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1,2,4-Trichlorobenzene Solution (Solvent: Hexane)
| Item number | 673856 |
| CAS | 120-82-1 |
| Formula | C6H3Cl3 |
| Molecular weight | 181,45 g/mol |
| Quantity | 1X5ML |
| Concentration | 100 µg/ml |
| Solvent | Hexane |
| storage conditions | 20 °C |
| CoA / MSDS | Retrieve CoA Retrieve MSDS |
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Part of Product groups:
Product Variations:
Product | Catalog No./ CAS No. | Quantity | Price | |
|---|---|---|---|---|
 | 678143 | 1X1000MG | Please log in. | |
1,2,3-Trichlorobenzene solution 100 µg/ml Cyclohexane |  | 680362 | 1X1ML | Please log in. |
1,2,3-Trichlorobenzene solution |  | 689113 | 1X10ML | Please log in. |
1,2,3-Trichlorobenzene solution |  | 689219 | 1X5ML | Please log in. |
 | 673853 | 1X1000MG | Please log in. | |
1,2,4-Trichlorobenzene solution |  | 673856 | 1X5ML | Please log in. |
1,2,4-Trichlorobenzene solution |  | 689213 | 1X5ML | Please log in. |
 | 688811 | 1X10MG | Please log in. | |
D3-1,3,5-Trichlorobenzene solution |  | 688812 | 1X1ML |
| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 07.11.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | 1,2,4-Trichlorobenzene |
| Catalog No.: | 673856 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 2), H225 Skin irritation (Category 2), H315 Reproductive toxicity (Category 2), H361f Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 Specific target organ toxicity - repeated exposure (Category 2), H373 Aspiration hazard (Category 1), H304 Chronic aquatic toxicity (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC F Highly flammable R11 R62 Xn Harmful R48/20, R65 Xi Irritant R38 R67 N Dangerous for the environment R51/53 |
| Label elements | |
| Pictogram | flamme flamme GHS07 exclam exclam GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red |
| Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H361f Suspected of damaging fertility. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. Precautionary statement(s) P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P331 Do NOT induce vomiting. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : n-Hexane Formula : C6H14 Molecular weight : 86,18 g/mol CAS-No. : 110-54-3 EC-No. : 203-777-6 Index-No. : 601-037-00-0 Registration number : 01-2119480412-44-XXXX Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration n-Hexane CAS-No. EC-No. Index-No. 110-54-3 203-777-6 601-037-00-0 Flam. Liq. 2; Skin Irrit. 2; Repr. 2; STOT SE 3; STOT RE 2; Asp. Tox. 1; Aquatic Chronic 2; H225, H304, H315, H336, H361f, H373, H411 <= 100 % Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration n-Hexane CAS-No. EC-No. Index-No. 110-54-3 203-777-6 601-037-00-0 F, Xn, N, Repr.Cat.3, R11 - R38 - R48/20 - R62 - R65 - R67 - R51/53 <= 100 % |
| Formula | C6H3Cl3 |
| Molecular Weight (g/mol) | 181.45 |
| CAS-No. | 120-82-1 |
| FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers. |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13. |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: colourless b) Odour No data available c) Odour Threshold No data available d) pH 7,0 e) Melting point/freezing point Melting point/range: -95 °C f) Initial boiling point and boiling range 69 °C g) Flash point -26,0 °C - closed cup h) Evaporation rate 15,8 i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 7,7 %(V) Lower explosion limit: 1,2 %(V) k) Vapour pressure 341,3 hPa at 37,7 °C 176,0 hPa at 20,0 °C l) Vapour density No data available m) Relative density 0,659 g/mL at 25 °C n) Water solubility insoluble o) Partition coefficient: noctanol/ water log Pow: 3,90 - 4,11 p) Auto-ignition temperature 234,0 °C q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available |
| STABILITY AND REACTIVITY | 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. 10.5 Incompatible materials Oxidizing agents 10.6 Hazardous decomposition products Other decomposition products - No data available In the event of fire: see section 5 |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 25.000 mg/kg LC50 Inhalation - Rat - 4 h - 48000 ppm Skin corrosion/irritation Irritating to skin. Serious eye damage/eye irritation Eyes - Rabbit Result: Mild eye irritation Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Overexposure may cause reproductive disorder(s) based on tests with laboratory animals. Suspected human reproductive toxicant Suspected of damaging fertility. Specific target organ toxicity - single exposure May cause drowsiness or dizziness. Specific target organ toxicity - repeated exposure Ingestion - May cause damage to organs through prolonged or repeated exposure. - Nervous system Aspiration hazard May be fatal if swallowed and enters airways. Additional Information RTECS: MN9275000 Prolonged or repeated contact with skin may cause:, defatting, Dermatitis, Contact with eyes can cause:, Redness, Blurred vision, Provokes tears., Effects due to ingestion may include:, Gastrointestinal discomfort, Central nervous system depression, Lung irritation, chest pain, pulmonary edema, giddiness, slowed reaction time, slurred speech, Headache, Dizziness, Drowsiness, Unconsciousness |
| ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 2,5 mg/l - 96,0 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 3.878,00 mg/l - 48 h Toxicity to algae EC50 - Chlorella vulgaris (Fresh water algae) - 12.840,00 mg/l - 3 h EC50 - SKELETOMA - 0,30 mg/l - 8 h 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Toxic to aquatic life. |
| DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 1208 IMDG: 1208 IATA: 1208 14.2 UN proper shipping name ADR/RID: HEXANES IMDG: HEXANES IATA: Hexanes 14.3 Transport hazard class(es) ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: no 14.6 Special precautions for user No data available |
| REGULATORY INFORMATION | This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |