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Di-n-butylamine

Item number	677593
CAS	111-92-2
Formula	C8H19N
Molecular weight	129,24 g/mol
Quantity	1X1000MG
storage conditions	20 °C
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Di-n-butylamine		677593 111-92-2	1X1000MG	Please log in.

Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 02.11.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	Di-n-butylamine
Catalog No.:	677593
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com
Emergency telephone number	HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours.
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 3), H226 Acute toxicity , Oral (Category 4), H302 Acute toxicity, Inhalation (Category 2), H330 Acute toxicity, Dermal (Category 3), H311 Skin corrosion, (Category 1A), H314
Label elements
Pictogram	flamme flamme GHS05 acid acid GHS06 skull skull
	2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H226 Flammable liquid and vapour. H302 H armful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H330 Fatal if inhaled. Precautionary statement(s) P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 Wear respiratory protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rin sing. P310 Immediately call a POISON CENTER or doctor/ physician. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS	3.1 Substances Formula : C 8 H 19 N Molecular weight : 129,24 g/mol CAS - No. : 111 - 92 - 2 EC - No. : 203 - 921 - 8 Index - No. : 612 - 049 - 00 - 0 Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration Dibutylamine CAS - No. EC - No. Index - No. 111 - 92 - 2 203 - 921 - 8 612 - 049 - 00 - 0 Flam. Liq. 3 ; Acute Tox. 4 ; Acute Tox. 2 ; Acute Tox. 3 ; Skin Corr. 1A ; H226, H302, H311, H314, H330 <= 100 % Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration Dibutylamine CAS - No. EC - No. Index - No. 111 - 92 - 2 203 - 921 - 8 612 - 049 - 00 - 0 T , R10 - R21/22 - R23 - R35 <= 100 %
Formula	C8H19N
Molecular Weight (g/mol)	129.24
CAS-No.	111-92-2
FIRST AID MEASURES	4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a phy sician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES	5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol - resistant foa m, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx) 5.3 Advice for firefighters Wear self - contained breathing apparatus for firefighting if necessary. 5.4 Furt her information Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumula ting to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the envir onment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet - brushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE	7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly c losed in a dry and well - ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510) : Flammable liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION	8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8 - inch minim um). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touchi ng glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clot hing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air - purifying respirators are appropriate use a full - face respirator with multi - purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full - face supplied air respirator. Use respirators and componen ts tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties a) Appearance Form : clear, liquid Colour : colourless b) Odour ammoniacal c) Odour Threshold No data available d) pH 11,1 at 1 g/l at 20 °C e) Melting point/freezing point Melting point/range : - 62 °C - lit. f) Initial boiling point and boiling range 159 °C - lit. g) Flash point 40,5 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit : 6,8 %(V) Lower explosion limit : 0,6 %(V) k) Vapour pressure 2,5 hPa at 20 °C l) Vapour density 4,46 - (Air = 1.0) m) Relative density 0,767 g/cm3 at 25 °C n) Water solubility 3,8 g/l at 20 °C - OECD Test Guideline 105 - completely miscible o) Partition coefficient: n - octanol/water log Pow : 2,1 at 23 °C p) Auto - ignition temperature 225 °C at 1.013,25 hPa q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Surface tension 50,6 mN/m at 20 °C Dissociation constant 11 at 20 °C Relative vapour density 4,46 - (Air = 1.0)
STABILITY AND REACTIVITY	10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks 10.5 Incompatible materials Strong oxidizing agents, Carbon dioxide (CO2), Zinc, Iron, Copper 10.6 Hazardous decomposition products Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - male - 550 mg/kg LC50 Inhalation - Rat - male and female - 4 h - 1,15 mg/l ( OECD Test Guideline 403 ) LD50 Dermal - Rabbit - male - 768 mg/kg Skin corrosion/irritation Skin - Rabbit Result : Causes severe burns. - 3 min - 1 h ( OECD Test Guideline 404 ) Serious eye damage/eye irritation Eyes - Rabbit Result : Corrosive ( OECD Test Guideline 405 ) Respiratory or skin sensitisation Buehler Test - Guinea pig Result : Does not cause skin sensitisation. Germ cell mutagenicity Mouse lymphocyte Result : negative OECD Test Guideline 475 Mouse - male and female Result : negative Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS : HR7780000 Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea
ECOLOGICAL INFORMATION	12.1 Toxicity Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 5,5 - 37,0 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 65,98 mg/l - 48 h ( Directive 67/548/EEC, Annex V, C.2. ) Toxicity to algae static test EC50 - Desmodesmus subspicatus (Scenedesmus subspicatus) - 16,91 mg/l - 72 h 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 28 d Result : 95 % - Readily biodegradable. ( OECD Test Guideline 301C ) 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be eith er persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Toxic to aquatic life.
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non - recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.
TRANSPORT INFORMATION	14.1 UN number ADR/RID : 2248 IMDG : 2248 IATA: 2248 14.2 UN proper shipping name ADR/RID : DI - n - BUTYLAMINE IMDG : DI - n - BUTYLAMINE IATA: Di - n - butylamine 14.3 Transport hazard class(es) ADR/RID : 8 ( 3 ) IMDG : 8 ( 3 ) IATA: 8 ( 3 ) 14.4 Packaging group ADR/RID : II IMDG : II IATA: II 14.5 Environmental hazards ADR/RID : no IMDG Marine pollutant : no IATA: no 14.6 Special pr ecautions for user No data available
REGULATORY INFORMATION	This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No data available 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!