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Item number | 678371 |
CAS | 106-89-8 |
Formula | C3H5ClO |
Molecular weight | 92,52 g/mol |
Quantity | 1X1ML |
storage conditions | 20 °C |
CoA / MSDS | Retrieve CoA Retrieve MSDS |
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684303 | 1X25MG | Please log in. | ||
D5-Epichlorohydrin solution | 691231 | 1X1ML | Please log in. | |
678371 | 1X1ML | Please log in. | ||
Epichlorohydrin solution | 679903 | 1X1ML | Please log in. |
Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 15.01.2025 |
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
Product name: | Epichlorohydrin |
Catalog No.: | 678371 |
Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 3), H226 Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 3), H331 Acute toxicity, Dermal (Category 3), H311 Skin corrosion (Category 1B), H314 Skin sensitisation (Category 1), H317 Carcinogenicity (Category 1B), H350 Classification according to EU Directives 67/548/EEC or 1999/45/EC R10 R45 T Toxic R23/24/25 C Corrosive R34 R43 |
Label elements | |
Pictogram | flamme flamme GHS05 acid acid GHS06 skull skull GHS08 silhouete silhouete |
2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H226 Flammable liquid and vapour. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H350 May cause cancer. Precautionary statement(s) P201 Obtain special instructions before use. P261 Avoid breathing vapours. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/ physician. Supplemental Hazard Statements none Restricted to professional users. 2.3 Other hazards Rapidly absorbed through skin | |
COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : 1-Chloro-2,3-epoxypropane (±)-2-(Chloromethyl)oxirane Formula : C3H5ClO Molecular Weight : 92,52 g/mol CAS-No. : 106-89-8 EC-No. : 203-439-8 Index-No. : 603-026-00-6 Registration number : 01-2119457436-33-XXXX Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration Epichlorhydrin CAS-No. EC-No. Index-No. Registration number 106-89-8 203-439-8 603-026-00-6 01-2119457436-33-XXXX Flam. Liq. 3; Acute Tox. 3; Skin Corr. 1B; Skin Sens. 1; Carc. 1B; H226, H301 + H311 + H331, H314, H317, H350 <= 100 % Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration Epichlorhydrin CAS-No. EC-No. Index-No. Registration number 106-89-8 203-439-8 603-026-00-6 01-2119457436-33-XXXX T, Carc.Cat.2, R45 - R10 - R23/24/25 - R34 - R43 <= 100 % |
Formula | C3H5ClO |
Molecular Weight (g/mol) | 92.52 |
CAS-No. | 106-89-8 |
FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed no data available |
FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Hydrogen chloride gas 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 Further information Use water spray to cool unopened containers |
ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13. |
HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store under inert gas. 7.3 Specific end use(s) A part from the uses mentioned in section 1.2 no other specific uses are stipulated |
EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. |
PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: clear, liquid Colour: colourless b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point Melting point/range: -57 °C f) Initial boiling point and boiling range 115 - 117 °C g) Flash point 32 °C - closed cup h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits Upper explosion limit: 21 %(V) Lower explosion limit: 3,8 %(V) k) Vapour pressure 18,4 hPa at 21,1 °C l) Vapour density 3,19 - (Air = 1.0) m) Relative density 1,183 g/mL at 25 °C n) Water solubility no data available o) Partition coefficient: noctanol/ water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available 9.2 Other safety information Relative vapour density 3,19 - (Air = 1.0) |
STABILITY AND REACTIVITY | 10.1 Reactivity no data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials acids, Bases, Ammonia, Amines, Sodium/sodium oxides, Zinc, Magnesium, Aluminum, and its alloys, Halides 10.6 Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5 |
TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - rat - 90 mg/kg LC50 Inhalation - rat - 8 h - 250 ppm Skin corrosion/irritation Skin - rabbit Result: Open irritation test - 24 h Serious eye damage/eye irritation Eyes - rabbit Result: Severe eye irritation Respiratory or skin sensitisation May cause sensitisation by skin contact. Germ cell mutagenicity May alter genetic material. Carcinogenicity This product is or contains a component that has been reported to be probably carcinogenic based on its IARC, OSHA, ACGIH, NTP, or EPA classification. Possible human carcinogen IARC: 2A - Group 2A: Probably carcinogenic to humans (Epichlorhydrin) Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Additional Information RTECS: Not available Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough |
ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 10,6 mg/l - 96 h Toxicity to daphnia and other aquatic LC50 - Daphnia magna (Water flea) - 21 mg/l - 48 h invertebrates 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential no data available 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.6 Other adverse effects Harmful to aquatic life |
DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. |
TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 2023 IMDG: 2023 IATA: 2023 14.2 UN proper shipping name ADR/RID: EPICHLOROHYDRIN IMDG: EPICHLOROHYDRIN IATA: Epichlorohydrin 14.3 Transport hazard class(es) ADR/RID: 6.1 (3) IMDG: 6.1 (3) IATA: 6.1 (3) 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: yes IATA: no 14.6 Special precautions for user no data available |
REGULATORY INFORMATION | This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture no data available 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |