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Diisopropylether

Item number686456
CAS108-20-3
FormulaC6H14O
Molecular weight102,18 g/mol
Quantity 1X5ML
storage conditions20 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
Diisopropylether

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Diisopropylether

Diisopropylether

686456
108-20-3

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 27.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Diisopropylether
Catalog No.:686456
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 2), H225
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H336
For the full text of the H-Statements mentioned in this Section, see Section 16.
Label elements
PictogramExplosiv

flamme
flamme
Signal Word Danger
Hazard statement(s)
H225 Highly flammable liquid and vapor.
H336 May cause drowsiness or dizziness.
Precautionary statement(s)
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
Supplemental Hazard information (EU)
EUH019 May form explosive peroxides.
EUH066 Repeated exposure may cause skin dryness or cracking.
Signal Word Danger
Hazard statement(s) none
Precautionary
statement(s)
none
Supplemental Hazard information (EU)
EUH019 May form explosive peroxides.
EUH066 Repeated exposure may cause skin dryness or cracking.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
May form explosive peroxides.
COMPOSITION/INFORMATION ON INGREDIENTSSynonyms : Isopropyl ether
Formula : C6H14O
Molecular weight : 102,17 g/mol
CAS-No. : 108-20-3
EC-No. : 203-560-6
Index-No. : 603-045-00-X
Component
Diisopropyl ether
CAS-No.
EC-No.
Index-No.
108-20-3
203-560-6
603-045-00-X
Classification
Flam. Liq. 2; STOT SE 3;
H225, H336
Concentration limits:
>= 20 %: STOT SE 3,
H336;
Concentration
<= 100 %
FormulaC6H14O
Molecular Weight (g/mol)102.18
CAS-No.108-20-3
FIRST AID MEASURES4.1 Description of first-aid measures
General advice
Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air. Call in physician.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower.
In case of eye contact
After eye contact: rinse out with plenty of water. Remove contact lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a
physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Carbon dioxide (CO2) Foam Dry powder
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
Combustible.
Pay attention to flashback.
Vapors are heavier than air and may spread along floors.
Development of hazardous combustion gases or vapours possible in the event of fire.
Forms explosive mixtures with air at ambient temperatures.
5.3 Advice for firefighters
In the event of fire, wear self-contained breathing apparatus.
5.4 Further information
Remove container from danger zone and cool with water. Prevent fire extinguishing water
from contaminating surface water or the ground water system.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance
contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.
Evacuate the danger area, observe emergency procedures, consult an expert.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains. Risk of explosion.
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ).
Dispose of properly. Clean up affected area.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Advice on safe handling
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Advice on protection against fire and explosion
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary
measures against static discharge.
Hygiene measures
Change contaminated clothing. Preventive skin protection recommended. Wash hands after
working with substance.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and
sources of ignition.
Test for peroxide formation periodically and before distillation.
Storage class
Storage class (TRGS 510): 3: Flammable liquids
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Ingredients with workplace control parameters
Derived No Effect Level (DNEL)
Application Area Routes of Health effect Value
exposure
Worker DNEL, dermal Systemic effects
longterm
Worker DNEL, inhalation Systemic effect 850 mg/m3
longterm
Consumer DNEL, dermal Systemic effect
longterm
Consumer DNEL, inhalation Systemic effect 151 mg/m3
longterm
Consumer DNEL, oral Systemic effects
longterm

Predicted No Effect Concentration (PNEC)
Compartment Value
Fresh water 0,19 mg/l
Sea water 0,019 mg/l
Fresh water sediment 2,79 mg/kg
Sea sediment 0,28 mg/kg
Soil 0,47 mg/kg
Sewage treatment plant 37 mg/l

8.2 Exposure controls
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching gloves outer surface) to avoid skin contact
with this product. Dispose of contaminated gloves after use in accordance with
applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU)
2016/425 and the standard EN 374 derived from it.
Full contact
Material: butyl-rubber
Minimum layer thickness: 0,3 mm
Break through time: 480 min
Material tested:Butoject®
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,2 mm
Break through time: 35 min
Material tested:Dermatril® P
If used in solution, or mixed with other substances, and under conditions which
differ from EN 374, contact the supplier of the EC approved gloves. This
recommendation is advisory only and must be evaluated by an industrial hygienist
and safety officer familiar with the specific situation of anticipated use by our
customers. It should not be construed as offering an approval for any specific use
scenario.
Body Protection
Flame retardant antistatic protective clothing.
Respiratory protection
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic
compounds
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Control of environmental exposure
Do not let product enter drains. Risk of explosion.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Physical state clear, liquid
b) Color colorless
c) Odor No data available
d) Melting
point/freezing point
Melting point/range: -85 °C - lit.
e) Initial boiling point
and boiling range
68 - 69 °C - lit.
f) Flammability (solid,
gas)
No data available
g) Upper/lower
flammability or
explosive limits
Upper explosion limit: 21 %(V)
Lower explosion limit: 1 %(V)
h) Flash point -29 °C - closed cup
i) Autoignition
temperature
No data available
j) Decomposition
temperature
No data available
k) pH No data available
l) Viscosity Viscosity, kinematic: No data available
Viscosity, dynamic: 0,33 mPa.s at 20 °C0,24 mPa.s at 40 °C
m) Water solubility 3,11 g/l at 20,2 °C - soluble
n) Partition coefficient:
n-octanol/water
log Pow: 2,4 at 20 °C - Bioaccumulation is not expected.
o) Vapor pressure 227 hPa at 25 °C
160 hPa at 20 °C
p) Density 0,725 g/mL at 25 °C - lit.
Relative density No data available
q) Relative vapor
density
No data available
r) Particle
characteristics
No data available
s) Explosive properties No data available
t) Oxidizing properties none
9.2 Other safety information
Relative vapor
density
3,53 - (Air = 1.0)
STABILITY AND REACTIVITY10.1 Reactivity
Formation of peroxides possible.
Vapors may form explosive mixture with air.
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
Contains the following stabilizer(s):
butyl hydroxytoluene (BHT) (0,001 %)
10.3 Possibility of hazardous reactions
Exothermic reaction with:
Risk of explosion with:
Aldehydes
Amines
mineral acids
Oxidizing agents
Zinc
10.4 Conditions to avoid
May form explosive peroxides.
Warming.
Moisture.
10.5 Incompatible materials
various plastics
10.6 Hazardous decomposition products
Peroxides
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male and female - 4.600 mg/kg
(OECD Test Guideline 401)
Symptoms: Nausea, Vomiting, Irritations of mucous membranes in the mouth, pharynx,
oesophagus and gastrointestinal tract., Risk of aspiration upon vomiting.
Symptoms: mucosal irritations, Cough, Shortness of breath
Dermal: No data available
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
Skin - In vitro study
Result: No skin irritation - 1 h
Remarks: (ECHA)
Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye irritation
(OECD Test Guideline 405)
Respiratory or skin sensitization
Local lymph node assay (LLNA) - Mouse
Result: negative
(OECD Test Guideline 429)
Germ cell mutagenicity
Test Type: Ames test
Test system: Escherichia coli/Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
Test Type: Mutagenicity (mammal cell test): chromosome aberration.
Test system: rat hepatocytes
Metabolic activation: without metabolic activation
Method: OECD Test Guideline 473
Result: negative
Test Type: gene mutation test
Test system: Saccharomyces cerevisiae
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 480
Result: negative
Test Type: In vitro mammalian cell gene mutation test
Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
Carcinogenicity
No data available
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
May cause drowsiness or dizziness.
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
11.2 Additional Information
Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain
components considered to have endocrine
disrupting properties according to REACH Article
57(f) or Commission Delegated regulation (EU)
2017/2100 or Commission Regulation (EU)
2018/605 at levels of 0.1% or higher.
RTECS: TZ5425000
Nausea, Headache, Vomiting, narcosis
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
After absorption of large quantities:
Headache
narcosis
agitation
Unconsciousness
respiratory arrest
drop in blood pressure
Handle in accordance with good industrial hygiene and safety practice.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to daphnia
and other aquatic
invertebrates
static test EC50 - Daphnia magna (Water flea) - 190 mg/l - 48 h
(OECD Test Guideline 202)
Toxicity to bacteria static test EC50 - activated sludge - 2.249 mg/l - 3 h
(OECD Test Guideline 209)
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 0 % - Not biodegradable
(OECD Test Guideline 301D)
Theoretical oxygen
demand
2.833 mg/g
Remarks: (Lit.)
Ratio BOD/ThBOD 19 %
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
12.6 Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties
according to REACH Article 57(f) or Commission
Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.
12.7 Other adverse effects
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 1159 IMDG: 1159 IATA: 1159
14.2 UN proper shipping name
ADR/RID: DIISOPROPYL ETHER
IMDG: DIISOPROPYL ETHER
IATA: Diisopropyl ether
14.3 Transport hazard class(es)
ADR/RID: 3 IMDG: 3 IATA: 3
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
Tunnel restriction code : (D/E)
Further information : No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.
National legislation
Seveso III: Directive 2012/18/EU of the European
Parliament and of the Council on the control of
: FLAMMABLE LIQUIDS
major-accident hazards involving dangerous
substances.
Other regulations
Take note of Dir 94/33/EC on the protection of young people at work.
15.2 Chemical Safety Assessment
A Chemical Safety Assessment has been carried out for this substance
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!