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Fentin hydroxide

Item number678657
CAS76-87-9
FormulaC18H16OSn
Molecular weight367,03 g/mol
Quantity 1X250MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
Fentin hydroxide

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Fentin hydroxide

Fentin hydroxide

678657
76-87-9

1X250MG

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Fentin hydroxide solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Fentin hydroxide solution

688968
76-87-9

1X5ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 31.01.2025
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Fentin hydroxide
Catalog No.:678657
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 2), H330
Acute toxicity, Dermal (Category 3), H311
Skin irritation (Category 2), H315
Serious eye damage (Category 1), H318
Carcinogenicity (Category 2), H351
Reproductive toxicity (Category 2), H361d
Specific target organ toxicity - single exposure (Category 2), H371
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Specific target organ toxicity - repeated exposure (Category 1), H372
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410 Classification according to EU Directives 67/548/EEC or 1999/45/EC
R40 T+ Very toxic R26
T Toxic R24/25, R48/23
Xi Irritant R37/38, R41
N Dangerous for the
environment
R50/53
Label elements
PictogramGHS05 acid
acid
GHS06 skull
skull
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger
Hazard statement(s)
H301 + H311 Toxic if swallowed or in contact with skin
H315 Causes skin irritation.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H361d Suspected of damaging the unborn child.
H371 May cause damage to organs.
H372 Causes damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P201 Obtain special instructions before use.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P273 Avoid release to the environment.
P280 Wear eye protection/ face protection.
P280 Wear protective gloves/ protective clothing.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER or doctor/ physician.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : Triphenyltin hydroxide
Formula : C18H16OSn
Molecular weight : 367,03 g/mol
CAS-No. : 76-87-9
EC-No. : 200-990-6
Index-No. : 050-004-00-1
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Triphenyltin hydroxide
CAS-No.
EC-No.
Index-No.
76-87-9
200-990-6
050-004-00-1
Acute Tox. 3; Acute Tox. 2;
Acute Tox. 3; Skin Irrit. 2; Eye
Dam. 1; Carc. 2; Repr. 2;
STOT SE 2; STOT SE 3;
<= 100 % STOT RE 1; Aquatic Acute 1;
Aquatic Chronic 1; H301 +
H311, H315, H318, H330,
H335, H351, H361d, H371,
H372, H410
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
Triphenyltin hydroxide
CAS-No.
EC-No.
Index-No.
76-87-9
200-990-6
050-004-00-1
T+, N, Carc.Cat.3, Repr.Cat.3,
R24/25 - R26 - R37/38 - R40 -
R41 - R48/23 - R63 - R50/53
<= 100 %
FormulaC18H16OSn
Molecular Weight (g/mol)367.03
CAS-No.76-87-9
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Tin/tin oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8. 6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire
protection.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Recommended storage temperature 2 - 8 °C
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/range: 124 - 126 °C
f) Initial boiling point and
boiling range
No data available
g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure No data available
l) Vapour density No data available
m) Relative density No data available
n) Water solubility No data available
o) Partition coefficient: noctanol/
water
No data available
p) Auto-ignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available 9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 46 mg/kg
LD50 Dermal - Rabbit - 1.600 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
This product is or contains a component that has been reported to be possibly carcinogenic based on its
IARC, ACGIH, NTP, or EPA classification.
Limited evidence of carcinogenicity in animal studies
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Possible risk of congenital malformation in the fetus.
Suspected human reproductive toxicant
Specific target organ toxicity - single exposure
May cause damage to organs.
Specific target organ toxicity - repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard
No data available Additional Information
RTECS: WH8575000
Muscle cramps/spasms., narcosis, Respiratory disorders
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 0,007 mg/l - 96,0 h
Toxicity to daphnia and
other aquatic
invertebrates
EC50 - Daphnia magna (Water flea) - 0,0087 mg/l - 48 h
Toxicity to algae EC50 - Skeletonema costatum - 0,0017 mg/l - 72 h
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
Bioaccumulation Poecilia reticulata (guppy) - 30 d
- 4,1 &#956;g/l
Bioconcentration factor (BCF): 2.900
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
Very toxic to aquatic life with long lasting effects
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material. Dissolve or mix the material with a
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 3146 IMDG: 3146 IATA: 3146
14.2 UN proper shipping name
ADR/RID: ORGANOTIN COMPOUND, SOLID, N.O.S. (Triphenyltin hydroxide)
IMDG: ORGANOTIN COMPOUND, SOLID, N.O.S. (Triphenyltin hydroxide)
IATA: Organotin compound, solid, n.o.s. (Triphenyltin hydroxide)
14.3 Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: yes IATA: no 14.6 Special precautions for user
No data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Triphenyltin hydroxide CAS-No.: 76-87-9
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
Chemical qualifying for PIC notification.
Triphenyltin hydroxide CAS-No.: 76-87-9
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
Chemical qualifying for PIC notification.
Triphenyltin hydroxide CAS-No.: 76-87-9
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
Chemical qualifying for PIC notification.
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!