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Item number | 680097 |
CAS | 93951-73-6 |
Formula | C6HClD4O |
Molecular weight | 132,58 g/mol |
Quantity | 1X25MG |
storage conditions | 20 °C |
CoA / MSDS | Retrieve CoA Retrieve MSDS |
Product | Catalog No./ CAS No. | Quantity | Price | |
---|---|---|---|---|
679246 | 1X500MG | Please log in. | ||
2-Chlorophenol solution 10 µg/ml Methanol | 681565 | 1X10ML | Please log in. | |
2-Chlorophenol solution | 681684 | 1X5ML | Please log in. | |
684760 | 1X500MG | Please log in. | ||
3-Chlorophenol solution | 689360 | 1X5ML | Please log in. | |
673138 | 1X500MG | Please log in. | ||
4-Chlorophenol solution 100 µg/ml Methanol | 675393 | 1X5ML | Please log in. | |
D4-2-Chlorophenol solution | 675981 | 1X1ML | Please log in. | |
680097 | 1X25MG | Please log in. | ||
D4-2-Chlorophenol solution | 684771 | 1X1ML | ||
684774 | 1X10MG | Please log in. | ||
D4-4-Chlorophenol solution | 684775 | 1X1ML |
Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 23.11.2024 |
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
Product name: | D4-2-Chlorophenol |
Catalog No.: | 680097 |
Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 3), H331 Acute toxicity, Dermal (Category 3), H311 Skin corrosion (Sub-category 1B), H314 Serious eye damage (Category 1), H318 Long-term (chronic) aquatic hazard (Category 2), H411 |
Label elements | |
Pictogram | GHS05 acid acid GHS06 skull skull GHS09 Aquatic-pollut-red Aquatic-pollut-red |
Labelling according Regulation (EC) No 1272/2008 Signal Word Danger Hazard statement(s) H302 Harmful if swallowed. H311 + H331 Toxic in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H411 Toxic to aquatic life with long lasting effects. Precautionary statement(s) P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplemental Hazard Statements none Reduced Labeling (<= 125 ml) Signal Word Danger Hazard statement(s) H314 Causes severe skin burns and eye damage. H311 + H331 Toxic in contact with skin or if inhaled. Precautionary statement(s) P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. | |
COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Formula : C6HD4ClO Molecular weight : 132,54 g/mol CAS-No. : 93951-73-6 Classification : Acute Tox. 4; Acute Tox. 3; Skin Corr. 1B; Eye Dam. 1; Aquatic Chronic 2; H302, H331, H311, H314, H318, H411 |
Formula | C6HClD4O |
Molecular Weight (g/mol) | 132.58 |
CAS-No. | 93951-73-6 |
FIRST AID MEASURES | 4.1 Description of first-aid measures General advice Consult a physician. Show this material safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media Do NOT use water jet. 5.2 Special hazards arising from the substance or mixture Carbon oxides Hydrogen chloride gas Combustible. 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers. |
ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13. |
HANDLING AND STORAGE | 7.1 Precautions for safe handling Advice on safe handling Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Advice on protection against fire and explosion Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Storage conditions Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place. Storage class Storage class (TRGS 510): 6.1C: Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching outer surface of glove) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. |
PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Physical state liquid, clear b) Color light yellow c) Odor No data available d) Melting point/freezing point Melting point: 8,0 °C e) Initial boiling point and boiling range 62,0 - 63,0 °C at 14,7 hPa f) Flammability (solid, gas) No data available g) Upper/lower flammability or explosive limits No data available h) Flash point 64 °C - closed cup i) Autoignition temperature No data available j) Decomposition temperature No data available k) pH No data available l) Viscosity Viscosity, kinematic: No data available Viscosity, dynamic: No data available m) Water solubility No data available n) Partition coefficient: n-octanol/water log Pow: 5,0 - Potential bioaccumulation o) Vapor pressure 1,3 hPa at 121,0 °C p) Density 1,26 g/cm3 Relative density No data available q) Relative vapor density No data available r) Particle characteristics No data available s) Explosive properties No data available t) Oxidizing properties none 9.2 Other safety information No data available |
STABILITY AND REACTIVITY | 10.1 Reactivity No data available 10.2 Chemical stability Avoid moisture. Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Acid chlorides, Acid anhydrides, Oxidizing agents 10.6 Hazardous decomposition products In the event of fire: see section 5 |
TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - male and female - 2.000 mg/kg (OECD Test Guideline 401) LC50 Inhalation - Rat - male and female - 4 h - >= 4,77 mg/l - vapor (OECD Test Guideline 403) LD50 Dermal - Rat - male and female - 1.000 - 1.580 mg/kg Remarks: (ECHA) Skin corrosion/irritation Skin - Rabbit Result: Causes burns. Remarks: (ECHA) Serious eye damage/eye irritation Eyes - Rabbit Result: Causes serious eye damage. Remarks: (ECHA) Respiratory or skin sensitization No data available Germ cell mutagenicity Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Remarks: (IUCLID) Test Type: Mutagenicity (mammal cell test): micronucleus. Test system: Chinese hamster lung cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: negative Carcinogenicity No data available Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available 11.2 Additional Information Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Lepomis macrochirus (Bluegill) - 5,7 - 12 mg/l - 96,0 h Remarks: (ECOTOX Database) Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 3,91 mg/l - 48 h Remarks: (ECOTOX Database) Toxicity to algae EC50 - Pseudokirchneriella subcapitata (green algae) - 70,00 mg/l - 96 h Remarks: (ECOTOX Database) EC50 - Pseudokirchneriella subcapitata (green algae) - 70,00 mg/l - 96 h Remarks: (ECOTOX Database) Toxicity to bacteria microtox test EC50 - Photobacterium phosphoreum - 6,8 mg/l - 1 h Remarks: (IUCLID) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) NOEC - Daphnia magna (Water flea) - 1 mg/l - 2 d Remarks: (ECOTOX Database) 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 14 d Result: 0 % - Not readily biodegradable. (OECD Test Guideline 301C) 12.3 Bioaccumulative potential Bioaccumulation Lepomis macrochirus (Bluegill) - 28 d - 0,00918 mg/l(2-Chlorophenol-3,4,5,6-d4) Bioconcentration factor (BCF): 214 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. 12.7 Other adverse effects Toxic to aquatic life with long lasting effects. |
DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. Contaminated packaging Dispose of as unused product. |
TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 2021 IMDG: 2021 IATA: 2021 14.2 UN proper shipping name ADR/RID: CHLOROPHENOLS, LIQUID IMDG: CHLOROPHENOLS, LIQUID IATA: Chlorophenols, liquid 14.3 Transport hazard class(es) ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user Tunnel restriction code : (E) Further information : No data available |
REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. National legislation Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ACUTE TOXIC : ENVIRONMENTAL HAZARDS 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |