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Item number | 680441 |
CAS | 83164-33-4 |
Formula | C19H11F5N2O2 |
Molecular weight | 394,29 g/mol |
Quantity | 1X1ML |
Concentration | 100 µg/ml |
Solvent | Acetone |
storage conditions | 4 °C |
CoA / MSDS | Retrieve CoA Retrieve MSDS |
Product | Catalog No./ CAS No. | Quantity | Price | |
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D3-Diflufenican solution | 677492 | 1X1ML | Please log in. | |
685900 | 1X10MG | Please log in. | ||
Diflufenican solution | 673787 | 1X1ML | ||
ISO 17034 Reference Material | 673830 | 1X100MG | Please log in. | |
Diflufenican solution | 675181 | 1X1ML | Please log in. | |
Diflufenican solution | 680441 | 1X1ML | ||
Diflufenican solution | 688953 | 1X10ML | ||
ISO 17034 Certified Reference Material | 692214 | 1X50MG | Please log in. |
Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 15.12.2024 |
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
Product name: | Diflufenican |
Catalog No.: | 680441 |
Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 2), H225 Eye irritation (Category 2), H319 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 |
Label elements | |
Pictogram | flamme flamme GHS07 exclam exclam |
Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. Precautionary statement(s) P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370 + P378 In case of fire: Use dry powder or dry sand to extinguish. P403 + P235 Store in a well-ventilated place. Keep cool. Supplemental Hazard information (EU) EUH066 Repeated exposure may cause skin dryness or cracking. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. | |
COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Formula : C3H6O Molecular Weight : 58,08 g/mol CAS-No. : 67-64-1 EC-No. : 200-662-2 Index-No. : 606-001-00-8 Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration Acetone CAS-No. EC-No. Index-No. 67-64-1 200-662-2 606-001-00-8 Flam. Liq. 2; Eye Irrit. 2; STOT SE 3; H225, H319, H336 <= 100 % Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration Acetone CAS-No. EC-No. Index-No. 67-64-1 200-662-2 606-001-00-8 F, Xi, R11 - R36 - R66 - R67 <= 100 % |
Formula | C19H11F5N2O2 |
Molecular Weight (g/mol) | 394.29 |
CAS-No. | 83164-33-4 |
FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers. |
ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13. |
HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510): Flammable liquids 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Impervious clothing, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engine protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. |
PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid, clear Colour: colourless b) Odour no data available c) Odour Threshold no data available d) pH no data available e) Melting point/freezingpoint Melting point/range: -94 °C f) Initial boiling point and boiling range 56 °C at 1.013 hPa g) Flash point -17,0 °C - closed cup h) Evapouration rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits Upper explosion limit: 13 %(V) Lower explosion limit: 2 %(V) k) Vapour pressure 533,3 hPa at 39,5 °C 245,3 hPa at 20,0 °C l) Vapour density no data available m) Relative density 0,791 g/mL at 25 °C n) Water solubility completely miscible o) Partition coefficient: noctanol/water log Pow: -0,24 p) Auto-ignition temperature 465,0 °C q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available 9.2 Other safety information Surface tension 23,2 mN/m at 20,0 °C |
STABILITY AND REACTIVITY | 10.1 Reactivity no data available 10.2 Chemical stability no data available 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides In the event of fire: see section 5 |
TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 5,800 mg/kg(Acetone) Remarks: Behavioral:Altered sleep time (including change in righting reflex). Behavioral:Tremor. Behavioral:Headache. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. LC50 Inhalation - Rat - 8 h - 50,100 mg/m3(Acetone) Remarks: Drowsiness Dizziness Unconsciousness LD50 Dermal - Guinea pig - 7,426 mg/kg(Acetone) Skin corrosion/irritation Skin - Rabbit(Acetone) Result: Mild skin irritation - 24 h Serious eye damage/eye irritation Eyes - Rabbit(Acetone) Result: Eye irritation - 24 h Respiratory or skin sensitisation - Guinea pig(Acetone) Result: Does not cause skin sensitisation. Germ cell mutagenicity No data available(Acetone) Carcinogenicity This product is or contains a component that is not classifiable as to its classification.(Acetone) (Acetone) IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available(Acetone) Specific target organ toxicity - single exposure May cause drowsiness or dizziness.(Acetone) Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available(Acetone) Additional Information RTECS: Not available To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.(Acetone) Kidney - Irregularities - Based on Human Evidence(Acetone) Skin - Dermatitis - Based on Human Evidence(Acetone) |
ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 5,540 mg/l - 96 h(Acetone) Toxicity to daphnia and other aquatic invertebrates LC50 - Daphnia magna (Water flea) - 8,800 mg/l - 48 h(Acetone) Toxicity to algae Remarks: No data available 12.2 Persistence and degradability Biodegradability Result: 91 % - Readily biodegradable. (OECD Test Guideline 301B) 12.3 Bioaccumulative potential Does not bioaccumulate. 12.4 Mobility in soil No data available(Acetone) 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects No data available |
DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber b highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. |
TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 1090 IMDG: 1090 IATA: 1090 14.2 UN proper shipping name ADR/RID: ACETONE IMDG: ACETONE IATA: Acetone 14.3 Transport hazard class(es) ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user no data available |
REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out |
OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |