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Nitrothal-isopropyl

ISO 17034 Certified Reference Material

Item number691087
CAS10552-74-6
FormulaC14H17NO6
Molecular weight295,29 g/mol
Quantity 1X50MG
storage conditions4 °C
CoA / MSDSRetrieve CoA
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Nitrothal-isopropyl

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Nitrothal-isopropyl solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Nitrothal-isopropyl solution

678446
10552-74-6

1X5ML

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ISO 17034 Reference Material

Nitrothal-isopropyl

Nitrothal-isopropyl

681037
10552-74-6

1X100MG

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ISO 17034 Certified Reference Material

Nitrothal-isopropyl

Nitrothal-isopropyl

691087
10552-74-6

1X50MG

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 28.11.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Nitrothal-isopropyl
Catalog No.:691087
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1. Classification of the substance or mixture

Regulation (EC) No 1272/2008
Acute aquatic toxicity Category 1 - (H400)
Chronic aquatic toxicity Category 1 - (H410)
Label elements
PictogramGHS09 Aquatic-pollut-red
Aquatic-pollut-red
Signal word
Warning

Hazard statements
H410 - Very toxic to aquatic life with long lasting effects

Precautionary Statements - EU (§28, 1272/2008)
P273 - Avoid release to the environment
P391 - Collect spillage
P501 - Dispose of contents/ container to an approved waste disposal plant

2.3. Other hazards

This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances

Chemical name
Nitrothal-isopropyl
Weight-%
100
EC No
234-139-5
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Aquatic Acute 1 (H400)
Aquatic Chronic 1 (H410)

Acute Toxicity Estimate
If LD50/LC50 data is not available or does not correspond to the classification category, then the appropriate conversion
value from CLP Annex I, Table 3.1.2, is used to calculate the acute toxicity estimate (ATEmix) for classifying a mixture based on its components

Oral LD50
mg/kg
6400

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No. 1907/2006 (REACH), Article 59)
FormulaC14H17NO6
Molecular Weight (g/mol)295.29
CAS-No.10552-74-6
FIRST AID MEASURES4.1. Description of first aid measures

Inhalation
Remove to fresh air.
Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a doctor.
Skin contact
Wash skin with soap and water. In the case of skin irritation or allergic reactions see a doctor.
Ingestion
Rinse mouth.

4.2. Most important symptoms and effects, both acute and delayed Symptoms

No information available.

4.3. Indication of any immediate medical attention and special treatment needed

Note to doctors
Treat symptomatically.
FIRE-FIGHTING MEASURES5.1. Extinguishing media

Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Large Fire
CAUTION: Use of water spray when fighting fire may be inefficient.
Unsuitable extinguishing media
Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the chemical
No information available.

5.3. Advice for firefighters

Special protective equipment and precautions for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment.
ACCIDENTAL RELEASE MEASURES6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions
Ensure adequate ventilation.
For emergency responders
Use personal protection recommended in Section 8.

6.2. Environmental precautions

Environmental precautions
See Section 12 for additional Ecological Information.

6.3. Methods and material for containment and cleaning up

Methods for containment
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.

6.4. Reference to other sections

Reference to other sections
See section 8 for more information. See section 13 for more information.
HANDLING AND STORAGE7.1. Precautions for safe handling

Advice on safe handling Ensure adequate ventilation.
General hygiene considerations Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this
product. Wash hands before breaks and after work. Wear suitable gloves and eye/face protection.

7.2. Conditions for safe storage, including any incompatibilities

Storage Conditions Please refer to the manufacturer certificate for specific storage and transport temperature
conditions. Store only in the original receptacle unless other advice is given on the CoA.

7.3. Specific end use(s)

Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1. Control parameters

Exposure Limits
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits
This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies
Derived No Effect Level (DNEL)
No information available.
Predicted No Effect Concentration (PNEC)
No information available.

8.2. Exposure controls

Personal protective equipment
Eye/face protection
Avoid contact with eyes. Wear safety glasses with side shields (or goggles).
Hand protection
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374. Wear protective nitrile rubber gloves.
Skin and body protection
Wear suitable protective clothing.
Respiratory protection
No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations
Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Wash hands before breaks and after work. Wear suitable gloves and eye/face protection.
Environmental exposure controls
Do not allow into any sewer, on the ground or into any body of water.
PHYSICAL AND CHEMICAL PROPERTIES9.1. Information on basic physical and chemical properties

Physical state Solid
Appearance Crystalline
Colour yellow
Odour Slight.
Odour threshold No information available

Property Values Remarks / Method
Melting point / freezing point 65 °C None known
Boiling point / boiling range No data available None known
Flammability (solid, gas) No data available None known
Flammability Limit in Air None known
Upper flammability or explosive
limits
No data available
Lower flammability or explosive
limits
No data available
Flash point 400 °C None known
Autoignition temperature No data available None known
Decomposition temperature None known
pH No data available None known
pH (as aqueous solution) No data available No information available
Kinematic viscosity No data available None known
Dynamic viscosity No data available None known
Water solubility 2.7 mg/l None known
Solubility(ies) Ethanol None known
Partition coefficient 3.1 None known
Vapour pressure 0.01 mPa @ 20 °C None known
Relative density 1.21 None known
Bulk density No data available
Liquid Density No data available
Relative vapour density No data available None known
Particle characteristics
Particle Size No information available
Particle Size Distribution No information available

9.2. Other information

Molecular weight 295.29
Molecular formula C14 H17 N O6

9.2.1. Information with regards to physical hazard classes
Not applicable
9.2.2. Other safety characteristics
No information available
STABILITY AND REACTIVITY10.1. Reactivity

Reactivity No information available.

10.2. Chemical stability

Stability Stable under normal conditions.
Explosion data
Sensitivity to mechanical impact None.
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions

Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid None known based on information supplied.

10.5. Incompatible materials

Incompatible materials None known based on information supplied.
Hazardous decomposition products None known based on information supplied.
TOXICOLOGICAL INFORMATION11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Information on likely routes of exposure
Product Information
Inhalation Specific test data for the substance or mixture is not available.
Eye contact Specific test data for the substance or mixture is not available.
Skin contact Specific test data for the substance or mixture is not available.
Ingestion Specific test data for the substance or mixture is not available.
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms No information available.
Numerical measures of toxicity
Acute toxicity
Oral LD50
> 6400 mg/kg ( Rat )
Dermal LD50
> 2500 mg/kg (rat)
> 4000 mg/kg (rabbit)
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation No information available.
Serious eye damage/eye irritation No information available.
Respiratory or skin sensitisation No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT - single exposure No information available.
STOT - repeated exposure No information available.
Aspiration hazard No information available.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties
Endocrine disrupting properties No information available.
11.2.2. Other information
Other adverse effects No information available.
ECOLOGICAL INFORMATION12.1. Toxicity

Ecotoxicity Very toxic to aquatic life with long lasting effects.
Algae/aquatic plants
EC50: 1.72 mg/l (Algae,72h)
Fish
LC50: 0.56 mg/l (Oncorhynchus mykiss, 96h)
Toxicity to microorganisms
-
Crustacea
EC50: 2.84 mg/l (daphnia magna, 48h)

12.2. Persistence and degradability

Persistence and degradability No information available.

12.3. Bioaccumulative potential

Bioaccumulation There is no data for this product

12.4. Mobility in soil

Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment The product does not contain any substance(s) classified as PBT or vPvB.

12.6. Endocrine disrupting properties

Endocrine disrupting properties No information available.

12.7. Other adverse effects

No information available.
DISPOSAL CONSIDERATIONS13.1. Waste treatment methods

Waste from residues/unused products
Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.
Contaminated packaging
Do not reuse empty containers.
TRANSPORT INFORMATIONIATA
14.1 UN number or ID number UN3077
14.2 UN proper shipping name Environmentally hazardous substances, solid, n.o.s. (Nitrothal-isopropyl)
14.3 Transport hazard class(es) 9
14.4 Packing group III
Description UN3077, Environmentally hazardous substances, solid, n.o.s. (Nitrothal-isopropyl), 9, III
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions A97, A158, A179, A197, A215
ERG Code 9L

IMDG
14.1 UN number or ID number UN3077
14.2 UN proper shipping name Environmentally hazardous substances, solid, n.o.s. (Nitrothal-isopropyl)
14.3 Transport hazard class(es) 9
14.4 Packing group III
Description UN3077, Environmentally hazardous substances, solid, n.o.s. (Nitrothal-isopropyl), 9, III,
Marine pollutant
14.5 Marine pollutant P
Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 335, 966, 967, 969
EmS-No F-A, S-F No information available
14.7 Maritime transport in bulk
according to IMO instruments
No information available

RID
14.1 UN number or ID number UN3077
14.2 UN proper shipping name Environmentally hazardous substances, solid, n.o.s. (Nitrothal-isopropyl)
14.3 Transport hazard class(es) 9
14.4 Packing group III
Description UN3077, Environmentally hazardous substances, solid, n.o.s. (Nitrothal-isopropyl), 9, III
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 335, 375, 601
Classification code M7

ADR
14.1 UN number or ID number UN3077
14.2 UN proper shipping name Environmentally hazardous substances, solid, n.o.s. (Nitrothal-isopropyl)
14.3 Transport hazard class(es) 9
14.4 Packing group III
Description UN3077, Environmentally hazardous substances, solid, n.o.s. (Nitrothal-isopropyl), 9, III, (-)
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 335, 601, 375
Classification code M7
Tunnel restriction code (-)
REGULATORY INFORMATION15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations
Germany
Water hazard class (WGK) obviously hazardous to water (WGK 2)
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work.
Authorisations and/or restrictions on use:
This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII) DIRECTIVE (EU) 2021/1187 on the marketing and use of explosives precursors
Not applicable
Persistent Organic Pollutants
Not applicable
Dangerous substance category per Seveso Directive (2012/18/EU)
E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1
Ozone-depleting substances (ODS) regulation (EC) 1005/2009
Not applicable
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!