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Emamectin B1a

Item number679132
CAS121124-29-6
FormulaC49H75NO13
Molecular weight886,12 g/mol
Quantity 1X10MG
storage conditions4 °C
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Emamectin B1a

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Emamectin B1a solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Emamectin B1a solution

676145
121124-29-6

1X1ML

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Emamectin B1a

Emamectin B1a

679132
121124-29-6

1X10MG

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 15.01.2025
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Emamectin B1a
Catalog No.:679132
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATIONHazard statements
H301 - Toxic if swallowed
H311 - Toxic in contact with skin
H318 - Causes serious eye damage
H331 - Toxic if inhaled
H370 - Causes damage to organs
H372 - Causes damage to organs through prolonged or repeated exposure
H410 - Very toxic to aquatic life with long lasting effects
Label elements
PictogramGHS06 skull
skull
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
Signal word
Danger

Precautionary Statements - EU (§28, 1272/2008)
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor
P391 - Collect spillage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
2.3. Other hazards
No information available.
This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.
COMPOSITION/INFORMATION ON INGREDIENTSClassification
according to
Regulation (EC) No.
1272/2008 [CLP]
Acute Tox. 3 (H301)
Acute Tox. 3 (H311)
Acute Tox. 3 (H331)
Eye Dam. 1 (H318)
STOT SE 1 (H370)
STOT RE 1 (H372)
Aquatic Acute 1
(H400)
Aquatic Chronic 1
(H410)
Full text of H- and EUH-phrases: see section 16
Acute Toxicity Estimate
No information available
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)
FormulaC49H75NO13
Molecular Weight (g/mol)886.12
CAS-No.121124-29-6
FIRST AID MEASURES4.1. Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur. IF exposed or
concerned: Get medical advice/attention. If breathing has stopped, give artificial respiration.
Get medical attention immediately. Do not breathe dust. Do not use mouth-to-mouth
method if victim ingested or inhaled the substance; give artificial respiration with the aid of a
pocket mask equipped with a one-way valve or other proper respiratory medical device. If
breathing is difficult, (trained personnel should) give oxygen.
Eye contact Get immediate medical advice/attention. Rinse immediately with plenty of water, also under
the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Remove contact
lenses, if present and easy to do. Continue rinsing. Do not rub affected area.
Skin contact Get immediate medical advice/attention. Wash off immediately with soap and plenty of
water while removing all contaminated clothes and shoes.
Ingestion Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious
person. Get immediate medical advice/attention.
Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or
clothing. Do not breathe dust. Do not use mouth-to-mouth method if victim ingested or
inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with
a one-way valve or other proper respiratory medical device. Use personal protective
equipment as required. See section 8 for more information.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms Burning sensation. Coughing and/ or wheezing. Difficulty in breathing.
4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors Treat symptomatically.
FIRE-FIGHTING MEASURES5.1. Extinguishing media
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.
Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.
5.2. Special hazards arising from the substance or mixture
Specific hazards arising from the
chemical
No information available.
5.3. Advice for firefighters
Special protective equipment and
precautions for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout
gear. Use personal protection equipment.
ACCIDENTAL RELEASE MEASURES6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required. Evacuate personnel to safe areas. Avoid generation of
dust. Do not breathe dust. Keep people away from and upwind of spill/leak.
Other information Refer to protective measures listed in Sections 7 and 8.
For emergency responders Use personal protection recommended in Section 8.
6.2. Environmental precautions
Environmental precautions Prevent further leakage or spillage if safe to do so.
6.3. Methods and material for containment and cleaning up
Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal.
Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information.
HANDLING AND STORAGE7.1. Precautions for safe handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Take off contaminated clothing and wash it before reuse. Do not eat,
drink or smoke when using this product. Do not breathe dust. Avoid generation of dust. In
case of insufficient ventilation, wear suitable respiratory equipment. Handle product only in
closed system or provide appropriate exhaust ventilation.
General hygiene considerations Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this
product. Wash hands before breaks and after work. Wear suitable gloves and eye/face
protection. Remove and wash contaminated clothing and gloves, including the inside,
before re-use. Regular cleaning of equipment, work area and clothing is recommended.
Wash hands before breaks and immediately after handling the product. Do not breathe
dust. Take off contaminated clothing and wash it before reuse. Contaminated work clothing
should not be allowed out of the workplace.
7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions Please refer to the manufacturers certificate for specific storage and transport temperature
conditions. Store only in the original receptacle unless other advice is given on the CoA.
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach
of children. Store locked up.
7.3. Specific end use(s)
Identified uses
Risk Management Methods: The information required is contained in this Safety Data Sheet.
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1. Control parameters
Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.
Biological occupational exposure limits
This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific
regulatory bodies
Derived No Effect Level (DNEL) No information available.
Predicted No Effect Concentration
(PNEC)
No information available.
8.2. Exposure controls
Personal protective equipment
Eye/face protection Avoid contact with eyes. Wear safety glasses with side shields (or goggles). Tight sealing
safety goggles.
Hand protection The protective gloves to be used must comply with the specifications of EC Directive
89/686/EEC and the related standard EN374. Wear suitable gloves. Impervious gloves.
Glove material: Wear protective butyl
rubber gloves
Skin and body protection Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
General hygiene considerations Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Wash hands before breaks and after work. Wear suitable gloves and eye/face
protection. Remove and wash contaminated clothing and gloves, including the inside,
before re-use. Regular cleaning of equipment, work area and clothing is recommended.
Wash hands before breaks and immediately after handling the product. Do not breathe
dust. Take off contaminated clothing and wash it before reuse. Contaminated work clothing
should not be allowed out of the workplace.
Environmental exposure controls Do not allow into any sewer, on the ground or into any body of water.
PHYSICAL AND CHEMICAL PROPERTIES9.1. Information on basic physical and chemical properties
Physical state Solid
Appearance Solid
Colour off-white
Odour No information available.
Odour threshold No information available
9.2. Other information
Property Values
Melting point / freezing point 141 - 146 °C
Boiling point / boiling range No data available
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability or explosive
limits
No data available
Lower flammability or explosive
limits
No data available
Flash point No data available
Autoignition temperature No data available
Decomposition temperature
pH No data available
pH (as aqueous solution) No data available No information available
Kinematic viscosity No data available
Dynamic viscosity No data available
Water solubility 0.024 g/L
Solubility(ies) No data available
Partition coefficient 5.0
Vapour pressure No data available
Relative density 1.23
Bulk density No data available
Liquid Density No data available
Relative vapour density No data available
Particle characteristics
Particle Size No information available
Particle Size Distribution No information available
9.2. Other information
Molecular weight 886.1
Molecular formula C49 H75 N O13
9.2.1. Information with regards to physical hazard classes
Not applicable
9.2.2. Other safety characteristics
No information available
STABILITY AND REACTIVITY10.1. Reactivity
Reactivity No information available.
10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data
Sensitivity to mechanical impact None.
Sensitivity to static discharge None.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.
10.4. Conditions to avoid
Conditions to avoid Excessive heat.
10.5. Incompatible materials
Incompatible materials Strong acids. Strong bases. Strong oxidizing agents.
Hazardous decomposition products None known based on information supplied.
TOXICOLOGICAL INFORMATION11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Information on likely routes of exposure
Product Information
Inhalation Specific test data for the substance or mixture is not available. Toxic by inhalation. (based
on components).
Eye contact Specific test data for the substance or mixture is not available. Causes serious eye
damage. May cause irreversible damage to eyes.
Skin contact Specific test data for the substance or mixture is not available. May cause irritation. Toxic in
contact with skin. (based on components).
Ingestion Specific test data for the substance or mixture is not available. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea. Toxic if swallowed. (based on
components).
Symptoms related to the physical, chemical and toxicological characteristics
Symptoms Redness. Burning. May cause blindness. Coughing and/ or wheezing. Difficulty in
breathing.
Numerical measures of toxicity
No information available
Acute toxicity
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation May cause skin irritation.
Serious eye damage/eye irritation Classification based on data available for ingredients. Causes burns. Risk of serious
damage to eyes.
Respiratory or skin sensitisation No information available.
Germ cell mutagenicity No information available.
Carcinogenicity No information available.
Reproductive toxicity No information available.
STOT - single exposure Based on the classification criteria of the Globally Harmonized System as adopted in the
country or region with which this safety data sheet complies, this product has been
determined to cause systemic target organ toxicity from acute exposure. (STOT SE).
Causes damage to organs if swallowed. Causes damage to organs in contact with skin.
STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard No information available.
11.2. Information on other hazards
11.2.1. Endocrine disrupting properties
Endocrine disrupting properties No information available.
11.2.2. Other information
Other adverse effects No information available.
ECOLOGICAL INFORMATION12.1. Toxicity
Ecotoxicity Very toxic to aquatic life with long lasting effects.
12.2. Persistence and degradability
Persistence and degradability No information available.
12.3. Bioaccumulative potential
Bioaccumulation There is no data for this product.

12.4. Mobility in soil
Mobility in soil No information available.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment No information available.
12.6. Endocrine disrupting properties
Endocrine disrupting properties No information available.
12.7. Other adverse effects
No information available.
DISPOSAL CONSIDERATIONS13.1. Waste treatment methods
Waste from residues/unused
products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers.
TRANSPORT INFORMATIONIATA
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Emamectin B1a)
14.3 Transport hazard class(es) 6.1
14.4 Packing group III
Description UN2811, Toxic solid, organic, n.o.s. (Emamectin B1a), 6.1, III
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions A3, A5
ERG Code 6L
IMDG
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Emamectin B1a)
14.3 Transport hazard class(es) 6.1
14.4 Packing group III
Description UN2811, Toxic solid, organic, n.o.s. (Emamectin B1a), 6.1, III, Marine pollutant
14.5 Marine pollutant P
Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 223, 274
EmS-No F-A, S-A No information available
14.7 Maritime transport in bulk
according to IMO instruments
No information available
RID
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Emamectin B1a)
14.3 Transport hazard class(es) 6.1
14.4 Packing group III
Description UN2811, Toxic solid, organic, n.o.s. (Emamectin B1a), 6.1, III, Environmentally Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 614
Classification code T2
ADR
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Emamectin B1a)
14.3 Transport hazard class(es) 6.1
14.4 Packing group III
Description UN2811, Toxic solid, organic, n.o.s. (Emamectin B1a), 6.1, III, (E), Environmentally
Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 614
Classification code T2
Tunnel restriction code (E)
REGULATORY INFORMATION15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Water hazard class (WGK) strongly hazardous to water (WGK 3)
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents
at work.
Authorisations and/or restrictions on use:
This product does not contain substances subject to authorisation (Regulation (EC) No. 1907/2006 (REACH), Annex XIV) This
product does not contain substances subject to restriction (Regulation (EC) No. 1907/2006 (REACH), Annex XVII)
DIRECTIVE (EU) 2021/1187 on the marketing and use of explosives precursors
Not applicable
Persistent Organic Pollutants
Not applicable
Dangerous substance category per Seveso Directive (2012/18/EU)
H2 - ACUTE TOXIC
H3 - STOT SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
E1 - Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1
Ozone-depleting substances (ODS) regulation (EC) 1005/2009
Not applicable
15.2. Chemical safety assessment
Chemical Safety Report A Chemical Safety Assessment has been carried out for this substance

OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!