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Sulfotep

Item number678224
CAS3689-24-5
FormulaC8H20O5P2S2
Molecular weight322,32 g/mol
Quantity 1X100MG
storage conditions4 °C
CoA / MSDSRetrieve CoA
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Sulfotep

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Sulfotep solution
Concentration: 100 µg/ml
Solvent: Ethyl acetate

Sulfotep solution

677926
3689-24-5

1X1ML

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Sulfotep

Sulfotep

678224
3689-24-5

1X100MG

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Sulfotep solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Sulfotep solution

678504
3689-24-5

1X1ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 15.01.2025
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Sulfotep
Catalog No.:678224
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity - Oral Category 2 - (H300)
Acute toxicity - Dermal Category 1 - (H310)
Acute toxicity - Inhalation (Dusts/Mists) Category 1 - (H330)
Acute aquatic toxicity Category 1 - (H400)
Chronic aquatic toxicity Category 1 - (H410)
Label elements
PictogramGHS06 skull
skull
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
Signal word
Danger

Hazard statements
H300 - Fatal if swallowed
H310 - Fatal in contact with skin
H330 - Fatal if inhaled
H410 - Very toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P262 - Do not get in eyes, on skin, or on clothing
P273 - Avoid release to the environment
P280 - Wear protective gloves and protective clothing
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing
P310 - Immediately call a POISON CENTER or doctor
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed

2.3. Other hazards

No information available.
This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.
This product does not contain any known or suspected endocrine disruptors.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances

Chemical name
sulfotep
Weight-%
100
REACH registration number
-
EC No (EU Index No)
222-995-2 (015-027-00-3)
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute Tox. 2 (H300)
Acute Tox. 1 (H310)
Acute Tox. 1 (H330)
Aquatic Acute 1 (H400)
Aquatic Chronic 1 (H410)

Acute Toxicity Estimate
If LD50/LC50 data is not available or does not correspond to the classification category, then the appropriate conversion value from CLP Annex I, Table 3.1.2, is used to calculate the acute toxicity estimate (ATEmix) for classifying a mixture based on its components
Oral LD50 mg/kg
5
Dermal LD50 mg/kg
5
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No. 1907/2006 (REACH), Article 59)
FormulaC8H20O5P2S2
Molecular Weight (g/mol)322.32
CAS-No.3689-24-5
FIRST AID MEASURES4.1. Description of first aid measures

General advice Immediate medical attention is required. Show this safety data sheet to the doctor in attendance.
Inhalation If breathing has stopped, give artificial respiration. Get medical attention immediately.
Remove to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If breathing is difficult, (trained personnel should) give oxygen.
Eye contact Get immediate medical attention. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing.
Skin contact Get immediate medical attention. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.
Ingestion Get immediate medical attention. Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Do not breathe vapour or mist. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Use personal protective equipment as required. See section 8 for more information.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms Coughing and/ or wheezing. Difficulty in breathing.

4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors Treat symptomatically.
FIRE-FIGHTING MEASURES5.1. Extinguishing media

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the chemical
No information available.

5.3. Advice for firefighters

Special protective equipment and precautions for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.
Use personal protection equipment.
ACCIDENTAL RELEASE MEASURES6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Do not breathe vapour
or mist. Keep people away from and upwind of spill/leak.
Other information Refer to protective measures listed in Sections 7 and 8.
For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions Prevent further leakage or spillage if safe to do so. Should not be released into the environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains.

6.3. Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

6.4. Reference to other sections

Reference to other sections See section 8 for more information. See section 13 for more information
HANDLING AND STORAGE7.1. Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Take off contaminated clothing and wash it before reuse. Do not
breathe vapour or mist. In case of insufficient ventilation, wear suitable respiratory equipment. Handle product only in closed system or provide appropriate exhaust ventilation.
Do not eat, drink or smoke when using this product.
General hygiene considerations Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Wash hands before breaks and after work. Wear suitable gloves and eye/face protection. Wash hands before breaks and immediately after handling the product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Regular cleaning of equipment, work area and clothing is recommended. Do not breathe vapour or mist. Contaminated work clothing should not be allowed out of the workplace.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Please refer to the manufacturer certificate for specific storage and transport temperature conditions. Store only in the original receptacle unless other advice is given on the CoA.
Store locked up. Keep containers tightly closed in a dry, cool and well-ventilated place.
Keep out of the reach of children.

7.3. Specific end use(s)

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters

Ingredients with workplace control parameters

8.2 Exposure controls

Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
required
Body Protection
protective clothing
Respiratory protection
required when vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.
Recommended Filter type: Filter type ABEK
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Control of environmental exposure
Do not let product enter drains.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
b) Odor No data available
c) Odor Threshold No data available
d) pH No data available
e) Melting point/freezing point
Melting point: < 25 °C
f) Initial boiling point and boiling range
136 - 139 °C at 2,66 hPa
g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid, gas)
No data available
j) Upper/lower flammability or explosive limits
No data available
k) Vapor pressure No data available
l) Vapor density No data available
m) Density No data available
Relative density No data available
n) Water solubility No data available
o) Partition coefficient: n-octanol/water
No data available
p) Autoignition temperature
No data available
q) Decomposition temperature
No data available
r) Viscosity Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
s) Explosive properties No data available
t) Oxidizing properties none

9.2 Other safety information

No data available
STABILITY AND REACTIVITY10.1. Reactivity

Reactivity No information available.

10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data
Sensitivity to mechanical impact None.
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid Excessive heat.

10.5. Incompatible materials

Incompatible materials None known based on information supplied.
Hazardous decomposition products None known based on information supplied.
TOXICOLOGICAL INFORMATION11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Information on likely routes of exposure
Product Information
Inhalation Specific test data for the substance or mixture is not available. Fatal if inhaled. (based on components).
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available. Fatal in contact with skin. (based on components).
Ingestion Specific test data for the substance or mixture is not available. Fatal if swallowed. (based on components).
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Coughing and/ or wheezing. Difficulty in breathing.
Numerical measures of toxicity
Acute toxicity
Oral LD50 = 5 mg/kg ( Rat )
Dermal LD50 = 20 mg/kg ( Rabbit )
Inhalation LC50 = 38 mg/m3 ( Rat ) 4 h

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation Based on available data, the classification criteria are not met
Serious eye damage/eye irritation No information available.
Respiratory or skin sensitisation No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Aspiration hazard No information available.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties
Endocrine disrupting properties No information available.
11.2.2. Other information
Other adverse effects No information available.
ECOLOGICAL INFORMATION12.1 Toxicity

Toxicity to daphnia and other aquaticinvertebrates
EC50 - Daphnia magna (Water flea) - 0,0025 mg/l - 48 h
Remarks: (ECOTOX Database)

12.2 Persistence and degradability

No data available

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6 Endocrine disrupting properties

Product:
Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

12.7 Other adverse effects

No data available
DISPOSAL CONSIDERATIONS13.1. Waste treatment methods

Waste from residues/unused products
Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.
Contaminated packaging Do not reuse empty containers.
TRANSPORT INFORMATIONIATA
14.1 UN number or ID number UN1704
14.2 UN proper shipping name Tetraethyl dithiopyrophosphate
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN1704, Tetraethyl dithiopyrophosphate, 6.1, II
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions A6
ERG Code 6L

IMDG
14.1 UN number or ID number UN1704
14.2 UN proper shipping name Tetraethyl dithiopyrophosphate
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN1704, Tetraethyl dithiopyrophosphate (sulfotep (ISO)), 6.1, II, Marine pollutant
14.5 Marine pollutant P
Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 43
EmS-No. F-A, S-A No information available
14.7 Maritime transport in bulk
according to IMO instruments
No information available

RID
14.1 UN number or ID number UN1704
14.2 UN proper shipping name Tetraethyl dithiopyrophosphate
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN1704, Tetraethyl dithiopyrophosphate, 6.1, II, Environmentally Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 43
Classification code T1

ADR
14.1 UN number or ID number UN1704
14.2 UN proper shipping name Tetraethyl dithiopyrophosphate
14.3 Transport hazard class(es) 6.1
14.4 Packing group II
Description UN1704, Tetraethyl dithiopyrophosphate, 6.1, II, (D/E), Environmentally Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 43
Classification code T1
Tunnel restriction code (D/E)
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
National legislation
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances.
: ACUTE TOXIC
: ENVIRONMENTAL HAZARDS

Other regulations
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable.
Take note of Dir 94/33/EC on the protection of young people at work.

15.2 Chemical Safety Assessment

For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!