STABILITY AND REACTIVITY | 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials No data available 10.6 Hazardous decomposition products Other decomposition products - No data available Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx) In the event of fire: see section 5 |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - male and female - 3.010 mg/kg (OECD Test Guideline 401) Remarks: The value is given in analogy to the following substances: LC50 Inhalation - Rat - 4 h - 9 - 15 mg/l Remarks: (Lit.) The value is given in analogy to the following substances: LD50 Dermal - Rabbit - 1.500 mg/kg Remarks: (IUCLID) The value is given in analogy to the following substances: Skin corrosion/irritation Skin - Rabbit Result: No skin irritation Remarks: (IUCLID) The value is given in analogy to the following substances: Serious eye damage/eye irritation Eyes - Rabbit Result: Eye irritation Remarks: (IUCLID) The value is given in analogy to the following substances: Respiratory or skin sensitisation Sensitisation test: - Guinea pig Result: negative Remarks: (Lit.) The value is given in analogy to the following substances: Sensitisation test: - Mouse Result: negative (OECD Test Guideline 406) Remarks: The value is given in analogy to the following substances: Germ cell mutagenicity Ames test Salmonella typhimurium Result: negative (ECHA) The value is given in analogy to the following substances: Mouse - male - Bone marrow Result: negative (ECHA) The value is given in analogy to the following substances: Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity May damage the unborn child. Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Additional Information RTECS: Not available Warning: intolerance for alcohol can occur up to 4 days after dimethylformamide exposure. N,N-dimethylformamide is considered to be a potent liver toxin., Vomiting, Diarrhoea, Abdominal pain, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Liver - |
| ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish flow-through test LC50 - Lepomis macrochirus (Bluegill sunfish) - 7.100 mg/l - 96 h (US-EPA) Remarks: The value is given in analogy to the following substances: Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 13.100 mg/l - 48 h (OECD Test Guideline 202) Remarks: The value is given in analogy to the following substances: Toxicity to algae static test EC50 - Desmodesmus subspicatus (green algae) - > 1.000 mg/l - 72 h (DIN 38412) Remarks: The value is given in analogy to the following substances: Toxicity to bacteria static test EC50 - Vibrio fischeri - 12.300 - 17.500 mg/l - 5 min Remarks: (ECHA)The value is given in analogy to the following substances: 12.2 Persistence and degradability Biodegradability Result: - Readily biodegradable. aerobic - Exposure time 21 d (OECD Test Guideline 301E) Remarks: The value is given in analogy to the following substances: 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects |
| DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. Contaminated packaging Dispose of as unused product. |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 2265 IMDG: 2265 IATA: 2265 14.2 UN proper shipping name ADR/RID: N,N-DIMETHYLFORMAMIDE IMDG: N,N-DIMETHYLFORMAMIDE IATA: N,N-Dimethylformamide 14.3 Transport hazard class(es) ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available |
| REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |