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Salicylaldehyde

Item number676457
CAS90-02-8
FormulaC7H6O2
Molecular weight122,12 g/mol
Quantity 1X1ML
storage conditions4 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
Salicylaldehyde

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Salicylaldehyde

Salicylaldehyde

676457
90-02-8

1X1ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 25.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Salicylaldehyde
Catalog No.:676457
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Chronic aquatic toxicity (Category 2), H411 Classification according to EU Directives 67/548/EEC or 1999/45/EC
Xn Harmful R22
N Dangerous for the
environment
R51/53
Label elements
PictogramGHS07 exclam
exclam
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
Signal word Warning
Hazard statement(s)
H302 Harmful if swallowed.
H411 Toxic to aquatic life with long lasting effects. Precautionary statement(s)
P273 Avoid release to the environment.
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you
feel unwell. Rinse mouth.
P391 Collect spillage.
P501 Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : 2-Hydroxybenzaldehyde
Formula : C7H6O2
Molecular weight : 122,12 g/mol
CAS-No. : 90-02-8
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Salicylaldehyde
CAS-No.
EC-No.
90-02-8
201-961-0
Acute Tox. 4; Aquatic Chronic
2; H302, H411
<= 100 %
Phenol
CAS-No.
EC-No.
Index-No.
108-95-2
203-632-7
604-001-00-2
Acute Tox. 3; Skin Corr. 1B;
Muta. 2; STOT RE 2; Aquatic
Chronic 2; H301 + H311 +
H331, H314, H341, H373,
H411
>= 0,25 - < 1 %
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
Salicylaldehyde
CAS-No.
EC-No.
90-02-8
201-961-0
Xn, N, R22 - R51/53 <= 100 %
Phenol
CAS-No.
EC-No.
Index-No.
108-95-2
203-632-7
604-001-00-2
T, Mut.Cat.3, R23/24/25 - R34
- R48/20/21/22 - R68
< 1 %
FormulaC7H6O2
Molecular Weight (g/mol)122.12
CAS-No.90-02-8
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
Use water spray to cool unopened containers
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations.
Vapours can accumulate in low areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
place in container for disposal according to local regulations (see section 13). Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Light sensitive. Store under inert gas. Air sensitive.
Storage class (TRGS 510): Combustible liquids 7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/range: 1 - 2 °C
f) Initial boiling point and
boiling range
197 °C
g) Flash point 77 °C - closed cup
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure 1,33 hPa at 33 °C
l) Vapour density No data available
m) Relative density 1,146 g/mL at 25 °C
n) Water solubility No data available
o) Partition coefficient: noctanol/
water
Pow: 1,244
p) Auto-ignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
Water, Reducing agents, Halogens, Acids
10.6 Hazardous decomposition products
Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 520 mg/kg
Inhalation: No data available
LD50 Dermal - Rabbit - 3.000 mg/kg
LD50 Subcutaneous - Rat - 900 mg/kg
LD50 Intraperitoneal - Mouse - 231 mg/kg
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation
(OECD Test Guideline 404)
Serious eye damage/eye irritation
No eye irritation The preceding data, or interpretation of data, was determined using Quantitative Structure
Activity Relationship (QSAR) modeling.
Respiratory or skin sensitisation
No data available
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Phenol)
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available Aspiration hazard
No data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 2,3 mg/l - 96 h
Toxicity to daphnia and
other aquatic
invertebrates
LC50 - Daphnia magna (Water flea) - 3,2 mg/l - 48 h
Immobilization EC50 - Daphnia magna (Water flea) - 2,6 mg/l - 48 h
(OECD Test Guideline 202) Toxicity to algae Growth inhibition NOEC - Pseudokirchneriella subcapitata (green algae) - 0,55
mg/l - 72 h
12.2 Persistence and degradability
Biodegradability Result: 2 % - Not rapidly biodegradable
(OECD Test Guideline 301C)
12.3 Bioaccumulative potential
Due to the distribution coefficient n-octanol/water, accumulation in organisms is not expected.
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
Toxic to aquatic life with long lasting effects.
No data available
Toxic to aquatic life with long lasting effects
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
This combustible material may be burned in a chemical incinerator equipped with an afterburner and
scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product
TRANSPORT INFORMATION14.1 UN number
ADR/RID: - IMDG: - IATA: -
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
14.4 Packaging group
ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No data available
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!