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Tetraethyltin

Item number677686
CAS597-64-8
FormulaC8H20Sn
Molecular weight234,95 g/mol
Quantity 1X100MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
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Tetraethyltin

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Tetraethyltin

Tetraethyltin

677686
597-64-8

1X100MG

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Tetraethyltin solution
Concentration: 1000 µg/ml
Solvent: Methanol

Tetraethyltin solution

677687
597-64-8

1X5ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 08.09.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Tetraethyltin
Catalog No.:677686
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 3), H226 Acute toxicity, Oral (Category 2), H300 Acute toxicity, Inhalation (Category 2), H330 Acute toxicity, Dermal (Category 1), H310 Acute aquatic toxicity (Category 1), H400 Chronic aquatic toxicity (Category 1), H410 Classification according to EU Directives 67/548/EEC or 1999/45/EC T+ Very toxic R26/27/28 N Dangerous for the environment R50/53
Label elements
Pictogramflamme
flamme
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger
Hazard statement(s) H226 Flammable liquid and vapour. H300 + H310 + H330 Fatal if swallowed, in contact with skin or if inhaled H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s) P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash hands thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing. P284 Wear respiratory protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician.
Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances Formula : C8H20Sn Molecular weight : 234,95 g/mol CAS-No. : 597-64-8 EC-No. : 209-906-2 Index-No. : 050-006-00-2


Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration Tetraethyltin CAS-No. EC-No. Index-No.
597-64-8 209-906-2 050-006-00-2
Flam. Liq. 3; Acute Tox. 2; Acute Tox. 1; Aquatic Acute 1; Aquatic Chronic 1; H226, H300 + H310 + H330, H410 <= 100 %
Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration Tetraethyltin CAS-No. EC-No. Index-No.
597-64-8 209-906-2 050-006-00-2
T+, N, R26/27/28 - R50/53 <= 100 %
FormulaC8H20Sn
Molecular Weight (g/mol)234.95
CAS-No.597-64-8
FIRST AID MEASURES4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Tin/tin oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510): Flammable liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Ingredients with workplace control parameters
Component CAS-No. Value Control
parameters
Basis
tetramethyltin
594-27-4
AGW 0,001 ppm
0,005 mg/m3
Germany. TRGS 900 -
Occupational exposure limit
values.
Remarks Skin absorption
8.2 Exposure controls
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,4 mm
Break through time: 480 min
Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Chloroprene
Minimum layer thickness: 0,65 mm
Break through time: 30 min
Material tested:KCL 720 Camapren®
Body Protection
Flame retardant antistatic protective clothing.
Respiratory protection
Recommended Filter type: Respirator The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Control of environmental exposure
Do not let product enter drains. Risk of explosion
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Colour: colourless b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/range: -112 °C - lit. f) Initial boiling point and boiling range 181 °C - lit. g) Flash point 53 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or No data available explosive limits k) Vapour pressure No data available l) Vapour density No data available m) Relative density 1,187 g/cm3 at 25 °C n) Water solubility No data available o) Partition coefficient: noctanol/water No data available p) Auto-ignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available
STABILITY AND REACTIVITY10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 6,25 mg/kg Remarks: Behavioral:Ataxia. Gastrointestinal:Changes in structure or function of salivary glands. Diarrhoea
LC50 Inhalation - Rat - 114 mg/m3 Remarks: Behavioral:Muscle weakness. Lungs, Thorax, or Respiration:Dyspnea. Blood: Hemorrhage.
Skin corrosion/irritation No data available Serious eye damage/eye irritation No data available Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated., General signs of toxicity for overexposure to tetraalkyl tin compounds include muscular weakness and paralysis, leading to respiratory failure, tremors, convulsive movements, closure of the eyelids, and photophobia. Histologically, tetraalkyl tin compounds show a decrease in cytoplasmic basophilia of the liver, chromatolysis of the Purkinje cells of the cerebellum, and increase in the water content of the brain and spinal cord.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 0,011 mg/l - 96,0 h
Toxicity to algae EC50 - Skeletonema costatum - 0,142 mg/l - 72 h 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Very toxic to aquatic life with long lasting effects.
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number ADR/RID: 3384 IMDG: 3384 IATA: 3384 14.2 UN proper shipping name ADR/RID: TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. (Tetraethyltin) IMDG: TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S. (Tetraethyltin) IATA: Toxic by inhalation liquid, flammable, n.o.s. (Tetraethyltin) Passenger Aircraft: Not permitted for transport Cargo Aircraft: Not permitted for transport

14.3 Transport hazard class(es) ADR/RID: 6.1 (3) IMDG: 6.1 (3) IATA: 6.1 (3) 14.4 Packaging group ADR/RID: I IMDG: I IATA: - 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No data available
15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!