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Clavulanic acid potassium salt

Item number676839
CAS61177-45-5
FormulaC8H8KNO5
Molecular weight237,25 g/mol
Quantity 1X100MG
storage conditions-20 °C
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Clavulanic acid potassium salt

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Clavulanic acid potassium salt

Clavulanic acid potassium salt

676839
61177-45-5

1X100MG

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 15.01.2025
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Clavulanic acid potassium salt
Catalog No.:676839
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable solids (Category 2), H228
Self-heating substances and mixtures (Category 2), H252
Respiratory sensitization (Category 1), H334
Skin sensitization (Category 1), H317
Label elements
Pictogramflamme
flamme
GHS08 silhouete
silhouete
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger
Hazard statement(s)
H228 Flammable solid.
H252 Self-heating in large quantities; may catch fire.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties
if inhaled.
Precautionary statement(s)
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P235 Keep cool.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection/ hearing protection.
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/ doctor if you feel unwell.
P403 + P235 Store in a well-ventilated place. Keep cool.
Supplemental Hazard information (EU)
EUH014 Reacts violently with water.
EUH044 Risk of explosion if heated under confinement.
Reduced Labeling (<= 125 ml)
Pictogram Signal word Danger
Hazard statement(s)
H334 May cause allergy or asthma symptoms or breathing difficulties
if inhaled.
H317 May cause an allergic skin reaction.
Precautionary statement(s)
P302 + P352 IF ON SKIN: Wash with plenty of water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/ doctor if you feel unwell.
Supplemental Hazard information (EU)
EUH014 Reacts violently with water.
EUH044 Risk of explosion if heated under confinement.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : Clavulanate potassium
Formula : C8H8NO5K Molecular weight : 237,25 g/mol
CAS-No. : 61177-45-5
EC-No. : 262-640-9
Component Classification Concentration
Potassium clavulanate
Flam. Sol. 2; Self-heat. 2;
Resp. Sens. 1; Skin Sens.
1; H228, H252, H334,
H317
<= 100 %
FormulaC8H8KNO5
Molecular Weight (g/mol)237.25
CAS-No.61177-45-5
FIRST AID MEASURES4.1 Description of first-aid measures
General advice
First aider needs to protect himself. Show this material safety data sheet to the doctor in
attendance.
If inhaled
After inhalation: fresh air. Call in physician.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower. Consult a physician.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact
lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a
physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media
Water Foam 5.2 Special hazards arising from the substance or mixture
Carbon oxides
Nitrogen oxides (NOx)
Potassium oxides
Hydrogen cyanide (hydrocyanic acid)
Combustible.
May not get in touch with: Water
Development of hazardous combustion gases or vapours possible in the event of fire.
5.3 Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by
keeping a safe distance or by wearing suitable protective clothing.
5.4 Further information
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire
extinguishing water from contaminating surface water or the ground water system
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact.
Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the
danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains. Risk of explosion.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up carefully. Dispose of properly. Clean up affected area.
Avoid generation of dusts.
6.4 Reference to other sections
For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling
Advice on safe handling
Work under hood. Do not inhale substance/mixture. Keep workplace dry. Do not allow
product to come into contact with water.
Advice on protection against fire and explosion
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary
measures against static discharge.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands
and face after working with substance.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Tightly closed. Keep away from heat and sources of ignition. Keep locked up or in an area
accessible only to qualified or authorized persons. Never allow product to get in contact with water during storage.
Storage stability
Recommended storage temperature
2 - 8 °C
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Ingredients with workplace control parameters
8.2 Exposure controls
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use.
Body Protection
Flame retardant antistatic protective clothing.
Respiratory protection
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Recommended Filter type: Filter type P2
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Control of environmental exposure
Do not let product enter drains. Risk of explosion.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odor No data available
c) Odor Threshold No data available
d) pH No data available
e) Melting
point/freezing point
Decomposes before melting.
f) Initial boiling point
and boiling range
Decomposes on heating.
g) Flash point Not applicable
h) Evaporation rate No data available
i) Flammability (solid,
gas)
The substance or mixture is a flammable solid with the category
2.
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapor pressure No data available
l) Vapor density No data available
m) Relative density No data available
n) Water solubility soluble
o) Partition coefficient:
n-octanol/water
No data available
p) Autoignition
temperature
Self-heating in large quantities; may catch fire.
q) Decomposition
temperature
185 °C - Decomposes on heating.
r) Viscosity Viscosity, kinematic: No data available
Viscosity, dynamic: No data available s) Explosive properties Risk of explosion if heated under confinement.
t) Oxidizing properties No data available 9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
Risk of explosion if heated under confinement.
The following applies in general to flammable organic substances and mixtures: in
correspondingly fine distribution, when whirled up a dust explosion potential may generally
be assumed.
10.2 Chemical stability
Decomposes when moist.
sensitive to moisture
10.3 Possibility of hazardous reactions
May decompose on exposure to moist air or water.
10.4 Conditions to avoid
Moisture.
10.5 Incompatible materials
Strong oxidizing agents, Water
10.6 Hazardous decomposition products
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 7.936 mg/kg
Remarks: Behavioral:Somnolence (general depressed activity). Lungs, Thorax, or
Respiration:Dyspnea. (RTECS)
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitization
May cause allergic respiratory and skin reactions
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Additional Information
RTECS: RN6802700
Blurred vision, reddened eyes, swelling, Pain
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
12.6 Other adverse effects
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 1325 IMDG: 1325 IATA: 1325
14.2 UN proper shipping name
ADR/RID: FLAMMABLE SOLID, ORGANIC, N.O.S. (Potassium clavulanate)
IMDG: FLAMMABLE SOLID, ORGANIC, N.O.S. (Potassium clavulanate)
IATA: Flammable solid, organic, n.o.s. (Potassium clavulanate)
14.3 Transport hazard class(es)
ADR/RID: 4.1 IMDG: 4.1 IATA: 4.1 14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.
REACH - Restrictions on the manufacture,
placing on the market and use of certain
dangerous substances, preparations and articles
(Annex XVII)
:
National legislation
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the
control of major-accident hazards involving dangerous substances.
O1 OTHER HAZARDS
Other regulations
Take note of Dir 94/33/EC on the protection of young people at work.
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!