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Item number | 689183 |
CAS | 74-96-4 |
Formula | C2H5Br |
Molecular weight | 108,97 g/mol |
Quantity | 1X1000MG |
storage conditions | 4 °C |
CoA / MSDS | Retrieve CoA Retrieve MSDS |
Product | Catalog No./ CAS No. | Quantity | Price | |
---|---|---|---|---|
689183 | 1X1000MG | Please log in. | ||
Bromoethane solution | 689184 | 1X5ML |
Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 29.11.2024 |
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
Product name: | Bromoethane |
Catalog No.: | 689183 |
Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 2), H225 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 4), H332 Carcinogenicity (Category 2), H351 Hazardous to the ozone layer (Category 1), H420 |
Label elements | |
Pictogram | flamme flamme GHS07 exclam exclam GHS08 silhouete silhouete |
2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Signal Word Danger Hazard statement(s) H225 Highly flammable liquid and vapor. H302 + H332 Harmful if swallowed or if inhaled. H351 Suspected of causing cancer. H420 Harms public health and the environment by destroying ozone in the upper atmosphere. Precautionary statement(s) P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P502 Refer to manufacturer or supplier for information on recovery or recycling. Supplemental Hazard Statements none Reduced Labeling (<= 125 ml) Signal Word Danger Hazard statement(s) H351 Suspected of causing cancer. H420 Harms public health and the environment by destroying ozone in the upper atmosphere. Precautionary statement(s) P202 Do not handle until all safety precautions have been read and understood. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P502 Refer to manufacturer or supplier for information on recovery or recycling. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. | |
COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : Ethyl bromide Component: Ethyl bromide CAS-No. : 74-96-4 EC-No. : 200-825-8 Index-No. : 602-055-00-1 Classification: Flam. Liq. 2; Acute Tox. 4; Carc. 2; Ozone 1; H225, H302, H332, H351, H420 Concentration: <= 100 % |
Formula | C2H5Br |
Molecular Weight (g/mol) | 108.97 |
CAS-No. | 74-96-4 |
FIRST AID MEASURES | 4.1 Description of first-aid measures General advice Show this material safety data sheet to the doctor in attendance. If inhaled After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. In case of skin contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. In case of eye contact After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. If swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Water Foam Carbon dioxide (CO2) Dry powder Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. 5.2 Special hazards arising from the substance or mixture Carbon oxides Hydrogen bromide gas Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures. 5.3 Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. 5.4 Further information Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. 6.2 Environmental precautions Do not let product enter drains. Risk of explosion. 6.3 Methods and materials for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material. Dispose of properly. Clean up affected area. 6.4 Reference to other sections For disposal see section 13. |
HANDLING AND STORAGE | 7.1 Precautions for safe handling Advice on safe handling Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. Advice on protection against fire and explosion Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Storage conditions Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Refrigerate before opening. Handle and open container with care. Store under inert gas. Storage class Storage class (TRGS 510): 3: Flammable liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Personal protective equipment Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses Skin protection This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves. Body Protection Flame retardant antistatic protective clothing. Respiratory protection required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type AX The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. Control of environmental exposure Do not let product enter drains. Risk of explosion. |
PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Physical state clear, liquid b) Color colorless c) Odor No data available d) Melting point/freezing point Melting point/range: -119 °C - lit. e) Initial boiling point and boiling range 37 - 40 °C - lit. f) Flammability (solid, gas) No data available g) Upper/lower flammability or explosive limits Upper explosion limit: 11,25 %(V) Lower explosion limit: 6,75 %(V) h) Flash point -23 °C - closed cup i) Autoignition temperature No data available j) Decomposition temperature No data available k) pH No data available l) Viscosity Viscosity, kinematic: No data available Viscosity, dynamic: No data available m) Water solubility No data available n) Partition coefficient: n-octanol/water No data available o) Vapor pressure 519,7 hPa at 20 °C 1.745,2 hPa at 55 °C p) Density 1,46 g/cm3 at 25 °C - lit. Relative density No data available q) Relative vapor density No data available r) Particle characteristics No data available s) Explosive properties No data available t) Oxidizing properties none 9.2 Other safety information Relative vapor density 3,76 - (Air = 1.0) |
STABILITY AND REACTIVITY | 10.1 Reactivity Vapors may form explosive mixture with air. 10.2 Chemical stability The product is chemically stable under standard ambient conditions (room temperature) . 10.3 Possibility of hazardous reactions Violent reactions possible with: Alkali metals Alkaline earth metals sodium amide Oxidizing agents Metals Bases 10.4 Conditions to avoid Warming. 10.5 Incompatible materials No data available 10.6 Hazardous decomposition products In the event of fire: see section 5 |
TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 1.350 mg/kg Remarks: (RTECS) Acute toxicity estimate Oral - 1.350 mg/kg (Calculation method) Acute toxicity estimate Inhalation - 4 h - 11,1 mg/l - vapor (Expert judgment) Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Dermal: No data available Skin corrosion/irritation No data available Serious eye damage/eye irritation No data available Respiratory or skin sensitization No data available Germ cell mutagenicity No data available Carcinogenicity Suspected of causing cancer. Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available 11.2 Additional Information Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: KH6475000 narcosis, Dizziness, Weakness, Ataxia., Tremors To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata - 200 mg/l - 72 h (OECD Test Guideline 201) 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. 12.7 Other adverse effects No data available |
DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 1891 IMDG: 1891 IATA: 1891 14.2 UN proper shipping name ADR/RID: ETHYL BROMIDE IMDG: ETHYL BROMIDE IATA: Ethyl bromide 14.3 Transport hazard class(es) ADR/RID: 3 (6.1) IMDG: 3 (6.1) IATA: 3 (6.1) 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user Tunnel restriction code : (D/E) Further information : No data available |
REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. Authorisations and/or restrictions on use Regulation (EC) No 1005/2009 on substances that deplete the ozone layer : Ethyl bromide National legislation Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : FLAMMABLE LIQUIDS Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |