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Diuron

ISO 17034 Reference Material

Item number672847
CAS330-54-1
FormulaC9H10Cl2N2O
Molecular weight233,10 g/mol
Quantity 1X250MG
storage conditions4 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
Diuron

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Catalog No./ CAS No.

Quantity

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D6-Diuron

D6-Diuron

674692
1007536-67-5

1X10MG

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D6-Diuron solution
Concentration: 100 µg/ml
Solvent: Acetone

D6-Diuron solution

675413
1007536-67-5

1X1ML

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D6-Diuron solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

D6-Diuron solution

676314
1007536-67-5

1X1ML

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ISO 17034 Reference Material

Diuron

Diuron

672847
330-54-1

1X250MG

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Diuron solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Diuron solution

673269
330-54-1

1X5ML

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ISO 17034 Certified Reference Material

Diuron

Diuron

691438
330-54-1

1X100MG

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 04.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Diuron
Catalog No.:672847
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Carcinogenicity (Category 2), H351
Specific target organ toxicity - repeated exposure (Category 2), H373
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410 Classification according to EU Directives 67/548/EEC or 1999/45/EC
R40
Xn Harmful R22, R48/22
N Dangerous for the
environment
R50/53
Label elements
PictogramGHS07 exclam
exclam
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
Signal word Warning
Hazard statement(s)
H302 Harmful if swallowed.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P273 Avoid release to the environment.
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you
feel unwell. Rinse mouth.
P391 Collect spillage.
P501 Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : 3-(3,4-Dichlorophenyl)-1,1-dimethylurea
Formula : C9H10Cl2N2O
Molecular weight : 233,09 g/mol
CAS-No. : 330-54-1
EC-No. : 206-354-4
Index-No. : 006-015-00-9
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Diuron (ISO)
CAS-No.
EC-No.
Index-No.
330-54-1
206-354-4
006-015-00-9
Acute Tox. 4; Carc. 2; STOT
RE 2; Aquatic Acute 1; Aquatic
Chronic 1; H302, H351, H373,
H410
<= 100 %
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
Diuron (ISO)
CAS-No.
EC-No.
Index-No.
330-54-1
206-354-4
006-015-00-9
Xn, N, Carc.Cat.3, R22 - R40 -
R48/22 - R50/53
<= 100 %
FormulaC9H10Cl2N2O
Molecular Weight (g/mol)233.10
CAS-No.330-54-1
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician. In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
respirators and components tested and approved under appropriate government standards such
as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: powder
Colour: white
b) Odour amine-like
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
Melting point/range: 156
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Do not heat above melting point.
10.5 Incompatible materials
Strong oxidizing agents, Strong acids, Strong bases 10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male - 1.017 mg/kg
LC50 Inhalation - Rat - male and female - 4 h - > 5,05 mg/l
(OECD Test Guideline 403)
LD50 Dermal - Rat - male and female - > 5.000 mg/kg
(OECD Test Guideline 402)
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye irritation
(OECD Test Guideline 405)
Respiratory or skin sensitisation
Maximisation Test (GPMT) - Guinea pig
Result: Does not cause skin sensitisation.
(OECD Test Guideline 406)
Germ cell mutagenicity
Ames test
S. typhimurium
Result: negative
Directive 67/548/EEC, Annex V, B.12.
Mouse - male and female
Result: negative
Carcinogenicity
Carcinogenicity - Rat - male and female - Oral
Blood:Changes in spleen. This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC,
ACGIH, NTP, or EPA classification.
Limited evidence of carcinogenicity in animal studies
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Developmental Toxicity - Rat - Oral
Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus).
Developmental Toxicity - Rat - Oral
Specific Developmental Abnormalities: Musculoskeletal system.
Developmental Toxicity - Mouse - Subcutaneous
Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Effects on Embryo or Fetus:
Fetal death. Specific Developmental Abnormalities: Eye, ear.
Specific target organ toxicity - single exposure
No data available Specific target organ toxicity - repeated exposure
Oral - May cause damage to organs through prolonged or repeated exposure. - Blood
Aspiration hazard
No data available
Additional Information
Repeated dose toxicity - Rat - male - Oral - No observed adverse effect level - 6,7 mg/kg
Blood:Other changes.
RTECS: YS8925000
Central nervous system depression, Gastrointestinal disturbance, Liver injury may occur., Kidney injury
may occur., Blood disorders, To the best of our knowledge, the chemical, physical, and toxicological
properties have not been thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish static test LC50 - Oncorhynchus mykiss (rainbow trout) - 14,7 mg/l - 96 h
(OECD Test Guideline 203)
Toxicity to daphnia and
other aquatic
invertebrates
static test EC50 - Daphnia magna (Water flea) - 1,4 mg/l - 48 h
(OECD Test Guideline 202)
Toxicity to algae static test EC50 - Desmodesmus subspicatus (Scenedesmus subspicatus) -
0,022 mg/l - 72 h
(OECD Test Guideline 201)
Toxicity to bacteria Respiration inhibition EC50 - Sludge Treatment - 3.080 mg/l - 30 min
(OECD Test Guideline 209)
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 0 % - Not biodegradable
(OECD Test Guideline 301F)
12.3 Bioaccumulative potential
Bioaccumulation Gambusia affinis (Mosquito fish) - 72 h
- 159 μg/l
Bioconcentration factor (BCF): 290
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
Very toxic to aquatic life with long lasting effects.
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 3077 IMDG: 3077 IATA: 3077
14.2 UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Diuron (ISO))
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Diuron (ISO))
IATA: Environmentally hazardous substance, solid, n.o.s. (Diuron (ISO))
14.3 Transport hazard class(es)
ADR/RID: 9 IMDG: 9 IATA: 9
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes
14.6 Special precautions for user
Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination
packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No data available
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!