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3-Carene

Item number684147
CAS13466-78-9
FormulaC10H16
Molecular weight136,23 g/mol
Quantity 1X1ML
storage conditions20 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
3-Carene

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13466-78-9

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 15.01.2025
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:3-Carene
Catalog No.:684147
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 3), H226
Skin irritation (Category 2), H315
Skin sensitisation (Category 1), H317
Aspiration hazard (Category 1), H304
Label elements
Pictogramflamme
flamme
GHS07 exclam
exclam
GHS08 silhouete
silhouete
Signal word Danger
Hazard statement(s)
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
Precautionary statement(s)
P280 Wear protective gloves.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P331 Do NOT induce vomiting.
P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to
extinguish.
P403 + P235 Store in a well-ventilated place. Keep cool.
Supplemental Hazard Statements none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C10H16
Molecular weight : 136.23 g/mol
CAS-No. : 13466-78-9
EC-No. : 236-719-3
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component: 3-Carene
CAS-No.: 13466-78-9
EC-No.: 236-719-3
Classification:
Flam. Liq. 3; Skin Irrit. 2; Skin
Sens. 1; Asp. Tox. 1; H226,
H315, H317, H304
Concentration: <= 100 %



FormulaC10H16
Molecular Weight (g/mol)136.23
CAS-No.13466-78-9
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to
form explosive concentrations. Vapours can accumulate in low areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
place in container for disposal according to local regulations (see section 13).
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Store under inert gas. Air and moisture sensitive.
Storage class (TRGS 510): Flammable liquids
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching gloves outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing. The
type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use (US) or type ABEK (EN
14387) respirator cartridges as a backup to enginee protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
Colour: colourless
b) Odour sweet, pungent
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/freezing point: < -79.99 °C at 1,013 hPa - OECD Test
Guideline 102
f) Initial boiling point and
boiling range
168 - 169 °C at 940 hPa
g) Flash point 47 °C at ca.1,013 hPa - closed cup
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure 2.73 hPa at 20 °C - OECD Test Guideline 104
l) Vapour density No data available
m) Relative density 0.857 g/cm3 -
n) Water solubility 0.0005 g/l at 20 °C - OECD Test
o) Partition coefficient: noctanol/
water
log Pow: 4.38 at 37 °C - OECD Test Guideline 117
p) Auto-ignition
temperature
260 °C
at 998 hPa
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 4,800 mg/kg(3-Carene)
Skin corrosion/irritation
No data available(3-Carene)
Serious eye damage/eye irritation
Eyes - Rabbit(3-Carene)
Result: No eye irritation
(OECD Test Guideline 405)
Respiratory or skin sensitisation
- Guinea pig(3-Carene)
Result: May cause sensitisation by skin contact.
Germ cell mutagenicity
Ames test(3-Carene)
S. typhimurium
Result: negative
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available(3-Carene)
Specific target organ toxicity - single exposure
No data available(3-Carene)
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available(3-Carene)
Additional Information
RTECS: FH8400000
ECOLOGICAL INFORMATION12.1 Toxicity
No data available
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d(3-Carene)
Result: 53 % - Not readily biodegradable.
(OECD Test Guideline 301B)
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available(3-Carene)
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber b highly flammable. Offer
surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 2319 IMDG: 2319 IATA: 2319
14.2 UN proper shipping name
ADR/RID: TERPENE HYDROCARBONS, N.O.S.
IMDG: TERPENE HYDROCARBONS, N.O.S.
IATA: Terpene hydrocarbons, n.o.s.
14.3 Transport hazard class(es)
ADR/RID: 3 IMDG: 3 IATA: 3
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!