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Piperonyl butoxide

Item number	674844
CAS	51-03-6
Formula	C19H30O5
Molecular weight	338,44 g/mol
Quantity	1X100MG
storage conditions	20 °C
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Piperonyl butoxide		674844 51-03-6	1X100MG	Please log in.

Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 02.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	Piperonyl butoxide
Catalog No.:	674844
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com
Emergency telephone number	HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours.
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Short-term (acute) aquatic hazard (Category 1), H400 Long-term (chronic) aquatic hazard (Category 1), H410
Label elements
Pictogram	GHS09 Aquatic-pollut-red Aquatic-pollut-red
	2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Signal Word Warning Hazard statement(s) H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P273 Avoid release to the environment. P391 Collect spillage. P501 Dispose of contents/ container to an approved waste disposal plant. Supplemental Hazard Statements none Reduced Labeling (<= 125 ml) Signal Word Warning Hazard statement(s) none Precautionary statement(s) none Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS	3.1 Substances Component: 5-{[2-(2-Butoxyethoxy)ethoxy]methyl}-6-propyl-1,3-benzodioxole CAS-No. : 51-03-6 EC-No. : 200-076-7 Classification: Aquatic Acute 1; Aquatic Chronic 1; H400, H410 M-Factor - Aquatic Acute: 10 Concentration: <= 100 %
Formula	C19H30O5
Molecular Weight (g/mol)	338.44
CAS-No.	51-03-6
FIRST AID MEASURES	4.1 Description of first-aid measures If inhaled After inhalation: fresh air. In case of skin contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. In case of eye contact After eye contact: rinse out with plenty of water. Remove contact lenses. If swallowed After swallowing: make victim drink water (two glasses at most). Consult doctor if feeling unwell. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES	5.1 Extinguishing media Suitable extinguishing media Water Foam Carbon dioxide (CO2) Dry powder Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. 5.2 Special hazards arising from the substance or mixture Carbon oxides Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire. 5.3 Advice for firefighters In the event of fire, wear self-contained breathing apparatus. 5.4 Further information Prevent fire extinguishing water from contaminating surface water or the ground water system.
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. 6.2 Environmental precautions Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE	7.1 Precautions for safe handling For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Storage conditions Tightly closed. Storage stability Recommended storage temperature 2 - 8 °C Storage class Storage class (TRGS 510): 10: Combustible liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION	8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Personal protective equipment Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses Respiratory protection Recommended Filter type: Filter A-(P2) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. Control of environmental exposure Do not let product enter drains.
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties a) Physical state liquid b) Color light yellow c) Odor No data available d) Melting point/freezing point Melting point/range: < -20 °C - OECD Test Guideline 102 e) Initial boiling point and boiling range 180 °C at 1 hPa f) Flammability (solid, gas) No data available g) Upper/lower flammability or explosive limits No data available h) Flash point 171 °C - closed cup i) Autoignition temperature 265 °C at 1.010 hPa j) Decomposition temperature No data available k) pH No data available l) Viscosity Viscosity, kinematic: No data available Viscosity, dynamic: 28,7 mPa.s at 20 °C m) Water solubility 0,0289 g/l at 20,4 °C - OECD Test Guideline 105- slightly soluble n) Partition coefficient: n-octanol/water log Pow: 4,8 at 20 °C o) Vapor pressure No data available p) Density 1,059 g/cm3 Relative density 1,058 at 20 °C q) Relative vapor density r) Particle characteristics No data available s) Explosive properties Not explosive t) Oxidizing properties The product has been shown not to be oxidizing in a test following Directive 67/548/EEC (Method A17, oxidizing properties). 9.2 Other safety information Surface tension 35,79 mN/m at 25 °C
STABILITY AND REACTIVITY	10.1 Reactivity Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. 10.2 Chemical stability The product is chemically stable under standard ambient conditions (room temperature) . 10.3 Possibility of hazardous reactions Violent reactions possible with: Strong oxidizing agents 10.4 Conditions to avoid Strong heating. 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - male and female - 5.630 mg/kg (OECD Test Guideline 401) LC50 Inhalation - Rat - male and female - 4 h - > 5,9 mg/l LD50 Dermal - Rabbit - male and female - > 2.000 mg/kg (OECD Test Guideline 402) Skin corrosion/irritation Skin - Rabbit Result: No skin irritation - 4 h (OECD Test Guideline 404) Serious eye damage/eye irritation Eyes - Rabbit Result: No eye irritation - 168 h (OECD Test Guideline 405) Respiratory or skin sensitization Buehler Test - Guinea pig Result: Does not cause skin sensitization. Germ cell mutagenicity Test Type: Ames test Test system: S. typhimurium Metabolic activation: with and without metabolic activation Result: negative Test Type: In vivo micronucleus test Species: Mouse Application Route: Oral Result: negative Carcinogenicity No data available Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available 11.2 Additional Information Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - NOAEL (No observed adverse effect level) - 125 mg/kg - LOAEL (Lowest observed adverse effect level) - 250 mg/kg RTECS: XS8050000 Vomiting, Diarrhea, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
ECOLOGICAL INFORMATION	12.1 Toxicity Toxicity to fish: flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - ca. 6,12 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates: flow-through test EC50 - Daphnia magna (Water flea) - ca. 0,05 mg/l - 48 h (OECD Test Guideline 202) Toxicity to algae: Growth inhibition ErC50 - Pseudokirchneriella subcapitata (algae) - ca. 3,89 mg/l - 72 h (OECD Test Guideline 201) Toxicity to bacteria: EC50 - Sludge Treatment - > 1.000 mg/l - 3 h (OECD Test Guideline 209) Toxicity to fish(Chronic toxicity): NOEC - Pimephales promelas (fathead minnow) - 0,18 mg/l - 35 d Toxicity to daphnia and other aquatic invertebrates(Chronic toxicity) NOEC - Daphnia magna (Water flea) - 0,03 mg/l - 21 d 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 28 d Result: 24 - 48 % - Not readily biodegradable. (OECD Test Guideline 301B) 12.3 Bioaccumulative potential Bioaccumulation Lepomis macrochirus - 28 d (5-{[2-(2-Butoxyethoxy)ethoxy]methyl}-6-propyl-1,3-benzodioxole) Bioconcentration factor (BCF): 91 - 380 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. 12.7 Other adverse effects No data available
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods No data available
TRANSPORT INFORMATION	14.1 UN number ADR/RID: 3082 IMDG: 3082 IATA: 3082 14.2 UN proper shipping name ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (5-{[2-(2- Butoxyethoxy)ethoxy]methyl}-6-propyl-1,3-benzodioxole) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (5-{[2-(2- Butoxyethoxy)ethoxy]methyl}-6-propyl-1,3-benzodioxole) IATA: Environmentally hazardous substance, liquid, n.o.s. (5-{[2-(2- Butoxyethoxy)ethoxy]methyl}-6-propyl-1,3-benzodioxole) 14.3 Transport hazard class(es) ADR/RID: 9 IMDG: 9 IATA: 9 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: yes 14.6 Special precautions for user Tunnel restriction code : (-) Further information Packages smaller than or equal to 5 kg / L , not dangerous goods of Class 9
REGULATORY INFORMATION	15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. National legislation Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ENVIRONMENTAL HAZARDS Other regulations Take note of Dir 94/33/EC on the protection of young people at work. 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!