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n-Butyl acrylate (stabilized)

Item number688202
CAS141-32-2
FormulaC7H12O2
Molecular weight128,17 g/mol
Quantity 1X1ML
storage conditions4 °C
CoA / MSDSRetrieve CoA
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n-Butyl acrylate (stabilized)

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n-Butyl acrylate (stabilized)

n-Butyl acrylate (stabilized)

688202
141-32-2

1X1ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 05.10.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:n-Butyl acrylate (stabilized)
Catalog No.:688202
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 3), H226
Acute toxicity, Oral (Category 4), H302
Acute toxicity, Inhalation (Category 4), H332
Acute toxicity, Dermal (Category 4), H312
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Skin sensitisation (Category 1), H317
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Long-term (chronic) aquatic hazard (Category 3), H412
Label elements
Pictogramflamme
flamme
GHS07 exclam
exclam
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Warning
Hazard statement(s)
H226 Flammable liquid and vapour.
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
P261 Avoid breathing vapours.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
Lachrymator.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C7H12O2
Molecular weight : 128,17 g/mol
CAS-No. : 141-32-2
EC-No. : 205-480-7
Index-No. : 607-062-00-3
Component Classification Concentration
Butyl acrylate
Flam. Liq. 3; Acute Tox. 4;
Skin Irrit. 2; Eye Irrit. 2;
Skin Sens. 1; STOT SE 3;
Aquatic Chronic 3; H226,
H332, H315, H319, H317,
H335, H412
<= 100 %
FormulaC7H12O2
Molecular Weight (g/mol)128.17
CAS-No.141-32-2
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
Use water spray to cool unopened containers
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wetbrushing
and place in container for disposal according to local regulations (see section
13).
6.4 Reference to other sections
For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of
electrostatic charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent
leakage.
Light sensitive. Store under inert gas.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: clear, liquid
Colour: colourless
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting
point/freezing point
No data available
f) Initial boiling point
and boiling range
145 °C - lit.
g) Flash point 36 °C - closed cup
h) Evaporation rate No data available
i) Flammability (solid,
gas)
No data available
j) Upper/lower
flammability or
Upper explosion limit: 9,9 %(V)
Lower explosion limit: 1,3 %(V) explosive limits
k) Vapour pressure 4,4 hPa at 20 °C
l) Vapour density 4,43 - (Air = 1.0)
m) Relative density 0,894 g/mL at 25 °C
n) Water solubility slightly soluble
o) Partition coefficient:
n-octanol/water
log Pow: 2,38
p) Auto-ignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
Surface tension 20 mN/m at 27 °C
Relative vapour
density
4,43 - (Air = 1.0)
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
Contains the following stabiliser(s):
Mequinol (0,0015 %)
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
Strong acids, Strong oxidizing agents, Strong bases
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 3.150 mg/kg
(OECD Test Guideline 401)
LC50 Inhalation - Rat - male and female - 4 h - 10,3 mg/l
(OECD Test Guideline 403)
Skin corrosion/irritation
Skin - Rabbit
Result: irritating
Remarks: (External MSDS)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Eye irritation
Remarks: (External MSDS)
Respiratory or skin sensitisation
Local lymph node assay (LLNA) - Mouse
Result: positive
(OECD Test Guideline 429)
Germ cell mutagenicity
Ames test
Salmonella typhimurium
Result: negative
(National Toxicology Program)
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Specific target organ toxicity - single exposure
May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
Aspiration hazard
Additional Information Repeated dose toxicity - Rat - male - Oral - 90 d - No observed adverse effect level - 84
mg/kg
Subchronic toxicity
RTECS: UD3150000
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated., Cough, Shortness of breath, Headache, Nausea, Vomiting
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish flow-through test LC50 - Cyprinodon variegatus (sheepshead minnow) - 2,1 mg/l - 96 h
(OECD Test Guideline 203)
Toxicity to daphnia
and other aquatic
invertebrates
flow-through test EC50 - Daphnia magna (Water flea) - 2,6 mg/l -
48 h
(OECD Test Guideline 202)
EC5 - E.sulcatum - 50 mg/l - 72 h
Remarks: (maximum permissible toxic concentration)(IUCLID)
Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - 1,71
mg/l - 72 h
(OECD Test Guideline 201)
Toxicity to bacteria static test EC50 - activated sludge - > 1.000 mg/l - 30 min
(OECD Test Guideline 209)
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 80 - 90 % - Readily biodegradable.
(OECD Test Guideline 310)
12.3 Bioaccumulative potential
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
12.6 Other adverse effects
Toxic to aquatic life.
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra
care in igniting as this material is highly flammable. Offer surplus and non-recyclable
solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 2348 IMDG: 2348 IATA: 2348
14.2 UN proper shipping name
ADR/RID: BUTYL ACRYLATES, STABILIZED
IMDG: BUTYL ACRYLATES, STABILIZED
IATA: Butyl acrylates, stabilized
14.3 Transport hazard class(es)
ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!