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Iodomethane (stabilized with Copper chip)
| Item number | 691040 |
| CAS | 74-88-4 |
| Formula | CH3I |
| Molecular weight | 141,94 g/mol |
| Quantity | 1X1G |
| storage conditions | 4 °C |
| CoA / MSDS | Retrieve CoA Retrieve MSDS |
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Product Variations:
Product | Catalog No./ CAS No. | Quantity | Price | |
|---|---|---|---|---|
 | 691040 | 1X1G | Please log in. |
| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 08.09.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | Iodomethane (stabilized with Copper chip) |
| Catalog No.: | 691040 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 3), H226 Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 3), H331 Acute toxicity, Dermal (Category 4), H312 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Carcinogenicity (Category 2), H351 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Short-term (acute) aquatic hazard (Category 1), H400 Long-term (chronic) aquatic hazard (Category 2), H411 For the full text of the H-Statements mentioned in this Section, see Section 16. |
| Label elements | |
| Pictogram | flamme flamme GHS06 skull skull GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red |
| 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal Word Danger Hazard statement(s) H226 Flammable liquid and vapor. H301 + H331 Toxic if swallowed or if inhaled. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. Supplemental Hazard Statements none Reduced Labeling (<= 125 ml) Pictogram Signal Word Danger Hazard statement(s) H351 Suspected of causing cancer. H301 + H331 Toxic if swallowed or if inhaled. Precautionary statement(s) P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Vesicant., Rapidly absorbed through skin. | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : Methyl iodide Formula : CH3I Molecular weight : 141,94 g/mol CAS-No. : 74-88-4 EC-No. : 200-819-5 Index-No. : 602-005-00-9 Component iodomethane CAS-No. EC-No. Index-No. 74-88-4 200-819-5 602-005-00-9 Classification Flam. Liq. 3; Acute Tox. 3; Acute Tox. 4; Skin Irrit. 2; Eye Irrit. 2; Carc. 2; STOT SE 3; Aquatic Acute 1; Aquatic Chronic 2; H226, H301, H331, H312, H315, H319, H351, H335, H400, H411 M-Factor - Aquatic Acute: 1 Concentration >= 90 - <= 100 % For the full text of the H-Statements mentioned in this Section, see Section 16. |
| Formula | CH3I |
| Molecular Weight (g/mol) | 141.94 |
| CAS-No. | 74-88-4 |
| FIRST AID MEASURES | 4.1 Description of first-aid measures General advice First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. If inhaled After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. In case of skin contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. In case of eye contact After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. If swallowed If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. 5.2 Special hazards arising from the substance or mixture Carbon oxides Hydrogen iodide Not combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Ambient fire may liberate hazardous vapours. 5.3 Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. 5.4 Further information Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. 6.2 Environmental precautions Do not let product enter drains. Risk of explosion. 6.3 Methods and materials for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. 6.4 Reference to other sections For disposal see section 13. |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Advice on safe handling Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. Advice on protection against fire and explosion Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Storage conditions Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons. Storage stability Recommended storage temperature 2 - 8 °C Light sensitive. Moisture sensitive. Storage class Storage class (TRGS 510): 3: Flammable liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Personal protective equipment Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses Body Protection Flame retardant antistatic protective clothing. Respiratory protection required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type AX The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. Control of environmental exposure Do not let product enter drains. Risk of explosion |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Physical state liquid b) Color No data available c) Odor No data available d) Melting point/freezing point Melting point/range: -64 °C - lit. e) Initial boiling point and boiling range 41 - 43 °C - lit. f) Flammability (solid, gas) No data available g) Upper/lower flammability or explosive limits Upper explosion limit: 66 %(V) Lower explosion limit: 8,5 %(V) h) Flash point ca.32,1 °C at ca.998,1 hPa - closed cup - Regulation (EC) No. 440/2008, Annex, A.9 i) Autoignition temperature 350 °C at 994,10 hPa j) Decomposition temperature No data available k) pH 6,3 at 21,1 °C l) Viscosity Viscosity, kinematic: 0,23 mm2/s at 10 °C - OPPTS 830.71000,2 mm2/s at 30 °C - OPPTS 830.7100 Viscosity, dynamic: 0,45 mPa.s at 30 °C - OPPTS 830.71000,53 mPa.s at 10 °C - OPPTS 830.7100 m) Water solubility 8,66 g/l at 20 °C - OECD Test Guideline 105 n) Partition coefficient: n-octanol/water log Pow: 1,57 at 20 °C - Bioaccumulation is not expected. o) Vapor pressure 544 hPa at 20 °C 1.660 hPa at 55 °C p) Density 2,28 g/cm3 at 25 °C - lit. Relative density 2,27 at 25 °C q) Relative vapor density 4,90 - (Air = 1.0) r) Particle No data available characteristics s) Explosive properties No data available t) Oxidizing properties none 9.2 Other safety information Relative vapor density 4,90 - (Air = 1.0) |
| STABILITY AND REACTIVITY | 10.1 Reactivity Vapor/air-mixtures are explosive at intense warming. 10.2 Chemical stability The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): Copper(bulk) (>=0 - <=00,3 %) 10.3 Possibility of hazardous reactions Risk of explosion with: phosphines sodium strong alkalis Potassium Calcium Oxygen Exothermic reaction with: Strong oxidizing agents Reducing agents Chlorites 10.4 Conditions to avoid Heating. 10.5 Incompatible materials No data available 10.6 Hazardous decomposition products In the event of fire: see section 5 |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity Oral: No data available Inhalation: No data available Dermal: No data available Skin corrosion/irritation No data available Serious eye damage/eye irritation No data available Respiratory or skin sensitization No data available Germ cell mutagenicity No data available Carcinogenicity No data available Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available 11.2 Additional Information Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. No data available |
| ECOLOGICAL INFORMATION | 12.1 Toxicity No data available 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Endocrine disrupting properties Product: Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. 12.7 Other adverse effects No data available |
| DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 2644 IMDG: 2644 IATA: 2644 14.2 UN proper shipping name ADR/RID: METHYL IODIDE IMDG: METHYL IODIDE IATA: Methyl iodide Passenger Aircraft: Not permitted for transport Cargo Aircraft: Not permitted for transport 14.3 Transport hazard class(es) ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1 14.4 Packaging group ADR/RID: I IMDG: I IATA: - 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user Tunnel restriction code : (C/D) Further information : No data available |
| REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. National legislation Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ACUTE TOXIC : ENVIRONMENTAL HAZARDS : FLAMMABLE LIQUIDS Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |