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D4-2-Chlorophenol

Item number680097
CAS93951-73-6
FormulaC6HClD4O
Molecular weight132,58 g/mol
Quantity 1X25MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
D4-2-Chlorophenol

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Part of Product groups:
Product Variations:

Product

Catalog No./ CAS No.

Quantity

Price

2-Chlorophenol

2-Chlorophenol

679246
95-57-8

1X500MG

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2-Chlorophenol solution
Concentration: 10.0 µg/ml
Solvent: Methanol

10 µg/ml Methanol

2-Chlorophenol solution

681565
95-57-8

1X10ML

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2-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Methanol

2-Chlorophenol solution

681684
95-57-8

1X5ML

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3-Chlorophenol

3-Chlorophenol

684760
108-43-0

1X500MG

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3-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Methanol

3-Chlorophenol solution

689360
108-43-0

1X5ML

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4-Chlorophenol

4-Chlorophenol

673138
106-48-9

1X500MG

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4-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Methanol

100 µg/ml Methanol

4-Chlorophenol solution

675393
106-48-9

1X5ML

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D4-2-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Acetone

D4-2-Chlorophenol solution

675981
93951-73-6

1X1ML

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D4-2-Chlorophenol

D4-2-Chlorophenol

680097
93951-73-6

1X25MG

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D4-2-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Methanol

D4-2-Chlorophenol solution

684771
93951-73-6

1X1ML

On request

D4-4-Chlorophenol

D4-4-Chlorophenol

684774
285132-91-4

1X10MG

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D4-4-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

D4-4-Chlorophenol solution

684775
285132-91-4

1X1ML

On request

Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 14.11.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:D4-2-Chlorophenol
Catalog No.:680097
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Acute toxicity, Inhalation (Category 3), H331
Acute toxicity, Dermal (Category 3), H311
Skin corrosion (Sub-category 1B), H314
Serious eye damage (Category 1), H318
Long-term (chronic) aquatic hazard (Category 2), H411
Label elements
PictogramGHS05 acid
acid
GHS06 skull
skull
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
Labelling according Regulation (EC) No 1272/2008

Signal Word Danger

Hazard statement(s)
H302 Harmful if swallowed.
H311 + H331 Toxic in contact with skin or if inhaled.
H314 Causes severe skin burns and eye damage.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statement(s)
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental Hazard Statements
none

Reduced Labeling (<= 125 ml)

Signal Word Danger

Hazard statement(s)
H314 Causes severe skin burns and eye damage.
H311 + H331 Toxic in contact with skin or if inhaled.

Precautionary statement(s)
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental Hazard Statements
none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances

Formula : C6HD4ClO
Molecular weight : 132,54 g/mol
CAS-No. : 93951-73-6
Classification : Acute Tox. 4; Acute Tox. 3; Skin Corr. 1B; Eye Dam. 1; Aquatic Chronic 2; H302, H331, H311, H314, H318, H411
FormulaC6HClD4O
Molecular Weight (g/mol)132.58
CAS-No.93951-73-6
FIRST AID MEASURES4.1 Description of first-aid measures

General advice
Consult a physician. Show this material safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
Do NOT use water jet.

5.2 Special hazards arising from the substance or mixture

Carbon oxides
Hydrogen chloride gas
Combustible.

5.3 Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

5.4 Further information

Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures

Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.
For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling

Advice on safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapor or mist.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge.
Hygiene measures
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.
For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.

Storage class
Storage class (TRGS 510): 6.1C: Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Ingredients with workplace control parameters

8.2 Exposure controls
Personal protective equipment
Eye/face protection
Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching outer surface of glove) to avoid skin contact
with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387)
respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Physical state liquid, clear
b) Color light yellow
c) Odor No data available
d) Melting point/freezing point
Melting point: 8,0 °C
e) Initial boiling point and boiling range
62,0 - 63,0 °C at 14,7 hPa
f) Flammability (solid, gas)
No data available
g) Upper/lower flammability or explosive limits
No data available
h) Flash point 64 °C - closed cup
i) Autoignition temperature
No data available
j) Decomposition temperature
No data available
k) pH No data available
l) Viscosity Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
m) Water solubility No data available
n) Partition coefficient: n-octanol/water
log Pow: 5,0 - Potential bioaccumulation
o) Vapor pressure 1,3 hPa at 121,0 °C
p) Density 1,26 g/cm3
Relative density No data available
q) Relative vapor density
No data available
r) Particle characteristics
No data available
s) Explosive properties No data available
t) Oxidizing properties none

9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available

10.2 Chemical stability
Avoid moisture.
Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions
No data available

10.4 Conditions to avoid
Heat, flames and sparks.

10.5 Incompatible materials
Acid chlorides, Acid anhydrides, Oxidizing agents

10.6 Hazardous decomposition products
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male and female - 2.000 mg/kg
(OECD Test Guideline 401)
LC50 Inhalation - Rat - male and female - 4 h - >= 4,77 mg/l - vapor
(OECD Test Guideline 403)
LD50 Dermal - Rat - male and female - 1.000 - 1.580 mg/kg
Remarks: (ECHA)
Skin corrosion/irritation
Skin - Rabbit
Result: Causes burns.
Remarks: (ECHA)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Causes serious eye damage.
Remarks: (ECHA)
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Remarks: (IUCLID)
Test Type: Mutagenicity (mammal cell test): micronucleus.
Test system: Chinese hamster lung cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 473
Result: negative
Carcinogenicity
No data available
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available

11.2 Additional Information
Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Lepomis macrochirus (Bluegill) - 5,7 - 12 mg/l - 96,0 h
Remarks: (ECOTOX Database)
Toxicity to daphnia and other aquatic invertebrates
EC50 - Daphnia magna (Water flea) - 3,91 mg/l - 48 h
Remarks: (ECOTOX Database)
Toxicity to algae EC50 - Pseudokirchneriella subcapitata (green algae) - 70,00 mg/l - 96 h
Remarks: (ECOTOX Database)
EC50 - Pseudokirchneriella subcapitata (green algae) - 70,00 mg/l - 96 h
Remarks: (ECOTOX Database)
Toxicity to bacteria microtox test EC50 - Photobacterium phosphoreum - 6,8 mg/l - 1 h
Remarks: (IUCLID)
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)
NOEC - Daphnia magna (Water flea) - 1 mg/l - 2 d
Remarks: (ECOTOX Database)

12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 14 d
Result: 0 % - Not readily biodegradable.
(OECD Test Guideline 301C)

12.3 Bioaccumulative potential
Bioaccumulation Lepomis macrochirus (Bluegill) - 28 d
- 0,00918 mg/l(2-Chlorophenol-3,4,5,6-d4)
Bioconcentration factor (BCF): 214

12.4 Mobility in soil
No data available

12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties
according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

12.7 Other adverse effects
Toxic to aquatic life with long lasting effects.
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 2021 IMDG: 2021 IATA: 2021

14.2 UN proper shipping name
ADR/RID: CHLOROPHENOLS, LIQUID
IMDG: CHLOROPHENOLS, LIQUID
IATA: Chlorophenols, liquid

14.3 Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1

14.4 Packaging group
ADR/RID: III IMDG: III IATA: III

14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no

14.6 Special precautions for user
Tunnel restriction code : (E)
Further information : No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
National legislation
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances.
: ACUTE TOXIC
: ENVIRONMENTAL HAZARDS

15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!