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Clodinafop-propargyl
ISO 17034 Reference Material
| Item number | 681371 |
| CAS | 105512-06-9 |
| Formula | C17H13ClFNO4 |
| Molecular weight | 349,74 g/mol |
| Quantity | 1X100MG |
| storage conditions | 4 °C |
| CoA / MSDS | Retrieve CoA Retrieve MSDS |
Price | Please log in. |
Part of Product groups:
Product Variations:
Product | Catalog No./ CAS No. | Quantity | Price | |
|---|---|---|---|---|
Clodinafop-propargyl solution |  | 674600 | 1X5ML | Please log in. |
ISO 17034 Reference Material |  | 681371 | 1X100MG | Please log in. |
ISO 17034 Certified Reference Material |  | 690680 | 1X50MG | Please log in. |
| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 22.12.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | Clodinafop-propargyl |
| Catalog No.: | 681371 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 4), H332 Skin sensitisation (Category 1), H317 Specific target organ toxicity - repeated exposure (Category 2), H373 Short-term (acute) aquatic hazard (Category 1), H400 Long-term (chronic) aquatic hazard (Category 1), H410 |
| Label elements | |
| Pictogram | GHS07 exclam exclam GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red |
| Label elements Labelling according Regulation (EC) No 1272/2008 Signal word: Warning Hazard statement(s) H302 + H332 Harmful if swallowed or if inhaled. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P273 Avoid release to the environment. P280 Wear protective gloves. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P314 Get medical advice/ attention if you feel unwell. Supplemental Hazard Statements: none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. | |
| COMPOSITION/INFORMATION ON INGREDIENTS | |
| Formula | C17H13ClFNO4 |
| Molecular Weight (g/mol) | 349.74 |
| CAS-No. | 105512-06-9 |
| FIRST AID MEASURES | SECTION 4: First aid measures 4.1 Description of first aid measures General advice: Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact: Wash off with soap and plenty of water. Consult a physician. In case of eye contact: Flush eyes with water as a precaution. If swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. |
| FIRE-FIGHTING MEASURES | SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture: Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas, Hydrogen fluoride 5.3 Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information: No data available |
| ACCIDENTAL RELEASE MEASURES | SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. 6.2 Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up: Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. |
| HANDLING AND STORAGE | SECTION 7: Handling and storage 7.1 Precautions for safe handling: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. 7.2 Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. Store in cool place. |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | SECTION 8: Exposure controls/personal protection 8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection: Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Body Protection: Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. |
| PHYSICAL AND CHEMICAL PROPERTIES | SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties a) Appearance Form: crystalline Colour: beige b) Odour: No data available c) Odour Threshold: No data available d) pH: 4,1 at 25 °C e) Melting point/freezing point: 48,2 - 57,1 °C f) Initial boiling point and boiling range: No data available g) Flash point: No data available h) Evaporation rate: No data available i) Flammability (solid, gas): No data available j) Upper/lower flammability or explosive limits No data available k) Vapour pressure: No data available l) Vapour density: No data available m) Relative density: 1,360 g/cm3 at 20 °C n) Water solubility: No data available o) Partition coefficient: n-octanol/water log Pow: 3,9 at 25 °C p) Auto-ignition temperature: No data available q) Decomposition temperature: No data available r) Viscosity: No data available s) Explosive properties: No data available t) Oxidizing properties: No data available 9.2 Other safety information: No data available |
| STABILITY AND REACTIVITY | SECTION 10: Stability and reactivity 10.1 Reactivity: No data available 10.2 Chemical stability: Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions: No data available 10.4 Conditions to avoid: No data available 10.5 Incompatible materials: Strong oxidizing agents 10.6 Hazardous decomposition products: Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas, Hydrogen fluoride Other decomposition products - No data available In the event of fire: see section 5 |
| TOXICOLOGICAL INFORMATION | SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity: LD50 Oral - Rat - male - 1.392 mg/kg Remarks: (HSDB) LC50 Inhalation - Rat - 4 h - 2.325 mg/m3 Remarks: (HSDB) LD50 Dermal - Rabbit - > 2.000 mg/kg Remarks: (HSDB) Skin corrosion/irritation Skin: - Rabbit Result: No skin irritation Serious eye damage/eye irritation: Eyes - Rabbit Result: No eye irritation Respiratory or skin sensitisation: May cause an allergic skin reaction. Germ cell mutagenicity: No data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity: No data available Specific target organ toxicity: - single exposure: No data available - repeated exposure: No data available Aspiration hazard: No data available |
| ECOLOGICAL INFORMATION | SECTION 12: Ecological information 12.1 Toxicity Toxicity to fish: LC50 - Lepomis macrochirus (Bluegill) - 0,12 - 0,26 mg/l - 96,0 h Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - > 2 mg/l - 48 h Toxicity to algae: EC50 - Desmodesmus subspicatus (green algae) - 3,9 - 8,4 mg/l - 72 h 12.2 Persistence and degradability: No data available 12.3 Bioaccumulative potential: No data available 12.4 Mobility in soil: No data available 12.5 Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects: Very toxic to aquatic life with long lasting effects. No data available. |
| DISPOSAL CONSIDERATIONS | SECTION 13: Disposal considerations 13.1 Waste treatment methods Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. Contaminated packaging: Dispose of as unused product. |
| TRANSPORT INFORMATION | SECTION 14: Transport information 14.1 UN number ADR/RID: 3077 IMDG: 3077 IATA: 3077 14.2 UN proper shipping name ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Clodinafoppropargyl) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Clodinafoppropargyl) IATA: Environmentally hazardous substance, solid, n.o.s. (Clodinafop-propargyl) 14.3 Transport hazard class(es) ADR/RID: 9 IMDG: 9 IATA: 9 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: yes |
| REGULATORY INFORMATION | SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out. |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |