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Item number | 689967 |
CAS | 3342-67-4 |
Formula | C15H33ClSn |
Molecular weight | 367,59 g/mol |
Quantity | 1X25MG |
storage conditions | 20 °C |
CoA / MSDS | Retrieve CoA Retrieve MSDS |
Product | Catalog No./ CAS No. | Quantity | Price | |
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689967 | 1X25MG | Please log in. |
Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 22.12.2024 |
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
Product name: | Tri-n-pentyltin chloride |
Catalog No.: | 689967 |
Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
HAZARDS IDENTIFICATION | Acute toxicity (oral), Category 3 H301 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects No additional information available |
Label elements | |
Pictogram | GHS06 skull skull |
Signal word (CLP): Danger Hazard statements (CLP): H301 - Toxic if swallowed. H315 - Causes skin irritation. H319 - Causes serious eye irritation. Precautionary statements (CLP): P280 - Wear protective gloves/protective clothing/eye protection/face protection. P264 - Wash hands thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P301+P310 - IF SWALLOWED: Immediately call a doctor. P302+P352 - IF ON SKIN: Wash with plenty of water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 2.3. Other hazards No additional information available | |
COMPOSITION/INFORMATION ON INGREDIENTS | Substance type: Multi-constituent Name: TRI-n-PENTYLCHLOROTIN, tech-95 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Tripentyltin chloride (CAS-No.) 3342-67-4 90 - 100 Acute Tox. 3 (Oral), H301 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Other Organotins 0 - 10 Not classified |
Formula | C15H33ClSn |
Molecular Weight (g/mol) | 367.59 |
CAS-No. | 3342-67-4 |
FIRST AID MEASURES | 4.1. Description of first aid measures First-aid measures general: Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label. First-aid measures after inhalation: Remove person to fresh air and keep comfortable for breathing. If you feel unwell, seek medical advice. First-aid measures after skin contact: Wash with plenty of water/…. Get medical advice/attention. First-aid measures after eye contact: Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. First-aid measures after ingestion: Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation: May cause irritation to the respiratory tract. Overexposure may cause: Cough. Headache. Nausea. Symptoms/effects after skin contact: Causes skin irritation. Organotins may be absorbed through the skin. Symptoms/effects after eye contact: Causes serious eye irritation. Symptoms/effects after ingestion: Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. 4.3. Indication of any immediate medical attention and special treatment needed Note to physician: Application of corticosteroid creams has been effective in treating severe skin irritation. If blisters develop, they may require abrasion to promote healing. |
FIRE-FIGHTING MEASURES | 5.1. Extinguishing media Suitable extinguishing media: Water spray. Foam. Carbon dioxide. Dry chemical. Unsuitable extinguishing media: None known. 5.2. Special hazards arising from the substance or mixture Fire hazard: Irritating fumes and organic acid vapors may develop when material is exposed to elevated temperatures or open flame. 5.3. Advice for firefighters Firefighting instructions: Use water spray to cool exposed surfaces. Exercise caution when fighting any chemical fire. |
ACCIDENTAL RELEASE MEASURES | 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment: Wear protective equipment as described in Section 8. Emergency procedures: Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment: Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up: Clean up any spills as soon as possible, using an absorbent material to collect it. Sweep or shovel spills into appropriate container for disposal. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. |
HANDLING AND STORAGE | 7.1. Precautions for safe handling Precautions for safe handling: Avoid all eye and skin contact and do not breathe vapour and mist. Use only in well ventilated areas. Hygiene measures: Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Keep container tightly closed. Keep out of reach of children. Incompatible materials: Bases. Direct sunlight. Reducing agents. Moisture. Water : Storage area: Store in a well-ventilated place. Store away from heat. 7.3. Specific end use(s) No additional information available |
EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1. Control parameters Other Organotins Italy - Portugal - USA ACGIH ACGIH TWA (mg/m³) 0.1 mg/m³ as tin USA OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³ as tin Tripentyltin chloride (3342-67-4) Italy - Portugal - USA ACGIH ACGIH TWA (mg/m³) 0.1 mg/m³ as tin USA OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³ as tin 8.2. Exposure controls Appropriate engineering controls: Provide local exhaust or general room ventilation. Personal protective equipment: Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Hand protection: Neoprene or nitrile rubber gloves Eye protection: Chemical goggles. Contact lenses should not be worn Skin and body protection: Wear suitable protective clothing Respiratory protection: Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. NIOSH-certified combination organic vapor/acid gas (yellow cartridge) respirator. |
PHYSICAL AND CHEMICAL PROPERTIES | 9.1. Information on basic physical and chemical properties Physical state: Liquid Appearance: Colorless liquid. Molecular mass: 367.57 g/mol Colour: Pale yellow. Odour: characteristic. Odour threshold: No data available Refractive index: 1.486 pH: No data available Relative evaporation rate (butylacetate=1): No data available Melting point: No data available Freezing point: < 0 °C Boiling point: 120 °C @ 0.25 mm Hg Flash point: > 120 °C (TCC) Auto-ignition temperature: No data available Decomposition temperature: No data available Flammability (solid, gas): No data available Vapour pressure: 25 mm Hg @ 170°C Relative vapour density at 20 °C: No data available Relative density: 1.137 Solubility: Insoluble in water. Log Pow: No data available Log Kow: No data available Viscosity, kinematic: 4 cSt Viscosity, dynamic: No data available Explosive properties: No data available Oxidising properties: No data available Explosive limits: No data available 9.2. Other information No additional information available |
STABILITY AND REACTIVITY | 10.1. Reactivity No additional information available 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Direct sunlight causes slow degradation to an inorganic tin salt. 10.4. Conditions to avoid Heat. Open flame. Sparks. 10.5. Incompatible materials Bases. Direct sunlight. Reducing agents. Moisture. Water : 10.6. Hazardous decomposition products Organic acid vapors. Tin oxides. |
TOXICOLOGICAL INFORMATION | 11.1. Information on toxicological effects Acute toxicity: Toxic if swallowed. Tripentyltin chloride (3342-67-4) LD50 oral rat > 150 mg/kg ATE CLP (oral) 100 mg/kg bodyweight Skin corrosion/irritation: Causes skin irritation. Serious eye damage/irritation: Causes serious eye irritation. Respiratory or skin sensitisation: Not classified Germ cell mutagenicity: Not classified Carcinogenicity: Not classified Reproductive toxicity: Not classified STOT-single exposure: Not classified STOT-repeated exposure: Not classified Aspiration hazard: Not classified Symptoms/effects after inhalation: May cause irritation to the respiratory tract. Overexposure may cause: Cough. Headache. Nausea. Symptoms/effects after skin contact: Causes skin irritation. Organotins may be absorbed through the skin. Symptoms/effects after eye contact: Causes serious eye irritation. Symptoms/effects after ingestion: Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. Reason for classification: Expert judgment |
ECOLOGICAL INFORMATION | 12.1. Toxicity Ecology - general: This material is acutely toxic to aquatic life if released to open waters. This material is toxic to wildlife and fish. Acute aquatic toxicity: Not classified Chronic aquatic toxicity: Not classified 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential No additional information available 12.4. Mobility in soil No additional information available 12.5. Results of PBT and vPvB assessment No additional information available 12.6. Other adverse effects No additional information available |
DISPOSAL CONSIDERATIONS | 13.1. Waste treatment methods Product/Packaging disposal recommendations: Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to licensed waste disposal facility. Ecology - waste materials: Avoid release to the environment. |
TRANSPORT INFORMATION | 14.1. UN number In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No. (ADR): 2788 UN-No. (IMDG): 2788 UN-No. (IATA): 2788 UN-No. (ADN): 2788 UN-No. (RID): 2788 14.2. UN proper shipping name Proper Shipping Name (ADR): ORGANOTIN COMPOUND, LIQUID, N.O.S. Proper Shipping Name (IMDG): ORGANOTIN COMPOUND, LIQUID, N.O.S. Proper Shipping Name (IATA): Organotin compound, liquid, n.o.s. Proper Shipping Name (ADN): ORGANOTIN COMPOUND, LIQUID, N.O.S. Proper Shipping Name (RID): ORGANOTIN COMPOUND, LIQUID, N.O.S. Transport document description (ADR): UN 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. (TRI-n-PENTYLCHLOROTIN), 6.1, II, (D/E) Transport document description (IMDG): UN 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. (TRI-n-PENTYLCHLOROTIN), 6.1, II, MARINE POLLUTANT Transport document description (IATA): UN 2788 Organotin compound, liquid, n.o.s. (TRI-n-PENTYLCHLOROTIN), 6.1, II Transport document description (ADN): UN 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. (TRI-n-PENTYLCHLOROTIN), 6.1, II Transport document description (RID): UN 2788 ORGANOTIN COMPOUND, LIQUID, N.O.S. (TRI-n-PENTYLCHLOROTIN), 6.1, II 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR): 6.1 Danger labels (ADR): 6.1 IMDG Transport hazard class(es) (IMDG): 6.1 Danger labels (IMDG): 6.1IATA Transport hazard class(es) (IATA): 6.1 Hazard labels (IATA): 6.1 ADN Transport hazard class(es) (ADN): 6.1 Danger labels (ADN): 6.1 RID Transport hazard class(es) (RID): 6.1 Danger labels (RID): 6.1 14.4. Packing group Packing group (ADR): II Packing group (IMDG): II Packing group (IATA): II Packing group (ADN): II Packing group (RID): II 14.5. Environmental hazards Dangerous for the environment: No Marine pollutant: Yes (IMDG only) Other information: No supplementary information available 14.6. Special precautions for user - Overland transport Classification code (ADR): T3 Special provisions (ADR): 43, 274 Limited quantities (ADR): 100ml Excepted quantities (ADR): E4 Packing instructions (ADR): P001, IBC02 Mixed packing provisions (ADR): MP15 Portable tank and bulk container instructions (ADR): T11 Portable tank and bulk container special provisions (ADR): TP2, TP27 Tank code (ADR): L4BH Tank special provisions (ADR): TU15, TE19 Vehicle for tank carriage: AT Transport category (ADR): 2 Special provisions for carriage - Loading, unloading and handling (ADR): CV13, CV28 Special provisions for carriage - Operation (ADR): S9, S19 Hazard identification number (Kemler No.): 60 Tunnel restriction code (ADR): D/E EAC code: 2X APP code: B - Transport by sea Special provisions (IMDG): 43, 274 Limited quantities (IMDG): 100 ml Excepted quantities (IMDG): E4 Packing instructions (IMDG): P001 IBC packing instructions (IMDG): IBC02 Tank instructions (IMDG): T11 Tank special provisions (IMDG): TP2, TP13, TP27 EmS-No. (Fire): F-A EmS-No. (Spillage): S-A Stowage category (IMDG): A Stowage and handling (IMDG): SW2 Properties and observations (IMDG): A wide variety of toxic liquids. Toxic if swallowed, by skin contact or by inhalation. - Air transport PCA Excepted quantities (IATA): E4 PCA Limited quantities (IATA): Y641 PCA limited quantity max net quantity (IATA): 1L PCA packing instructions (IATA): 654 PCA max net quantity (IATA): 5L CAO packing instructions (IATA): 661 CAO max net quantity (IATA): 60L Special provisions (IATA): A3, A4, A6 ERG code (IATA): 6L - Inland waterway transport Classification code (ADN): T3 Special provisions (ADN): 43, 274, 802 Limited quantities (ADN): 100 ml Excepted quantities (ADN): E4 Equipment required (ADN): PP, EP, TOX, A Ventilation (ADN): VE02 Number of blue cones/lights (ADN): 2 - Rail transport Classification code (RID): T3 Special provisions (RID): 43, 274 Limited quantities (RID): 100ml Excepted quantities (RID): E4 Packing instructions (RID): P001, IBC02 Mixed packing provisions (RID): MP15 Portable tank and bulk container instructions (RID): T11 Portable tank and bulk container special provisions (RID): TP2, TP27 Tank codes for RID tanks (RID): L4BH Special provisions for RID tanks (RID): TU15 Transport category (RID): 2 Special provisions for carriage - Loading, unloading and handling (RID): CW13, CW28, CW31 Colis express (express parcels) (RID): CE5 Hazard identification number (RID): 60 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable |
REGULATORY INFORMATION | 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations No REACH Annex XVII restrictions TRI-n-PENTYLCHLOROTIN, tech-95 is not on the REACH Candidate List TRI-n-PENTYLCHLOROTIN, tech-95 is not on the REACH Annex XIV List TRI-n-PENTYLCHLOROTIN, tech-95 is not subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July 2012 concerning the export and import of hazardous chemicals. TRI-n-PENTYLCHLOROTIN, tech-95 is not subject to Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistent organic pollutants and amending Directive 79/117/EEC 15.1.2. National regulations Germany 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands SZW-lijst van kankerverwekkende stoffen: The substance is not listed SZW-lijst van mutagene stoffen: The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Borstvoeding: The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Vruchtbaarheid: The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Ontwikkeling: The substance is not listed Denmark Danish National Regulations: Young people below the age of 18 years are not allowed to use the product 15.2. Chemical safety assessment No additional information available |
OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |