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Endosulfan

Item number677236
CAS115-29-7
FormulaC9H6Cl6O3S
Molecular weight406,93 g/mol
Quantity 1X250MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
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Endosulfan

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Catalog No./ CAS No.

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alpha-Endosulfan solution
Concentration: 100 µg/ml
Solvent: Ethyl acetate

alpha-Endosulfan solution

673560
959-98-8

1X5ML

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alpha-Endosulfan

alpha-Endosulfan

677325
959-98-8

1X100MG

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alpha-Endosulfan solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

alpha-Endosulfan solution

678398
959-98-8

1X5ML

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beta-Endosulfan solution
Concentration: 10.0 µg/ml
Solvent: Ethyl acetate

beta-Endosulfan solution

673561
33213-65-9

1X10ML

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beta-Endosulfan solution
Concentration: 100 µg/ml
Solvent: Ethyl acetate

beta-Endosulfan solution

673562
33213-65-9

1X5ML

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beta-Endosulfan

beta-Endosulfan

678035
33213-65-9

1X100MG

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beta-Endosulfan solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

beta-Endosulfan solution

678397
33213-65-9

1X5ML

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beta-Endosulfan solution
Concentration: 100 µg/ml
Solvent: Methanol

beta-Endosulfan solution

679467
33213-65-9

1X1ML

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beta-Endosulfan solution
Concentration: 10.0 µg/ml
Solvent: Acetonitrile

beta-Endosulfan solution

687879
33213-65-9

1X10ML

On request

Endosulfan

Endosulfan

677236
115-29-7

1X250MG

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 16.11.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Endosulfan
Catalog No.:677236
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 2), H300
Acute toxicity, Inhalation (Category 2), H330
Acute toxicity, Dermal (Category 2), H310
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
Label elements
PictogramGHS06 skull
skull
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Danger Hazard statement(s)
H300 + H310 + H330 Fatal if swallowed, in contact with skin or if inhaled
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing.
P284 Wear respiratory protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/
physician.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C9H6Cl6O3S
Molecular weight : 406,93 g/mol
CAS-No. : 115-29-7
EC-No. : 204-079-4
Index-No. : 602-052-00-5
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Endosulfan
CAS-No.
EC-No.
Index-No.
115-29-7
204-079-4
602-052-00-5
Acute Tox. 2; Aquatic Acute 1;
Aquatic Chronic 1; H300,
H330, H310, H400, H410
M-Factor - Aquatic Acute: 10
M-Factor - Aquatic Chronic:
100
<= 100 %
FormulaC9H6Cl6O3S
Molecular Weight (g/mol)406.93
CAS-No.115-29-7
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician 4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Sulphur oxides, Hydrogen chloride gas
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Storage class (TRGS 510): Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling
the product Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry Hands Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: crystalline
Colour: white
b) Odour pungent
c) Odour Threshold No data available
d) pH 7,2
e) Melting point/freezing
point
No data available
f) Initial boiling point and
boiling range
106 °C at 0,9 hPa g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure No data available
l) Vapour density No data available
m) Relative density 1,744 g/cm3
n) Water solubility No data available
o) Partition coefficient: noctanol/
water
log Pow: 3,83
p) Auto-ignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Mercury/mercury oxides.
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 18 mg/kg
LC50 Inhalation - Rat - 4 h - 80 mg/m3
LD50 Dermal - Rabbit - 90 mg/kg
Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Eye:Other. Prolonged skin
contact may cause skin irritation and/or dermatitis.
Skin corrosion/irritation
No data available Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
Human
lymphocyte
Sister chromatid exchange
Mouse
lymphocyte
Mutation in mammalian somatic cells.
Mouse
sperm
Hamster
Cytogenetic analysis
Mouse
Cytogenetic analysis
Mouse
Dominant lethal test
Carcinogenicity
Carcinogenicity - Mouse - Subcutaneous
Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Lungs, Thorax, or Respiration:Tumors.
Liver:Tumors.
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Reproductive toxicity - Rat - Oral
Paternal Effects: Spermatogenesis (including genetic material, sperm morphology,motility, and count).
Paternal Effects: Testes, epididymis, sperm duct Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: RB9275000
Tremors, Convulsions, Headache, Nausea, Vomiting, Diarrhoea, Dizziness
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish mortality LOEC - Mugil cephalus - 0,013 mg/l - 96,0 h
LC50 - Cyprinus carpio (Carp) - < 0,01 mg/l - 96,0 h
Toxicity to daphnia and EC50 - Daphnia magna (Water flea) - 0,2 - 0,9 mg/l - 48 h other aquatic
invertebrates
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
Bioaccumulation Cyprinodon variegatus (sheepshead minnow) - 28 d
- 1,1 μg/l
Bioconcentration factor (BCF): 3.700
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
Very toxic to aquatic life with long lasting effects
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 2811 IMDG: 2811 IATA: 2811
14.2 UN proper shipping name
ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (Endosulfan)
IMDG: TOXIC SOLID, ORGANIC, N.O.S. (Endosulfan)
IATA: Toxic solid, organic, n.o.s. (Endosulfan)
14.3 Transport hazard class(es)
ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: yes IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 453/2010.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Endosulfan CAS-No.: 115-29-7
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
Chemical subject or partially subject to the PIC procedure Endosulfan CAS-No.: 115-29-7
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
Chemical subject or partially subject to the PIC procedure.
Endosulfan CAS-No.: 115-29-7
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
Chemical subject or partially subject to the PIC procedure.
Endosulfan CAS-No.: 115-29-7
Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and
import of dangerous chemicals
Chemical subject or partially subject to the PIC procedure.
Endosulfan CAS-No.: 115-29-7
Regulation (EC) No 850/2004 on Persistent Organic Pollutants - Annex I Substances Subject to
Prohibitions
Endosulfan CAS-No.: 115-29-7
Regulation (EC) No 850/2004 on Persistent Organic Pollutants - Annex IV Substances Subject to Waste
Management Provisions
Threshold limits : <= 50mg/kg
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!