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2-Chloroaniline

Item number675774
CAS95-51-2
FormulaC6H6ClN
Molecular weight127,57 g/mol
Quantity 1X500MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
2-Chloroaniline

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Product

Catalog No./ CAS No.

Quantity

Price

2-Chloroaniline

2-Chloroaniline

675774
95-51-2

1X500MG

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2-Chloroaniline solution
Concentration: 100 µg/ml
Solvent: Methanol

2-Chloroaniline solution

680101
95-51-2

1X5ML

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3-Chloroaniline

3-Chloroaniline

692363
108-42-9

1X500MG

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4-Chloroaniline

4-Chloroaniline

673999
106-47-8

1X1000MG

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4-Chloroaniline solution
Concentration: 100 µg/ml
Solvent: Methanol

4-Chloroaniline solution

674000
106-47-8

1X5ML

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4-Chloroaniline solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

4-Chloroaniline solution

679882
106-47-8

1X5ML

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D2-2-Chloroaniline

D2-2-Chloroaniline

679503
347840-10-2

1X10MG

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D3-3-Chloroaniline

D3-3-Chloroaniline

679504
347840-11-3

1X10MG

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D4-4-Chloroaniline

D4-4-Chloroaniline

679505
191656-33-4

1X10MG

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D4-4-Chloroaniline solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

D4-4-Chloroaniline solution

688999
191656-33-4

1X5ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 23.11.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:2-Chloroaniline
Catalog No.:675774
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 3), H331
Acute toxicity, Dermal (Category 3), H311
Eye irritation (Category 2A), H319
Specific target organ toxicity - repeated exposure (Category 2), H373
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
Label elements
PictogramGHS06 skull
skull
GHS07 exclam
exclam
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
Signal word Danger
Hazard statement(s)
H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled
H319 Causes serious eye irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves/ protective clothing.
P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician. Rinse mouth.
P302 + P352 + P312 IF ON SKIN: Wash with plenty of soap and water. Call a POISON
CENTER or doctor/ physician if you feel unwell.
P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P391 Collect spillage.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C6H6ClN
Molecular weight : 127.57 g/mol
CAS-No. : 95-51-2
EC-No. : 202-426-4
Index-No. : 612-010-00-8
Component
2-Chloroaniline
Classification
Acute Tox. 3; Eye Irrit. 2A;
STOT RE 2; Aquatic Acute 1;
Aquatic Chronic 1; H301 +
H311 + H331, H319, H373,
H410
Concentration
<= 100 %
FormulaC6H6ClN
Molecular Weight (g/mol)127.57
CAS-No.95-51-2
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Move out of dangerous area.Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx), Hydrogen chloride gas
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate
personnel to safe areas.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching gloves outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: clear, liquid
Colour: light yellow
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/range: 0 - 3 °C (32 - 37 °F)
f) Initial boiling point and
boiling range
208 - 210 °C (406 - 410 °F)
g) Flash point 98 °C (208 °F) - closed cup - DIN 51758
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
Upper explosion limit: 14.2 %(V)
Lower explosion limit: 2.4 %(V)
k) Vapour pressure 0.13 hPa (0.10 mmHg) at 20 °C (68 °F)
0.36 hPa (0.27 mmHg) at 30 °C (86 °F)
1.7 hPa (1.3 mmHg) at 50 °C (122 °F)
l) Vapour density 4.4 - (Air = 1.0)
m) Relative density 1.213 g/mL at 25 °C (77 °F)
n) Water solubility ca.5.13 g/l at 20 °C (68 °F)
o) Partition coefficient: noctanol/
water
log Pow: 1.9
p) Auto-ignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
Relative vapour density 4.4 - (Air = 1.0)
STABILITY AND REACTIVITY10.1 Reactivity
no data available
10.2 Chemical stability
no data available
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
acids, Acid chlorides, Acid anhydrides, Chloroformates, Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - no data available
TOXICOLOGICAL INFORMATION11.1 Angaben zu toxikologischen Wirkungen
Akute Toxizität
LD50 Oral - Maus - 256 mg/kg
LC50 Einatmen - Ratte - 4 h - 4,1 mg/l
Ätz-/Reizwirkung auf die Haut
Haut - Kaninchen
Ergebnis: Keine Hautreizung
(Richtlinie 67/548/EWG, Anhang V, B.4.)
Schwere Augenschädigung/-reizung
Augen - Kaninchen
Ergebnis: Reizt die Augen. - 4 h
(Richtlinie 67/548/EWG, Anhang V, B.5.)
Sensibilisierung der Atemwege/Haut
Maximierungstest (GPMT) - Meerschweinchen
Verursacht keine Sensibilisierung bei Labortieren.
(Richtlinie 67/548/EWG, Anhang V, B.6.)
Keimzell-Mutagenität
Maus
Lymphozyten
Hamster
Lungen
Mutation in somatischen Zellen von Säugetieren
Karzinogenität
IARC: Kein Bestandteil dieses Produkts, der in einer Konzentration von gleich oder mehr als 0.1%
vorhanden ist, wird durch das IARC als voraussichtliches, mögliches oder erwiesenes
krebserzeugendes Produkt für den Menschen identifiziert.
Reproduktionstoxizität
Keine Daten verfügbar
Spezifische Zielorgan-Toxizität - einmalige Exposition
Keine Daten verfügbar
Spezifische Zielorgan-Toxizität - wiederholte Exposition
Kann die Organe schädigen bei längerer oder wiederholter Exposition.
Aspirationsgefahr
Keine Daten verfügbar
Zusätzliche Informationen
RTECS: Keine Daten verfügbar
Körperresorption führt zur Bildung von Methämoglobin, das in erhöhter Konzentration Cyanose hervorruft.
Die Latenzzeit kann 2 bis 4 Stunden oder länger betragen., Leberschäden sind möglich., Nierenschäden
sind möglich.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 5,7 mg/l - 96 h
Toxicity to daphnia and
other aquatic
invertebrates
EC50 - Daphnia magna (Water flea) - 1,8 mg/l - 48 h
Toxicity to algae EC50 - Desmodesmus subspicatus (green algae) - 150 mg/l - 72 h
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 19 d
Result: 16 % - Not readily biodegradable.
12.3 Bioaccumulative potential
Bioaccumulation Danio rerio (zebra fish) - 96 h -25,5 μg/l
Bioconcentration factor (BCF): 15,3
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
no data available
12.6 Other adverse effects
Very toxic to aquatic life.
DISPOSAL CONSIDERATIONS13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a
chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 2019 IMDG: 2019 IATA: 2019
14.2 UN proper shipping name
ADR/RID: CHLOROANILINES, LIQUID
IMDG: CHLOROANILINES, LIQUID
IATA: Chloroanilines, liquid
14.3 Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: yes IMDG Marine Pollutant: yes IATA: no
14.6 Special precautions for user
no data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
15.2 Chemical Safety Assessment
no data available
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!