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Imibenconazole

Item number677298
CAS86598-92-7
FormulaC17H13Cl3N4S
Molecular weight411,74 g/mol
Quantity 1X100MG
storage conditions-20 °C
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Imibenconazole

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Imibenconazole solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Imibenconazole solution

674751
86598-92-7

1X5ML

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Imibenconazole

Imibenconazole

677298
86598-92-7

1X100MG

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 15.01.2025
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Imibenconazole
Catalog No.:677298
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 2), H225
Acute toxicity, Oral (Category 4), H302
Acute toxicity, Inhalation (Category 4), H332
Acute toxicity, Dermal (Category 4), H312
Eye irritation (Category 2), H319
Label elements
Pictogramflamme
flamme
GHS07 exclam
exclam
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger
Hazard statement(s)
H225 Highly flammable liquid and vapor.
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
H319 Causes serious eye irritation.
Precautionary statement(s)
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection/ hearing protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel
unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/ doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Supplemental Hazard
Statements
none
Reduced Labeling (<= 125 ml)
Pictogram
Signal word Danger
Hazard statement(s) none
Precautionary
statement(s)
none
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTSMixtures
Molecular weight : 411,74 g/mol
Component Acetonitrile CAS-No.75-05-8
EC-No.200-835-2
Index-No.608-001-00-3
Registrationnumber 01-2119471307-38-XXXX
FormulaC17H13Cl3N4S
Molecular Weight (g/mol)411.74
CAS-No.86598-92-7
FIRST AID MEASURES4.1 Description of first-aid measures
General advice
Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air. If breathing stops: mouth-to-mouth breathing or artificial
respiration. Oxygen if necessary. Immediately call in physician.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower. Consult a physician.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact
lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a
physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
Nitrogen oxides (NOx)
Combustible.
Pay attention to flashback.
Vapors are heavier than air and may spread along floors.
Development of hazardous combustion gases or vapours possible in the event of fire.
Forms explosive mixtures with air at ambient temperatures.
5.3 Advice for firefighters
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by
keeping a safe distance or by wearing suitable protective clothing.
5.4 Further information
Remove container from danger zone and cool with water. Suppress (knock down)
gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from
contaminating surface water or the ground water system.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance
contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains. Risk of explosion.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ).
Dispose of properly. Clean up affected area.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Advice on safe handling
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Advice on protection against fire and explosion
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary
measures against static discharge.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands
and face after working with substance.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and
sources of ignition.
Storage stability
Recommended storage temperature
2 - 8 °C
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Ingredients with workplace control parameters
8.2 Exposure controls
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
required
Body Protection
Flame retardant antistatic protective clothing.
Respiratory protection
required when vapours/aerosols are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Recommended Filter type: Filter type ABEK
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Control of environmental exposure
Do not let product enter drains. Risk of explosion.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: clear, liquid
Color: colorless
b) Odor pungent
c) Odor Threshold No data available
d) pH No data available
e) Melting
point/freezing point
No data available
f) Initial boiling point
and boiling range
No data available
g) Flash point 4,0 °C - closed cup
h) Evaporation rate 5,8
i) Flammability (solid,
gas)
No data available
j) Upper/lower Upper explosion limit: 7 %(V)
flammability or
explosive limits
Lower explosion limit: 1,2 %(V)
k) Vapor pressure 29,1 hPa at 20,0 °C
l) Vapor density No data available
m) Relative density No data available
n) Water solubility completely soluble
o) Partition coefficient:
n-octanol/water
log Pow: -0,34
p) Autoignition
temperature
523,0 °C
q) Decomposition
temperature
No data available
r) Viscosity Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
Surface tension 29,0 mN/m at 20,0 °C
STABILITY AND REACTIVITY10.1 Reactivity
Vapors may form explosive mixture with air.
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Warming.
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Mixture
Acute toxicity
No data available
Symptoms: Possible symptoms:, mucosal irritations
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
Mixture causes serious eye irritation.
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Acute inhalation toxicity - Possible symptoms:, mucosal irritations
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Additional Information
Not available
Lung irritation, chest pain, pulmonary edema, Inhalation studies on toluene have
demonstrated the development of inflammatory and ulcerous lesions of the penis, prepuce,
and scrotum in animals.
Other dangerous properties can not be excluded.
Handle in accordance with good industrial hygiene and safety practice.
Components
Acetonitrile
Acute toxicity
LD50 Oral - Mouse - male and female - 617 mg/kg
(OECD Test Guideline 401)
LC50 Inhalation - Mouse - male and female - 4 h - 6,022 mg/l
(OECD Test Guideline 403)
Acute toxicity estimate Dermal - 1.500 mg/kg
(Expert judgment)
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Causes serious eye irritation.
(OECD Test Guideline 405)
Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Respiratory or skin sensitization
Buehler Test - Guinea pig
Result: negative
(OECD Test Guideline 406)
Germ cell mutagenicity
Ames test
S. typhimurium
Result: negative
Remarks:
(ECHA)
In vitro mammalian cell gene mutation test
Chinese hamster ovary cells
Result: negative
Mutagenicity (mammal cell test): chromosome aberration.
Chinese hamster ovary cells
Result: Positive results were obtained in some in vitro tests.
Remarks:
(National Toxicology Program)
sister chromatid exchange assay
Chinese hamster ovary cells
Result: negative
Remarks:
Sister chromatid exchange
Saccharomyces cerevisiae
Result: positive
Remarks:
Cytogenetic analysis
(ECHA)
In vitro mammalian cell gene mutation test
Mouse lymphoma test
Result: negative
OECD Test Guideline 474
Mouse - male and female
Result: negative
Carcinogenicity
No evidence of carcinogenicity in animal studies.
Reproductive toxicity
Animal testing did not show any effects on fertility.
Specific target organ toxicity - single exposure
The substance or mixture is not classified as specific target organ toxicant, single
exposure.
Specific target organ toxicity - repeated exposure
The substance or mixture is not classified as specific target organ toxicant, repeated
exposure.Aspiration hazard
No aspiration toxicity classification
ECOLOGICAL INFORMATION12.1 Toxicity
Mixture
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
12.6 Other adverse effects
No data available
Components
Acetonitrile
Toxicity to fish flow-through test LC50 - Pimephales promelas (fathead
minnow) - 1.640 mg/l - 96 h
Remarks: (ECHA)
Toxicity to algae static test NOEC - Phaeodactylum tricornutum - 400 mg/l - 72
h
(ISO 10253)
static test ErC50 - Phaeodactylum tricornutum - 9.696 mg/l -
72 h
(ISO 10253)
Toxicity to bacteria
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 1648 IMDG: 1648 IATA: 1648
14.2 UN proper shipping name
ADR/RID: ACETONITRILE, SOLUTION
IMDG: ACETONITRILE, SOLUTION
IATA: Acetonitrile, SOLUTION
14.3 Transport hazard class(es)
ADR/RID: 3 IMDG: 3 IATA: 3
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.
National legislation
Seveso III: Directive 2012/18/EU of the
European Parliament and of the Council on the
control of major-accident hazards involving
dangerous substances.
: FLAMMABLE LIQUIDS
Other regulations
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or
stricter national regulations where applicable.
Take note of Dir 94/33/EC on the protection of young people at work.
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!