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Salicylaldehyde

Item number	676457
CAS	90-02-8
Formula	C7H6O2
Molecular weight	122,12 g/mol
Quantity	1X1ML
storage conditions	4 °C
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Salicylaldehyde		676457 90-02-8	1X1ML	Please log in.

Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 19.11.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	Salicylaldehyde
Catalog No.:	676457
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com
Emergency telephone number	HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours.
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Chronic aquatic toxicity (Category 2), H411 Classification according to EU Directives 67/548/EEC or 1999/45/EC Xn Harmful R22 N Dangerous for the environment R51/53
Label elements
Pictogram	GHS07 exclam exclam GHS09 Aquatic-pollut-red Aquatic-pollut-red
	Signal word Warning Hazard statement(s) H302 Harmful if swallowed. H411 Toxic to aquatic life with long lasting effects. Precautionary statement(s) P273 Avoid release to the environment. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P391 Collect spillage. P501 Dispose of contents/ container to an approved waste disposal plant. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS	3.1 Substances Synonyms : 2-Hydroxybenzaldehyde Formula : C7H6O2 Molecular weight : 122,12 g/mol CAS-No. : 90-02-8 Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration Salicylaldehyde CAS-No. EC-No. 90-02-8 201-961-0 Acute Tox. 4; Aquatic Chronic 2; H302, H411 <= 100 % Phenol CAS-No. EC-No. Index-No. 108-95-2 203-632-7 604-001-00-2 Acute Tox. 3; Skin Corr. 1B; Muta. 2; STOT RE 2; Aquatic Chronic 2; H301 + H311 + H331, H314, H341, H373, H411 >= 0,25 - < 1 % Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration Salicylaldehyde CAS-No. EC-No. 90-02-8 201-961-0 Xn, N, R22 - R51/53 <= 100 % Phenol CAS-No. EC-No. Index-No. 108-95-2 203-632-7 604-001-00-2 T, Mut.Cat.3, R23/24/25 - R34 - R48/20/21/22 - R68 < 1 %
Formula	C7H6O2
Molecular Weight (g/mol)	122.12
CAS-No.	90-02-8
FIRST AID MEASURES	4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES	5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE	7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Light sensitive. Store under inert gas. Air sensitive. Storage class (TRGS 510): Combustible liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION	8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties a) Appearance Form: liquid b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/range: 1 - 2 °C f) Initial boiling point and boiling range 197 °C g) Flash point 77 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits No data available k) Vapour pressure 1,33 hPa at 33 °C l) Vapour density No data available m) Relative density 1,146 g/mL at 25 °C n) Water solubility No data available o) Partition coefficient: noctanol/ water Pow: 1,244 p) Auto-ignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available
STABILITY AND REACTIVITY	10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Water, Reducing agents, Halogens, Acids 10.6 Hazardous decomposition products Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 520 mg/kg Inhalation: No data available LD50 Dermal - Rabbit - 3.000 mg/kg LD50 Subcutaneous - Rat - 900 mg/kg LD50 Intraperitoneal - Mouse - 231 mg/kg Skin corrosion/irritation Skin - Rabbit Result: No skin irritation (OECD Test Guideline 404) Serious eye damage/eye irritation No eye irritation The preceding data, or interpretation of data, was determined using Quantitative Structure Activity Relationship (QSAR) modeling. Respiratory or skin sensitisation No data available No data available Germ cell mutagenicity No data available Carcinogenicity IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Phenol) Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS: Not available To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
ECOLOGICAL INFORMATION	12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 2,3 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates LC50 - Daphnia magna (Water flea) - 3,2 mg/l - 48 h Immobilization EC50 - Daphnia magna (Water flea) - 2,6 mg/l - 48 h (OECD Test Guideline 202) Toxicity to algae Growth inhibition NOEC - Pseudokirchneriella subcapitata (green algae) - 0,55 mg/l - 72 h 12.2 Persistence and degradability Biodegradability Result: 2 % - Not rapidly biodegradable (OECD Test Guideline 301C) 12.3 Bioaccumulative potential Due to the distribution coefficient n-octanol/water, accumulation in organisms is not expected. 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Toxic to aquatic life with long lasting effects. No data available Toxic to aquatic life with long lasting effects
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods Product This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product
TRANSPORT INFORMATION	14.1 UN number ADR/RID: - IMDG: - IATA: - 14.2 UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods 14.3 Transport hazard class(es) ADR/RID: - IMDG: - IATA: - 14.4 Packaging group ADR/RID: - IMDG: - IATA: - 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION	This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No data available 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!