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1,2,5,6,9,10-Hexabromocyclododecane

Item number676923
CAS3194-55-6
FormulaC12H18Br6
Molecular weight641,70 g/mol
Quantity 1X250MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
1,2,5,6,9,10-Hexabromocyclododecane

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1,2,5,6,9,10-Hexabromocyclododecane

1,2,5,6,9,10-Hexabromocyclododecane

676923
3194-55-6

1X250MG

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1,2,5,6,9,10-Hexabromocyclododecane solution
Concentration: 100 µg/ml
Solvent: Methanol

1,2,5,6,9,10-Hexabromocyclododecane solution

679834
3194-55-6

1X5ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 15.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:1,2,5,6,9,10-Hexabromocyclododecane
Catalog No.:676923
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Reproductive toxicity (Category 2), H361
Effects on or via lactation, H362
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
Label elements
PictogramGHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Warning
Hazard statement(s)
H361 Suspected of damaging fertility or the unborn child.
H362 May cause harm to breast-fed children H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P260 Do not breathe dust or mist.
P263 Avoid contact during pregnancy/ while nursing.
P273 Avoid release to the environment.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P391 Collect spillage.
Supplemental Hazard
Statements
none
2.3 Other hazards
PBT substance
This substance/mixture contains components considered to be either persistent, bioaccumulative and toxic
(PBT), or very persistent and very bioaccumulative (vPvB).
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C12H18Br6
Molecular weight : 641,73 g/mol
CAS-No. : 3194-55-6
EC-No. : 221-695-9
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
1,2,5,6,9,10-Hexabromocyclododecane Included in the Candidate List of Substances of Very High
Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH)
CAS-No.
EC-No.
3194-55-6
221-695-9
Repr. 2; Lact. ; Aquatic Acute
1; Aquatic Chronic 1; H361,
H362, H400, H410
M-Factor - Aquatic Acute: 100
<= 100 %
FormulaC12H18Br6
Molecular Weight (g/mol)641.70
CAS-No.3194-55-6
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen bromide gas
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.Avoid exposure - obtain special
instructions before use.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Storage class (TRGS 510): Non Combustible Solids
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. Body Protection
Impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: powder
Colour: beige
b) Odour odourless
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/range: 188 °C
f) Initial boiling point and
boiling range
> 190 °C
g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure No data available
l) Vapour density No data available
m) Relative density No data available
n) Water solubility slightly soluble
o) Partition coefficient: noctanol/
water
log Pow: 5,62
p) Auto-ignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - > 20.000 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
Germ cell mutagenicity
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 0,003 mg/l - 96 h
(OECD Test Guideline 203)
Toxicity to daphnia and
other aquatic
invertebrates
EC50 - Daphnia (water flea) - > 3,2 mg/l - 48 h
Toxicity to algae EC50 - Algae - 0,009 mg/l - 72 h
12.2 Persistence and degradability
Biodegradability Result: - Not readily biodegradable.
(OECD Test Guideline 301)
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT substance
This substance/mixture contains components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB).
12.6 Other adverse effects
Very toxic to aquatic life with long lasting effects
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 3077 IMDG: 3077 IATA: 3077
14.2 UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1,2,5,6,9,10-
Hexabromocyclododecane)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1,2,5,6,9,10-
Hexabromocyclododecane)
IATA: Environmentally hazardous substance, solid, n.o.s. (1,2,5,6,9,10-Hexabromocyclododecane)
14.3 Transport hazard class(es)
ADR/RID: 9 IMDG: 9 IATA: 9
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes
14.6 Special precautions for user
Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination
packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 453/2010.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Authorisations and/or restrictions on use
1,2,5,6,9,10-
Hexabromocyclododecane
CAS-No.: 3194-55-6
REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).
Persistent, bioaccumulative and toxic (article 57d)
ED/67/2008
1,2,5,6,9,10-
Hexabromocyclododecane
CAS-No.: 3194-55-6
REACH - List of substances subject to authorisation (Annex XIV)
PBT
Sunset Date: 21.08.2015
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!