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Octylamine

Item number687307
CAS111-86-4
FormulaC8H19N
Molecular weight129,24 g/mol
Quantity 1X1ML
storage conditions4 °C
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Octylamine

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Octylamine

Octylamine

687307
111-86-4

1X1ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 08.09.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Octylamine
Catalog No.:687307
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 3), H226
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 4), H332
Acute toxicity, Dermal (Category 3), H311
Skin corrosion (Sub-category 1A), H314
Serious eye damage (Category 1), H318
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Short-term (acute) aquatic hazard (Category 1), H400
Long-term (chronic) aquatic hazard (Category 2), H411
Label elements
Pictogramflamme
flamme
GHS05 acid
acid
GHS06 skull
skull
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Signal Word Danger
Hazard statement(s)
H226 Flammable liquid and vapor.
H301 + H311 Toxic if swallowed or in contact with skin.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Supplemental Hazard Statements none
Reduced Labeling (<= 125 ml)
Signal Word Danger
Hazard statement(s)
H314 Causes severe skin burns and eye damage.
H301 + H311 Toxic if swallowed or in contact with skin.
Precautionary statement(s)
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Supplemental Hazard Statements none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : 1-Aminooctane
Caprylamine
n-Octylamine
EC-No. 203-916-0
Component: Octylamine
EC-No.: 203-916-0
Classification: Flam. Liq. 3; Acute Tox. 3;
Acute Tox. 4; Acute Tox.
3; Skin Corr. 1A; Eye
Dam. 1; STOT SE 3;
Aquatic Acute 1; Aquatic
Chronic 2; H226, H301,
H332, H311, H314, H318,
H335, H400, H411
M-Factor - Aquatic Acute: 1
Concentration: <= 100 %
FormulaC8H19N
Molecular Weight (g/mol)129.24
CAS-No.111-86-4
FIRST AID MEASURES4.1 Description of first-aid measures
General advice
First aiders need to protect themselves. Show this material safety data sheet to the doctor
in attendance.
If inhaled
After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately
apply artificial respiration, if necessary also oxygen.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower. Call a physician immediately.
In case of eye contact
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist.
Remove contact lenses.
If swallowed
If swallowed: give water to drink (two glasses at most). Seek medical advice immediately.
In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal
(20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Carbon dioxide (CO2) Foam Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
Nitrogen oxides (NOx)
Combustible.
Vapors are heavier than air and may spread along floors.
Forms explosive mixtures with air at elevated temperatures.
Development of hazardous combustion gases or vapours possible in the event of fire.
5.3 Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by
keeping a safe distance or by wearing suitable protective clothing.
5.4 Further information
Remove container from danger zone and cool with water. Suppress (knock down)
gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from
contaminating surface water or the ground water system.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance
contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains. Risk of explosion.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g.
Chemizorb®). Dispose of properly. Clean up affected area.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Advice on safe handling
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Advice on protection against fire and explosion
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary
measures against static discharge.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands
and face after working with substance.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and
sources of ignition. Keep locked up or in an area accessible only to qualified or authorized
persons.
Storage class
Storage class (TRGS 510): 3: Flammable liquids
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Ingredients with workplace control parameters
8.2 Exposure controls
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety
goggles
Skin protection
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use.
Body Protection
Flame retardant antistatic protective clothing.
Respiratory protection
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic
compounds
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Control of environmental exposure
Do not let product enter drains. Risk of explosion.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Physical state clear, liquid
b) Color colorless
c) Odor No data available
d) Melting
point/freezing point
Melting point/range: -5 - -1 °C - lit.
e) Initial boiling point
and boiling range
175 - 177 °C - lit.
f) Flammability (solid,
gas)
No data available
g) Upper/lower
flammability or
explosive limits
Upper explosion limit: 8,2 %(V)
Lower explosion limit: 1,6 %(V)
h) Flash point 60 °C - closed cup
i) Autoignition
temperature
275 °C
at 1.019 hPa
j) Decomposition
temperature
No data available
k) pH 11,8 at 25 °C
- DIN 19268
l) Viscosity Viscosity, kinematic: No data available
Viscosity, dynamic: 1,371 mPa.s at 20 °C - ASTM D 445
m) Water solubility 0,32 g/l at 20 °C - partly soluble
n) Partition coefficient:
n-octanol/water
log Pow: 2,9
o) Vapor pressure 0,81 hPa at 20 °C
p) Density 0,782 g/cm3 at 25 °C - lit.
Relative density No data available
q) Relative vapor
density
No data available
r) Particle
characteristics
No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
Surface tension 44,2 mN/m at 20 °C
STABILITY AND REACTIVITY10.1 Reactivity
Vapor/air-mixtures are explosive at intense warming.
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.3 Possibility of hazardous reactions
Exothermic reaction with:
Acids
Caution! In contact with nitrites, nitrates, nitrous acid possible liberation of nitrosamines!
10.4 Conditions to avoid
Heating.
10.5 Incompatible materials
Metals
10.6 Hazardous decomposition products
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male and female - < 200 mg/kg
(OECD Test Guideline 401)
LC50 Inhalation - Rat - male and female - 4 h - 1,6 mg/l - aerosol
(OECD Test Guideline 403)
LD50 Dermal - Rabbit - > 200 - < 2.000 mg/kg
LD50 Intraperitoneal - Mouse - 100 mg/kg
LD50 Intravenous - Mouse - 18 mg/kg
Skin corrosion/irritation
Skin - Rabbit
Result: Causes severe burns.
(OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Corrosive to eyes - 24 h
(OECD Test Guideline 405)
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Species: Mouse
Method: OECD Test Guideline 474
Result: negative
Carcinogenicity
No data available
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Additional Information
Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain
components considered to have endocrine
disrupting properties according to REACH Article
57(f) or Commission Delegated regulation (EU)
2017/2100 or Commission Regulation (EU)
2018/605 at levels of 0.1% or higher.
RTECS: RG8050000
burning sensation, Cough, wheezing, laryngitis, Shortness of breath, spasm, inflammation
and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis,
pulmonary edema, Material is extremely destructive to tissue of the mucous membranes
and upper respiratory tract, eyes, and skin., To the best of our knowledge, the chemical,
physical, and toxicological properties have not been thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish flow-through test LC50 - Pimephales promelas (fathead minnow) - 5,19 mg/l - 96 h
(OECD Test Guideline 203)
Toxicity to daphnia
and other aquatic
invertebrates
semi-static test EC50 - Daphnia magna (Water flea) - 1,9 mg/l - 48
h
Toxicity to algae static test EC50 - Desmodesmus subspicatus (green algae) - 0,23
mg/l - 72 h
(Tested according to Directive 92/69/EEC.)
Toxicity to
fish(Chronic toxicity)
Remarks: No data available
(Octylamine)
12.2 Persistence and degradability
Biodegradability Result: 97 % - Readily biodegradable.
12.3 Bioaccumulative potential
Does not bioaccumulate.
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
12.6 Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties
according to REACH Article 57(f) or Commission
Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.
12.7 Other adverse effects
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 2734 IMDG: 2734 IATA: 2734
14.2 UN proper shipping name
ADR/RID: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (Octylamine) (Octylamine)
IMDG: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (Octylamine) (Octylamine)
IATA: Amines, liquid, corrosive, flammable, n.o.s. (Octylamine) (Octylamine)
14.3 Transport hazard class(es)
ADR/RID: 8 (3) IMDG: 8 (3) IATA: 8 (3)
14.4 Packaging group
ADR/RID: I IMDG: I IATA: I
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: no
14.6 Special precautions for user
Tunnel restriction code : (D/E)
Further information : No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.
National legislation
Seveso III: Directive 2012/18/EU of the European
Parliament and of the Council on the control of
major-accident hazards involving dangerous
substances.
: ENVIRONMENTAL HAZARDS
: FLAMMABLE LIQUIDS
Other regulations
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or
stricter national regulations where applicable.
Take note of Dir 94/33/EC on the protection of young people at work.
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!