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m-Toluidine
| Item number | 680090 |
| CAS | 108-44-1 |
| Formula | C7H9N |
| Molecular weight | 107,15 g/mol |
| Quantity | 1X250MG |
| storage conditions | 20 °C |
| CoA / MSDS | Retrieve CoA Retrieve MSDS |
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Part of Product groups:
Product Variations:
Product | Catalog No./ CAS No. | Quantity | Price | |
|---|---|---|---|---|
 | 684693 | 1X50MG | Please log in. | |
 | 680090 | 1X250MG | Please log in. | |
m-Toluidine solution |  | 682071 | 1X5ML | Please log in. |
o-Toluidine solution |  | 676790 | 1X1ML | Please log in. |
o-Toluidine solution |  | 682069 | 1X5ML | Please log in. |
 | 680091 | 1X250MG | Please log in. | |
p-Toluidine solution |  | 682070 | 1X5ML | Please log in. |
| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 08.09.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | m-Toluidine |
| Catalog No.: | 680090 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Acute toxicity, Inhalation (Category 3) Acute toxicity, Dermal (Category 3) Acute toxicity, Oral (Category 3) Specific target organ toxicity - repeated exposure (Category 2) Acute aquatic toxicity (Category 1) Classification according to EU Directives 67/548/EEC or 1999/45/EC Toxic by inhalation, in contact with skin and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms. |
| Label elements | |
| Pictogram | GHS06 skull skull GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red |
| 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Danger Hazard statement(s) H301 Toxic if swallowed. H311 Toxic in contact with skin. H331 Toxic if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life Precautionary statement(s) P261 Avoid breathing vapours. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P311 Call a POISON CENTER or doctor/ physician. Supplemental Hazard Statements none According to European Directive 67/548/EEC as amended. Hazard symbol(s) R-phrase(s) R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R33 Danger of cumulative effects. R50 Very toxic to aquatic organisms. S-phrase(s) S28 After contact with skin, wash immediately with plenty of soap and water. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61 Avoid release to the environment. Refer to special instructions/ Safety data sheets. 2.3 Other hazards - none | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : 3-Methylaniline Formula : C7H9N Molecular Weight : 107,15 g/mol Component Concentration m-Toluidine CAS-No. EC-No. Index-No. 108-44-1 203-583-1 612-024-00-4 - |
| Formula | C7H9N |
| Molecular Weight (g/mol) | 107.15 |
| CAS-No. | 108-44-1 |
| FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician 4.2 Most important symptoms and effects, both acute and delayed To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated., Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. 4.3 Indication of any immediate medical attention and special treatment needed no data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx) 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 Further information Use water spray to cool unopened containers |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13 |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. 7.3 Specific end use(s) no data available |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry Hands Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: light yellow b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezing point no data available f) Initial boiling point and boiling range 203 - 204 °C - lit. g) Flash point 86 °C - closed cup h) Evaporation rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits Upper explosion limit: 6,6 %(V) Lower explosion limit: 1,1 %(V) k) Vapour pressure 67 hPa at 68 °C 1 hPa at 41 °C l) Vapour density 4,29 m) Relative density 0,999 g/cm3 at 25 °C n) Water solubility no data available o) Partition coefficient: noctanol/ water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available 9.2 Other safety information no data available |
| STABILITY AND REACTIVITY | 10.1 Reactivity no data available 10.2 Chemical stability no data available 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Acid anhydrides, Chloroformates, Strong oxidizing agents 10.6 Hazardous decomposition products Other decomposition products - no data available |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - rat - 450 mg/kg Skin corrosion/irritation Skin - rabbit - Mild skin irritation Serious eye damage/eye irritation Eyes - rabbit - Moderate eye irritation Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity This product is or contains a component that has been reported to be probably carcinogenic based on its IARC, OSHA, ACGIH, NTP, or EPA classification. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Toxic if inhaled. May cause respiratory tract irritation. Ingestion Harmful if swallowed. Skin Toxic if absorbed through skin. May cause skin irritation. Eyes Causes serious eye irritation. Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated., Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer. Additional Information RTECS: XU2800000 |
| ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to daphnia and other aquatic invertebrates LC50 - Daphnia magna (Water flea) - 0,73 mg/l - 48 h 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential no data available 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment no data available 12.6 Other adverse effects Very toxic to aquatic life |
| DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 1708 IMDG: 1708 IATA: 1708 14.2 UN proper shipping name ADR/RID: TOLUIDINES, LIQUID IMDG: TOLUIDINES, LIQUID IATA: Toluidines, liquid 14.3 Transport hazard class(es) ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: yes IMDG Marine Pollutant: yes IATA: no 14.6 Special precautions for user no data available |
| REGULATORY INFORMATION | This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture no data available 15.2 Chemical Safety Assessment no data available |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |