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Cyproconazole

ISO 17034 Reference Material

Item number673868
CAS94361-06-5
FormulaC15H18ClN3O
Molecular weight291,78 g/mol
Quantity 1X100MG
storage conditions4 °C
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Cyproconazole

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ISO 17034 Reference Material

Cyproconazole

Cyproconazole

673868
94361-06-5

1X100MG

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Cyproconazole solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Cyproconazole solution

673926
94361-06-5

1X5ML

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ISO 17034 Certified Reference Material

Cyproconazole

Cyproconazole

691528
94361-06-5

1X50MG

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 08.09.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Cyproconazole
Catalog No.:673868
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity - Oral Category 3 - (H301)
Reproductive toxicity Category 1B - (H360D)
Specific target organ toxicity — repeated exposure
Acute aquatic toxicity Category 1 - (H400)
Chronic aquatic toxicity Category 1 - (H410)
Label elements
PictogramGHS07 exclam
exclam
GHS08 silhouete
silhouete
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2. Label elements
619-020-1
Contains Cyproconazole (ISO)

Signal word - Danger

Hazard statements
H301 - Toxic if swallowed
H360D - May damage the unborn child
H373 - May cause damage to organs through prolonged or repeated exposure
H410 - Very toxic to aquatic life with long lasting effects
Precautionary Statements - EU (§28, 1272/2008)
P201 - Obtain special instructions before use
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor
P308 + P313 - IF exposed or concerned: Get medical advice/attention
P391 - Collect spillage

2.3. Other hazards
No information available.

This substance does not meet the PBT/vPvB criteria of REACH.
Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Chemical name
Cyproconazole (ISO) 94361-06-5

This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59
FormulaC15H18ClN3O
Molecular Weight (g/mol)291.78
CAS-No.94361-06-5
FIRST AID MEASURES4.1. Description of first aid measures
General advice Show this safety data sheet to the doctor in attendance.

Inhalation
Remove to fresh air.

Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a doctor

Skin contact
Wash skin with soap and water. In the case of skin irritation or allergic reactions see a doctor.

Ingestion
Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person. Get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms No information available.

4.3. Indication of any immediate medical attention and special treatment needed
Note to doctors Treat symptomatically


























FIRE-FIGHTING MEASURES5.1. Extinguishing media

Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Large Fire
CAUTION: Use of water spray when fighting fire may be inefficient.

Unsuitable extinguishing media
Do not scatter spilled material with high pressure water streams.

5.2. Special hazards arising from the substance or mixture

Specific hazards arising from the chemical
No information available.

5.3. Advice for firefighters
Special protective equipment and precautions for fire-fighters
Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.
Use personal protection equipment
ACCIDENTAL RELEASE MEASURES6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions
Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas.

Other information
Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

6.2. Environmental precautions
Environmental precautions See Section 12 for additional Ecological Information.

6.3. Methods and material for containment and cleaning up

Methods for containment
Prevent further leakage or spillage if safe to do so.


Methods for cleaning up
Take up mechanically, placing in appropriate containers for disposal.

Prevention of secondary hazards
Clean contaminated objects and areas thoroughly observing environmental regulations.

6.4. Reference to other sections
Reference to other sections See section 8 for more information. See section 13 for more information
HANDLING AND STORAGE7.1. Precautions for safe handling

Advice on safe handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Remove
contaminated clothing and shoes. Ensure adequate ventilation.

General hygiene considerations
Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this
product. Wash hands before breaks and after work. Wear suitable gloves and eye, face
protection. Wash hands before breaks and immediately after handling the product.

7.2. Conditions for safe storage, including any incompatibilities
Storage Conditions

Please refer to the manufacturers certificate for specific storage and transport temperature
conditions.

Store only in the original receptacle unless other advice is given on the CoA.
Keep containers tightly closed in a dry, cool and well ventilated place. Keep out of the reach
of children. Store locked up.



7.3. Specific end use
Risk Management Methods (RMM) The information required is contained in this Safety Data Sheet.
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1. Control parameters
Exposure Limits
This product, as supplied, does not contain any hazardous materials with occupational
exposure limits established by the region specific regulatory bodies.

Biological occupational exposure limits
This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies

Derived No Effect Level (DNEL) - No information available.
Predicted No Effect Concentration (PNEC) - No information available.

8.2. Exposure controls

Personal protective equipment
Eye/face protection Avoid contact with eyes. Wear safety glasses with side shields (or goggles).

Hand protection
The protective gloves to be used must comply with the specifications of EC Directive
89/686/EEC and the related standard EN374. Wear protective Viton™ gloves. Wear suitable
gloves.

Skin and body protection
Wear suitable protective clothing.

Respiratory protection
No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.

General hygiene considerations
Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this
product. Wash hands before breaks and after work. Wear suitable gloves and eye/face
protection. Wash hands before breaks and immediately after handling the product.

Environmental exposure controls
Do not allow into any sewer, on the ground or into any body of water
PHYSICAL AND CHEMICAL PROPERTIESPhysical state Solid
Appearance Crystalline
Colour light brown
Odour Odourless.
Odour threshold No information available

Property Values Remarks • Method
Melting point / freezing point 106 - 107 °C None known
Initial boiling point and boiling range No data available None known
Flammability No data available None known
Flammability Limit in Air None known
Upper flammability or explosive limits No data available
Lower flammability or explosive limits No data available
Flash point No data available None known
Autoignition temperature No data available None known
Decomposition temperature 299 °C None known
pH No data available None known
pH (as aqueous solution) No data available No information available
Kinematic viscosity No data available None known
Dynamic viscosity No data available None known
Water solubility 93 mg/l @ 20 °C
Solubility(ies) Acetone, Ethyl acetate, Methanol
Partition coefficient 3.1 None known
Vapour pressure No data available None known
Relative density 1.25 @ 21 °C
Bulk density No data available
Liquid Density No data available
Relative vapour density No data available None known
Particle characteristics
Particle Size No information available
Particle Size Distribution No information available


9.2. Other information
Molecular weight 291.77
Molecular formula C15 H18 Cl N3 O

9.2.1. Information with regards to physical hazard classes
Not applicable 299 °C 299 °C

9.2.2. Other safety characteristics
No information available
















STABILITY AND REACTIVITY10.1. Reactivity
Reactivity No information available.

10.2. Chemical stability
Stability Stable under normal conditions.
Explosion data
Sensitivity to mechanical impact None.
Sensitivity to static discharge None.

10.3. Possibility of hazardous reactions
Possibility of hazardous reactions None under normal processing.

10.4. Conditions to avoid
Conditions to avoid None known based on information supplied.

10.5. Incompatible materials
Incompatible materials None known based on information supplied.
Hazardous decomposition products None known based on information supplied
TOXICOLOGICAL INFORMATION11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Information on likely routes of exposure

Product Information
Inhalation - Specific test data for the substance or mixture is not available.
Eye contact - Specific test data for the substance or mixture is not available.
Ingestion - Specific test data for the substance or mixture is not available. Toxic if swallowed. (based on components).

Symptoms related to the physical, chemical and toxicological characteristics
Symptoms - No information available

Numerical measures of toxicity

Acute toxicity

Component Information
Chemical name Oral LD50 Dermal LD50 Inhalation LC50
Cyproconazole (ISO) = 200 mg/kg (Rat) > 2000 mg/kg ( Rat ) > 5650 mg/m3 ( Rat ) 4 h

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation - Based on available data, the classification criteria are not met.
Serious eye damage/eye irritation - No information available.
Respiratory or skin sensitisation - No information available.
Germ cell mutagenicity - No information available.
Carcinogenicity - No information available
Reproductive toxicity - Contains a known or suspected reproductive toxin. Classification based on data available
for ingredients. May damage fertility or the unborn child.


The table below indicates ingredients above the cut-off threshold considered as relevant which are listed as reproductive toxins.

Chemical name European Union
Cyproconazole (ISO) Repr. 1B

STOT - single exposure No information available.
STOT - repeated exposure May cause damage to organs through prolonged or repeated exposure

H373 - May cause damage to the following organs through prolonged or repeated exposure: Liver.

Aspiration hazard - No information available.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties
Endocrine disrupting properties - No information available.

11.2.2. Other information
Other adverse effects - No information available























ECOLOGICAL INFORMATION12.1. Toxicity
Ecotoxicity - Very toxic to aquatic life with long lasting effects.

Chemical name Algae/aquatic plants Fish Toxicity to Crustacea
microorganisms
Cyproconazole (ISO) EC50: 0.099 mg/l LC50: 19 mg/l - EC50: > 22 mg/l (Daphnia
(Scenedemus (Oncorhynchus mykiss, magna, 72h)
subspicatus, 72h) 96h)


12.2. Persistence and degradability
Persistence and degradability No information available.

12.3. Bioaccumulative potential
Bioaccumulation There is no data for this product.

12.4. Mobility in soil
Mobility in soil No information available.

12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment - No information available

12.6. Endocrine disrupting properties
Endocrine disrupting properties - No information available.

12.7. Other adverse effects - No information available
DISPOSAL CONSIDERATIONS13.1. Waste treatment methods
Waste from residues/unused products
Dispose of in accordance with local regulations. Dispose of waste in accordance with
environmental legislation.
Contaminated packaging Do not reuse empty containers
TRANSPORT INFORMATIONIATA
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Cyproconazole (ISO))
14.3 Transport hazard class(es) 6.1
14.4 Packing group III
Description UN2811, Toxic solid, organic, n.o.s. (Cyproconazole (ISO)), 6.1, III
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions A3, A5
ERG Code 6L

IMDG
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Cyproconazole (ISO))
14.3 Transport hazard class(es) 6.1
14.4 Packing group III
Description UN2811, Toxic solid, organic, n.o.s. (Cyproconazole (ISO)), 6.1, III, Marine pollutant
14.5 Marine pollutant P
Environmental hazards
Yes

14.6 Special precautions for user
Special Provisions 223, 274
EmS-No. F-A, S-A No information available
14.7 Maritime transport in bulk
according to IMO instruments
No information available

RID
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Cyproconazole (ISO))
14.3 Transport hazard class(es) 6.1
14.4 Packing group III
Description UN2811, Toxic solid, organic, n.o.s. (Cyproconazole (ISO)), 6.1, III, Environmentally
Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 614
Classification code T2

ADR
14.1 UN number or ID number UN2811
14.2 UN proper shipping name Toxic solid, organic, n.o.s. (Cyproconazole (ISO))
14.3 Transport hazard class(es) 6.1
14.4 Packing group III
Description UN2811, Toxic solid, organic, n.o.s. (Cyproconazole (ISO)), 6.1, III, (E), Environmentally
Hazardous
14.5 Environmental hazards Yes
14.6 Special precautions for user
Special Provisions 274, 614
Classification code T2
Tunnel restriction code (E)
REGULATORY INFORMATIONThis material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
Disclaimer
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to the best of our knowledge. The user must determine the suitability of the information for its particular purpose, ensure compliance
with existing laws and regulations, and be aware that other or additional safety or performance considerations may arise when using, handling and or storing the material. The information in this SDS does not purport to be all inclusive or a
guarantee as to the properties of the material supplied, and should be used only as a guide. HPC makes no warranties or representations as to the accuracy and completeness of the information contained herein, shall not be held responsible for the suitability of this information for the users intended purposes or the consequences of such use, and shall not be liable for any damage or loss, howsoever arising, direct or otherwise.
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!