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Phenthoate

Item number676876
CAS2597-03-7
FormulaC12H17O4PS2
Molecular weight320,36 g/mol
Quantity 1X100MG
storage conditions4 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
Phenthoate

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Phenthoate solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Phenthoate solution

673409
2597-03-7

1X5ML

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Phenthoate

Phenthoate

676876
2597-03-7

1X100MG

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 29.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Phenthoate
Catalog No.:676876
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS09 environment
Aquatic Acute 1 H400 Very toxic to aquatic life.
Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H312 Harmful in contact with skin.
Label elements
PictogramGHS07 exclam
exclam
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS07 GHS09
· Signal word Warning
· Hazard statements
H302+H312 Harmful if swallowed or in contact with skin.
H410 Very toxic to aquatic life with long lasting effects.
· Precautionary statements
P264 Wash thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves / protective clothing.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P321 Specific treatment (see on this label).
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Chemical characterisation: Substances
· CAS No. Description
2597-03-7 phenthoate (ISO)
· Identification number(s) None
· EC number: 219-997-0
· Index number: 015-097-00-5
· RTECS: AI 7875000
FormulaC12H17O4PS2
Molecular Weight (g/mol)320.36
CAS-No.2597-03-7
FIRST AID MEASURES4.1 Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48
hours after the accident is recommended.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Seek medical treatment.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing:
Rinse mouth. Do not induce vomiting.
Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
FIRE-FIGHTING MEASURES5.1 Extinguishing media
· Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.
5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
5.3 Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing.
6.2 Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
HANDLING AND STORAGE7.1 Precautions for safe handling Store in cool, dry place in tightly closed receptacles.
· Information about fire - and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturers certificate for specific storage and transport temperature conditions.
Store only in the original receptacle.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions: None.
7.3 Specific end use(s) No further relevant information available.
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace: Not required.
· Additional information: Lists used were valid at the time of SDS preparation.
8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection: Not required.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Butyl rubber, BR
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection: Safety glasses
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Colour: Yellowish
· Odour: Odourless
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/freezing point: 17.5 °C
Initial boiling point and boiling range: Not determined.
· Flash point: 165-170 °C
· Flammability (solid, gas): Not determined.
· Ignition temperature: Not determined
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Not determined.
· Explosive properties: Not determined.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapour pressure: Not determined.
· Density at 20 °C: 1.226 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water at 24 °C: 0.011 g/l
· Partition coefficient: n-octanol/water: 3.69 logP
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
9.2 Other information No further relevant information available.
STABILITY AND REACTIVITY10.1 Reactivity Stable under normal conditions.
10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:
Formation of toxic gases is possible during heating or in case of fire.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid Heat.
10.5 Incompatible materials: Strong oxidizing agents.
10.6 Hazardous decomposition products:
Formation of toxic gases is possible during heating or in case of fire.
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
· Acute toxicity
Harmful if swallowed or in contact with skin.
· LD/LC50 values relevant for classification:
Oral LD50 71 mg/kg (rat)
Dermal LD50 700 mg/kg (rat)
Inhalative (LC50/4h) 0.059 mg/l (rat)
· Primary irritant effect:
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
ECOLOGICAL INFORMATION12.1 Toxicity
· Aquatic toxicity:
LC50/96 h 0.005 mg/l (fish)
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
· Ecotoxicological effects:
· Remark: Very toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogue
Waste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:
· Recommendation: Dispose of in accordance with national regulations.
TRANSPORT INFORMATION14.1 UN-Number
· ADR, IMDG, IATA UN2810
· ADR 2810 TOXIC LIQUID, ORGANIC, N.O.S. (phenthoate
(ISO)), ENVIRONMENTALLY HAZARDOUS
· IMDG TOXIC LIQUID, ORGANIC, N.O.S. (phenthoate (ISO)),
MARINE POLLUTANT
· IATA TOXIC LIQUID, ORGANIC, N.O.S. (phenthoate (ISO))
14.3 Transport hazard class(es)
· ADR, IMDG
· Class 6.1 Toxic substances.
· Label 6.1
· IATA
· Class 6.1 Toxic substances.
· Label 6.1
14.4 Packing group
· ADR, IMDG, IATA I
14.5 Environmental hazards: Environmentally hazardous substance, liquid; Marine
Pollutant
· Marine pollutant: Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
14.6 Special precautions for user Warning: Toxic substances.
· Danger code (Kemler): 66
· EMS Number: F-A,S-A
· Stowage Category A
· Stowage Code SW2 Clear of living quarters.
14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 0
· Excepted quantities (EQ) Code: E5
Maximum net quantity per inner packaging: 1 ml
Maximum net quantity per outer packaging: 300 ml
· Transport category 1
· Tunnel restriction code C/E
· UN "Model Regulation": UN 2 8 1 0 TOXIC LIQUID, ORGANIC, N.O.S .
(PHENTHOATE (ISO)), 6.1, I, ENVIRONMENTALLY
HAZARDOUS
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Philippines Inventory of Chemicals and Chemical Substances Substance is not listed.
· Australian Inventory of Chemical Substances Substance is not listed.
· Standard for the Uniform Scheduling of Medicines and Poisons Substance is not listed.
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I Substance is not listed.
· Seveso category E1 Hazardous to the Aquatic Environment
· Qualifying quantity (tonnes) for the application of lower-tier requirements 100 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!