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Fenitrothion

Item number676107
CAS122-14-5
FormulaC9H12NO5PS
Molecular weight277,23 g/mol
Quantity 1X250MG
storage conditions4 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
Fenitrothion

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Product Variations:

Product

Catalog No./ CAS No.

Quantity

Price

D6-Fenitrothion

D6-Fenitrothion

689271
203645-59-4

1X10MG

On request

D6-Fenitrothion solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

D6-Fenitrothion solution

689272
203645-59-4

1X1ML

On request

Fenitrothion

Fenitrothion

676107
122-14-5

1X250MG

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Fenitrothion solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Fenitrothion solution

678409
122-14-5

1X5ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 30.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Fenitrothion
Catalog No.:676107
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Inhalation (Category 1), H330
Acute toxicity, Dermal (Category 4), H312
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410 Classification according to EU Directives 67/548/EEC or 1999/45/EC
T+, N Very toxic, Dangerous for the
environment
R21/22, R26, R50/53
Label elements
PictogramGHS06 skull
skull
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger
Hazard statement(s)
H301 Toxic if swallowed.
H312 Harmful in contact with skin.
H330 Fatal if inhaled.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing.
P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician. Rinse mouth.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER or doctor/ physician.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C9H12NO5PS
Molecular weight : 277,23 g/mol
CAS-No. : 122-14-5
EC-No. : 204-524-2
Index-No. : 015-054-00-0
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Fenitrothion
CAS-No.
EC-No.
Index-No.
122-14-5
204-524-2
015-054-00-0
Acute Tox. 3; Acute Tox. 1;
Acute Tox. 4; Aquatic Acute 1;
Aquatic Chronic 1; H301,
H312, H330, H410
<= 100 %
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
Fenitrothion
CAS-No.
EC-No.
Index-No.
122-14-5
204-524-2
015-054-00-0
T+, N, R21/22 - R26 - R50/53 <= 100 %
FormulaC9H12NO5PS
Molecular Weight (g/mol)277.23
CAS-No.122-14-5
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx), Sulphur oxides, Oxides of phosphorus
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Recommended storage temperature 2 - 8 °C
Storage class (TRGS 510): Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
Colour: brown
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
No data available
f) Initial boiling point and
boiling range
118 °C at 0,07 hPa
g) Flash point > 100,00 °C
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available k) Vapour pressure 72.000,00 hPa at 20 °C
l) Vapour density No data available
m) Relative density 1,323 g/cm3 at 25 °C
n) Water solubility insoluble
o) Partition coefficient: noctanol/
water
log Pow: 3,3
p) Auto-ignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agentsStrong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 250 mg/kg
LC50 Inhalation - Rat - 4 h - 378 mg/m3
Remarks: Behavioral:Tremor. Behavioral:Muscle contraction or spasticity. Lungs, Thorax, or
Respiration:Dyspnea.
LD50 Dermal - Rabbit - 1.250 mg/kg
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available Germ cell mutagenicity
Human
leukocyte
Cytogenetic analysis
Human
Sister chromatid exchange
Hamster
Lungs
Cytogenetic analysis
Hamster
Lungs
Sister chromatid exchange
Human
lymphocyte
Cytogenetic analysis
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Reproductive toxicity - Rat - Oral
Effects on Newborn: Behavioral. Effects on Newborn: Other postnatal measures or effects.
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: TG0350000
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Carassius auratus (goldfish) - 2,8 mg/l - 96,0 h
LC50 - Oncorhynchus mykiss (rainbow trout) - 1 - 2 mg/l - 96,0 h
Toxicity to daphnia and
other aquatic
invertebrates
EC50 - Daphnia magna (Water flea) - 0,01 mg/l - 48 h
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
Bioaccumulation Oncorhynchus mykiss (rainbow trout) - 72 h
- 20 μg/l
Bioconcentration factor (BCF): 250
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects
Very toxic to aquatic life with long lasting effects.
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 2810 IMDG: 2810 IATA: 2810
14.2 UN proper shipping name
ADR/RID: TOXIC LIQUID, ORGANIC, N.O.S. (Fenitrothion)
IMDG: TOXIC LIQUID, ORGANIC, N.O.S. (Fenitrothion)
IATA: Toxic liquid, organic, n.o.s. (Fenitrothion)
14.3 Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No data available
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!