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Potassium sorbate

Item number673083
CAS24634-61-5
FormulaC6H7O2K
Molecular weight150,22 g/mol
Quantity 1X250MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
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Potassium sorbate

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Potassium sorbate

Potassium sorbate

673083
24634-61-5

1X250MG

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 15.01.2025
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Potassium sorbate
Catalog No.:673083
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Eye irritation (Category 2), H319
For the full text of the H-Statements mentioned in this Section, see Section 16.
Label elements
PictogramGHS07 exclam
exclam
2.2 Label elements
Labeling according Regulation (EC) No 1272/2008
Signal Word Warning
Hazard statement(s)
H319 Causes serious eye irritation.
Precautionary statement(s)
P264 Wash skin thoroughly after handling.
P280 Wear eye protection/ face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
Supplemental Hazard
Statements
none
Reduced Labeling (<= 125 ml)
Signal Word Warning
Hazard statement(s) none
Precautionary
statement(s)
none
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
Ecological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Toxicological information:
The substance/mixture does not contain components considered to have endocrine
disrupting properties according to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : 2,4-Hexadienoic acidpotassium salt
Sorbic acidpotassium salt
Component
potassium sorbate
EC-No. 246-376-1
Index-No. 019-003-00-3
CAS- No. 24634-61-5
Classification
Eye Irrit. 2; H319
<= 100 %
For the full text of the H-Statements mentioned in this Section, see Section 16.


FormulaC6H7O2K
Molecular Weight (g/mol)150.22
CAS-No.24634-61-5
FIRST AID MEASURES4.1 Description of first-aid measures
General advice
Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact
lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a
physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labeling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
Potassium oxides
Combustible.
Development of hazardous combustion gases or vapours possible in the event of fire.
5.3 Advice for firefighters
In the event of fire, wear self-contained breathing apparatus.
5.4 Further information
Prevent fire extinguishing water from contaminating surface water or the ground water
system.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact.
Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures,
consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid
generation of dusts.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Tightly closed. Dry.
Storage class
Storage class (TRGS 510): 11: Combustible Solids
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Ingredients with workplace control parameters
Derived No Effect Level (DNEL)
Application Area Routes of exposure Health effect Value Value
dermal Systemic effects
Worker DNEL,
longterm
dermal Systemic effects
Worker DNEL,
longterm
inhalation Systemic effects 17,63 mg/m3
Consumer DNEL,
longterm
oral Systemic effects
Consumer DNEL,
longterm
dermal Systemic effects
Consumer DNEL,
longterm
inhalation Systemic effects 52,17 mg/m3
Worker DNEL,
longterm
dermal Local effects 0,17 mg/m3
Worker DNEL,
longterm
inhalation Local effects

Predicted No Effect Concentration (PNEC)
Compartment Value
Fresh water 0,48 mg/l
Fresh water sediment 0,173 mg/kg
Soil 1,67 mg/kg
Sewage treatment plant 10 mg/l
8.2 Exposure controls
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching gloves outer surface) to avoid skin contact
with this product. Dispose of contaminated gloves after use in accordance with
applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU)
2016/425 and the standard EN 374 derived from it.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested: Size M gloves
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested: Size M gloves
test method: EN374
If used in solution, or mixed with other substances, and under conditions which
differ from EN 374, contact the supplier of the EC approved gloves. This
recommendation is advisory only and must be evaluated by an industrial hygienist
and safety officer familiar with the specific situation of anticipated use by our
customers. It should not be construed as offering an approval for any specific use
scenario.
Body Protection
protective clothing
Respiratory protection
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Recommended Filter type: Filter type P2
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Control of environmental exposure
Do not let product enter drains.

PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Physical state crystalline
b) Color white
c) Odor odorless
d) Melting
point/freezing point
Decomposes before melting.
e) Initial boiling point
and boiling range
decomposition below boiling point
f) Flammability (solid,
gas)
No data available
g) Upper/lower
flammability or
explosive limits
No data available
h) Flash point Not applicable
i) Autoignition
temperature
178 °C
- Relative self-ignition temperature for solids
j) Decomposition
temperature
>= 205 °C
k) pH 7,75 - 7,77 at 20,1 °C
l) Viscosity Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
m) Water solubility 1,95 g/l at 20 °C - OECD Test Guideline 105- completely soluble
n) Partition coefficient:
n-octanol/water
log Pow: 1,32 at 20 °C - OECD Test Guideline 117 -
Bioaccumulation is not expected.
o) Vapor pressure < 0,01 hPa at 20 °C - OECD Test Guideline 104
p) Density No data available
Relative density 1,36 at 23,5 °C - OECD Test Guideline 109
q) Relative vapor
density
r) Particle
characteristics
No data available
s) Explosive properties No data available
t) Oxidizing properties none
9.2 Other safety information
Surface tension 72,6 mN/m at 20 °C
- OECD Test Guideline 115
Dissociation constant 4,69 at 20 °C
- OECD Test Guideline 112

STABILITY AND REACTIVITY10.1 Reactivity
The following applies in general to flammable organic substances and mixtures: in
correspondingly fine distribution, when whirled up a dust explosion potential may generally
be assumed.
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.3 Possibility of hazardous reactions
Violent reactions possible with:
Oxidizing agents
Aluminum
Zinc
Tin
10.4 Conditions to avoid
no information available
10.5 Incompatible materials
No data available
10.6 Hazardous decomposition products
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male and female - > 10.500 mg/kg
Remarks: (ECHA)
The value is given in analogy to the following substances: Sorbic acid
LC50 Inhalation - Rat - 4 h - > 5,15 mg/l - dust/mist
(OECD Test Guideline 403)
LD50 Dermal - Rat - male and female - > 2.000 mg/kg
(OECD Test Guideline 402)
Remarks: The value is given in analogy to the following substances: Sorbic acid
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Eye irritation
(OECD Test Guideline 405)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Respiratory or skin sensitization
Maximization Test - Guinea pig
Result: negative
(Regulation (EC) No. 440/2008, Annex, B.6)
Remarks: The value is given in analogy to the following substances: Sorbic acid
Germ cell mutagenicity
In vivo tests did not show mutagenic effects
Test Type: In vitro mammalian cell gene mutation test
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Test Type: Ames test
Test system: S. typhimurium
Metabolic activation: with and without metabolic activation
Method: Regulation (EC) No. 440/2008, Annex, B.13/14 (Ames test)
Result: negative
Remarks: The value is given in analogy to the following substances: Sorbic acidTest Type:
Mutagenicity (mammal cell test): chromosome aberration.
Test system: Chinese hamster lung cells
Metabolic activation: without metabolic activation
Method: Regulation (EC) No. 440/2008, Annex, B.10
Result: positive
Test Type: UDS (Unscheduled DNA synthesis assay)
Test system: mammalian cells
Metabolic activation: with and without metabolic activation
Method: Regulation (EC) No. 440/2008, Annex, B.18
Result: negative
Remarks: The value is given in analogy to the following substances: Sorbic acid
Test Type: In vivo micronucleus test
Species: Mouse
Cell type: Bone marrow
Application Route: Oral
Method: OECD Test Guideline 474
Result: negative
Remarks: The value is given in analogy to the following substances: Sorbic acid
Carcinogenicity
No data available
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Additional Information
Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain
components considered to have endocrine
disrupting properties according to REACH Article
57(f) or Commission Delegated regulation (EU)
2017/2100 or Commission Regulation (EU)
2018/605 at levels of 0.1% or higher.
RTECS: WG2170000
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish static test LC50 - Danio rerio (zebra fish) - > 1.000 mg/l - 96 h
(OECD Test Guideline 203)
Toxicity to daphnia
and other aquatic
invertebrates
static test EC50 - Daphnia magna (Water flea) - 982 mg/l - 48 h
(OECD Test Guideline 202)
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata - 77 mg/l - 72 h
(OECD Test Guideline 201)
Remarks: The value is given in analogy to the following substances:
Sorbic acid
static test NOEC - Pseudokirchneriella subcapitata - 56 mg/l - 72 h
(OECD Test Guideline 201)
Remarks: The value is given in analogy to the following substances:
Sorbic acid
Toxicity to bacteria static test EC50 - activated sludge - > 100 mg/l - 72 h
(OECD Test Guideline 209)
Remarks: The value is given in analogy to the following substances:
Sorbic acid
Toxicity to daphnia
and other aquatic
invertebrates(Chronic
toxicity)
semi-static test NOEC - Daphnia magna (Water flea) - 50 mg/l - 21
d
(OECD Test Guideline 211)
Remarks: The value is given in analogy to the following substances:
Sorbic acid
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 74,9 % - Readily biodegradable.
(OECD Test Guideline 301D)
Remarks: The value is given in analogy to the following substances:
Sorbic acid
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
12.6 Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties
according to REACH Article 57(f) or Commission
Delegated regulation (EU) 2017/2100 or Commission
12.7 Other adverse effects
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
No data available
TRANSPORT INFORMATION14.1 UN number
ADR/RID: - IMDG: - IATA: -
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
14.4 Packaging group
ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
Further information
Not classified as dangerous in the meaning of transport regulations.
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.
Authorisations and/or restrictions on use
Other regulations
Take note of Dir 94/33/EC on the protection of young people at work.
15.2 Chemical Safety Assessment
A Chemical Safety Assessment has been carried out for this substance.

OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!