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1H-Benzotriazole

Item number673969
CAS95-14-7
FormulaC6H5N3
Molecular weight119,12 g/mol
Quantity 1X100MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
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1H-Benzotriazole

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1H-Benzotriazole

1H-Benzotriazole

673969
95-14-7

1X100MG

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1H-Benzotriazole solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

1H-Benzotriazole solution

676968
95-14-7

1X1ML

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D4-1H-Benzotriazole

D4-1H-Benzotriazole

681254
1185072-03-0

1X10MG

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D4-1H-Benzotriazole solution
Concentration: 100 µg/ml
Solvent: Methanol

D4-1H-Benzotriazole solution

681255
1185072-03-0

1X1ML

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D4-1H-Benzotriazole solution
Concentration: 10.0 µg/ml
Solvent: Methanol

D4-1H-Benzotriazole solution

681256
1185072-03-0

1X10ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 26.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:1H-Benzotriazole
Catalog No.:673969
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Acute toxicity, Inhalation (Category 4), H332
Eye irritation (Category 2), H319
Chronic aquatic toxicity (Category 3), H412 Classification according to EU Directives 67/548/EEC or 1999/45/EC
Xn Harmful R20/22, R36, R52/53
Label elements
PictogramGHS07 exclam
exclam
Signal word Warning
Hazard statement(s)
H302 + H332 Harmful if swallowed or if inhaled
H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
P273 Avoid release to the environment.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard
Statements
none
2.3 Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : 1,2,3-Benzotriazole
Formula : C6H5N3
Molecular Weight : 119,12 g/mol
CAS-No. : 95-14-7
EC-No. : 202-394-1
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
Benzotriazole
CAS-No.
EC-No.
95-14-7
202-394-1
Acute Tox. 4; Eye Irrit. 2;
Aquatic Chronic 3; H302 +
H332, H319, H412
<= 100 %
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
Benzotriazole
CAS-No.
EC-No.
95-14-7
202-394-1
Xn, R20/22 - R36 - R52/53 <= 100 %
FormulaC6H5N3
Molecular Weight (g/mol)119.12
CAS-No.95-14-7
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx)
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: solid
Colour: beige
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing
point
Melting point/range: 94 - 99
STABILITY AND REACTIVITY10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
Exposure to light may affect product quality.
10.5 Incompatible materials
Strong oxidizing agents, Heavy metals
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - rat - 560 mg/kg
LC50 Inhalation - rat - 4 h - 1,4 mg/l
LD50 Dermal - rat - > 1.000 mg/kg
Skin corrosion/irritation
Skin - rabbit
Result: No skin irritation
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available Germ cell mutagenicity
rat
Embryo
Morphological transformation.
Carcinogenicity
Carcinogenicity - rat - Oral
Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Brain and Coverings:Tumors.
Carcinogenicity - mouse - Oral
Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Lungs, Thorax, or Respiration:Tumors.
Lungs, Thorax, or Respiration:Bronchiogenic carcinoma.
This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC,
ACGIH, NTP, or EPA classification.
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: DM1225000
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Lepomis macrochirus (Bluegill) - 25 mg/l - 96,0 h
Toxicity to daphnia and
other aquatic
invertebrates
EC50 - Daphnia magna (Water flea) - 91 mg/l - 48 h
12.2 Persistence and degradability
Biodegradability Result: - Not readily biodegradable.
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
Harmful to aquatic life with long lasting effects.
no data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: - IMDG: - IATA: -
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
14.4 Packaging group
ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
no data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!