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Bis(2-ethylhexyl) phthalate

Item number676542
CAS117-81-7
FormulaC24H38O4
Molecular weight390,56 g/mol
Quantity 1X500MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
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Bis(2-ethylhexyl) phthalate

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Bis(2-ethylhexyl) phthalate

Bis(2-ethylhexyl) phthalate

676542
117-81-7

1X500MG

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Bis(2-ethylhexyl) phthalate solution
Concentration: 10.0 µg/ml
Solvent: Cyclohexane

Bis(2-ethylhexyl) phthalate solution

680342
117-81-7

1X10ML

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Bis(2-ethylhexyl) phthalate solution
Concentration: 100 µg/ml
Solvent: Cyclohexane

Bis(2-ethylhexyl) phthalate solution

688562
117-81-7

1X1ML

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D4-Bis(2-ethylhexyl) phthalate

D4-Bis(2-ethylhexyl) phthalate

690272
93951-87-2

1X25MG

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 22.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Bis(2-ethylhexyl) phthalate
Catalog No.:676542
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Reproductive toxicity (Category 1B), H360FD
Label elements
PictogramGHS08 silhouete
silhouete
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger
Hazard statement(s)
H360FD May damage fertility. May damage the unborn child.
Precautionary statement(s)
P201 Obtain special instructions before use.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P308 + P313 IF exposed or concerned: Get medical advice/ Attention Supplemental Hazard
Statements
none
Restricted to professional users.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting chemical(s)
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : Phthalic acid bis(2-ethylhexyl ester)
‘Dioctyl’ phthalate
DEHP
Formula : C24H38O4
Molecular weight : 390,56 g/mol
CAS-No. : 117-81-7
EC-No. : 204-211-0
Index-No. : 607-317-00-9
Registration number : 01-2119484611-38-XXXX
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
bis(2-Ethylhexyl) phthalate Included in the Candidate List of Substances of Very High Concern (SVHC)
according to Regulation (EC) No. 1907/2006 (REACH)
CAS-No.
EC-No.
Index-No.
Registration number
117-81-7
204-211-0
607-317-00-9
01-2119484611-38-XXXX
Repr. 1B; H360FD <= 100 %
FormulaC24H38O4
Molecular Weight (g/mol)390.56
CAS-No.117-81-7
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation
of vapour or mist.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous
materials causing chronic effects
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry Hands Body Protection
Impervious clothing, The type of protective equipment must be selected according to the
concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
-50,0 °C
f) Initial boiling point and
boiling range
386 °C - lit.
g) Flash point 207,0 °C - closed cup
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
Lower explosion limit: 0,3 %(V) explosive limits
k) Vapour pressure 1,6 hPa at 93,0 °C
l) Vapour density No data available
m) Relative density 0,985 g/cm3 at 20 °C
n) Water solubility insoluble
o) Partition coefficient: noctanol/
water
No data available
p) Auto-ignition
temperature
390,0 °C
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 30.000 mg/kg
LD50 Dermal - Rabbit - 25.000 mg/kg
Skin corrosion/irritation
Skin - Rabbit
Result: Mild skin irritation - 24 h
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Mild eye irritation - 24 h
Respiratory or skin sensitisation
Maximisation Test (GPMT) - Guinea pig
Result: Does not cause skin sensitisation.
(OECD Test Guideline 406) Germ cell mutagenicity
No data available
Carcinogenicity
This product is or contains a component that has been reported to be possibly carcinogenic based on its
IARC, ACGIH, NTP, or EPA classification.
IARC: 2B - Group 2B: Possibly carcinogenic to humans (bis(2-Ethylhexyl) phthalate)
Reproductive toxicity
May cause congenital malformation in the fetus.
Presumed human reproductive toxicant
May cause reproductive disorders.
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: TI0350000
Effects due to ingestion may include:, Gastrointestinal disturbance
Kidney -
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - > 0,67 mg/l - 96 h
LC50 - Oncorhynchus mykiss (rainbow trout) - > 0,32 mg/l - 96 h
LC50 - Cyprinodon variegatus (sheepshead minnow) - > 0,17 mg/l - 96 h
LC50 - Lepomis macrochirus (Bluegill) - > 0,20 mg/l - 96 h
NOEC - other fish - > 0,3 mg/l - 96 h
Toxicity to daphnia and
other aquatic
invertebrates
Immobilization EC50 - Daphnia magna (Water flea) - > 0,16 mg/l - 48 h
12.2 Persistence and degradability
Biodegradability Result: - Readily biodegradable
(OECD Test Guideline 301)
12.3 Bioaccumulative potential
Bioaccumulation Oncorhynchus mykiss (rainbow trout) - 100 d
- 0,014 mg/l
Bioconcentration factor (BCF): 113
Remarks: Does not bioaccumulate.
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product
TRANSPORT INFORMATION14.1 UN number
ADR/RID: - IMDG: - IATA: -
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
14.4 Packaging group
ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 453/2010.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Authorisations and/or restrictions on use
bis(2-Ethylhexyl) phthalate CAS-No.: 117-81-7
REACH - List of substances subject to authorisation (Annex XIV)
Toxic for reproduction (category 1B)
Sunset Date: 21.02.2015
Exempted (Categories of) Uses: Uses in the immediate packaging of medicinal products covered under
Regulation (EC) No 726/2004, Directive 2001/82/EC, and/or Directive 2001/83/EC.
bis(2-Ethylhexyl) phthalate CAS-No.: 117-81-7
REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).
Toxic for reproduction (article 57c)
ED/67/2008
bis(2-Ethylhexyl) phthalate CAS-No.: 117-81-7
REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).
Equivalent level of concern having probable serious effects to the environment (article 57 f)
ED/108/2014
bis(2-Ethylhexyl) phthalate CAS-No.: 117-81-7
REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous
substances, preparations and articles (Annex XVII)
Toxic to reproduction: category 1B
Restricted to professional users.
See Annex XVII to Regulation (EC) no 1907/2006 for Conditions of restriction bis(2-Ethylhexyl) phthalate CAS-No.: 117-81-7
REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous
substances, preparations and articles (Annex XVII)
Shall not be used in toys
See Annex XVII to Regulation (EC) no 1907/2006 for Conditions of restriction
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!