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Item number | 676469 |
CAS | 62-53-3 |
Formula | C6H7N |
Molecular weight | 93,13 g/mol |
Quantity | 1X1ML |
storage conditions | 4 °C |
CoA / MSDS | Retrieve CoA Retrieve MSDS |
Product | Catalog No./ CAS No. | Quantity | Price | |
---|---|---|---|---|
676469 | 1X1ML | Please log in. | ||
Aniline solution | 684878 | 1X5ML | Please log in. | |
674819 | 1X100MG | Please log in. |
Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 27.12.2024 |
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
Product name: | Aniline |
Catalog No.: | 676469 |
Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 3), H331 Acute toxicity, Dermal (Category 3), H311 Serious eye damage (Category 1), H318 Skin sensitisation (Category 1), H317 Germ cell mutagenicity (Category 2), H341 Carcinogenicity (Category 2), H351 Specific target organ toxicity - repeated exposure (Category 1), H372 Specific target organ toxicity - repeated exposure (Category 1), Blood, H372 Acute aquatic toxicity (Category 1), H400 Chronic aquatic toxicity (Category 1), H410 Classification according to EU Directives 67/548/EEC or 1999/45/EC T Toxic R23/24/25, R48/23/24/25 R40 R68 Xi Irritant R41 R43 N Dangerous for the environment R50 |
Label elements | |
Pictogram | GHS05 acid acid GHS06 skull skull GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red |
Signal word Danger Hazard statement(s) H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H372 Causes damage to organs (Blood) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P261 Avoid breathing vapours. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P311 Call a POISON CENTER or doctor/ physician. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Rapidly absorbed through skin. | |
COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Formula : C6H7N Molecular weight : 93,13 g/mol CAS-No. : 62-53-3 EC-No. : 200-539-3 Index-No. : 612-008-00-7 Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration Aniline CAS-No. EC-No. Index-No. 62-53-3 200-539-3 612-008-00-7 Acute Tox. 3; Eye Dam. 1; Skin Sens. 1; Muta. 2; Carc. 2; STOT RE 1; Aquatic Acute 1; Aquatic Chronic 1; H301 + H311 + H331, H317, H318, H341, H351, H372, H410 <= 100 % Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration Aniline CAS-No. EC-No. Index-No. 62-53-3 200-539-3 612-008-00-7 T, N, Carc.Cat.3, Mut.Cat.3, R23/24/25 - R40 - R41 - R43 - R48/23/24/25 - R68 - R50 <= 100 % |
Formula | C6H7N |
Molecular Weight (g/mol) | 93.13 |
CAS-No. | 62-53-3 |
FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx) 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers. |
ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13 |
HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Light sensitive. Store under inert gas. Handle under inert gas. Protect from moisture. Storage class (TRGS 510): Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. |
PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid b) Odour No data available c) Odour Threshold No data available d) pH 8,8 at 36 g/l at 20 °C e) Melting point/freezing point Melting point/range: -6 °C - lit. f) Initial boiling point and boiling range 184 °C - lit. g) Flash point 70 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 23 %(V) Lower explosion limit: 1,3 %(V) k) Vapour pressure 0,49 hPa at 20 °C 0,8 hPa at 20 °C l) Vapour density 3,22 - (Air = 1.0) m) Relative density 1,022 g/mL at 25 °C n) Water solubility soluble o) Partition coefficient: noctanol/ water log Pow: 0,91 p) Auto-ignition temperature No data available q) Decomposition temperature 190 °C - r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Surface tension 42,12 mN/m at 25 °C Relative vapour density 3,22 - (Air = 1.0) |
STABILITY AND REACTIVITY | 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Oxidizing agents, Iron and iron salts., Zinc 10.6 Hazardous decomposition products Other decomposition products - No data available In the event of fire: see section 5 |
TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 250 mg/kg LC50 Inhalation - Mouse - 4 h - 248 ppm LD50 Dermal - Rabbit - 836 mg/kg Skin corrosion/irritation Skin - Rabbit Result: No skin irritation Serious eye damage/eye irritation Eyes - Rabbit Result: Severe eye irritation Respiratory or skin sensitisation May cause sensitisation by skin contact. Germ cell mutagenicity Laboratory experiments have shown mutagenic effects. In vitro tests showed mutagenic effects Carcinogenicity This product is or contains a component that has been reported to be possibly carcinogenic based on its IARC, ACGIH, NTP, or EPA classification. Limited evidence of carcinogenicity in animal studies IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Aniline) Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure Causes damage to organs through prolonged or repeated exposure. - Blood Aspiration hazard No data available Additional Information RTECS: BW6650000 Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer., Cyanosis, Headache, Vomiting, Nausea, Incoordination., fatigue, Dizziness, Drowsiness, Confusion., Weakness, Unconsciousness, Symptoms may be delayed. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 10,6 mg/l - 96,0 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 80 - 380 mg/l - 48 h semi-static test EC50 - Daphnia magna (Water flea) - 0,16 mg/l - 48 h Toxicity to algae EC50 - SELENASTRUM - 19 mg/l - 72 h 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 30 d Result: 90 % - Readily biodegradable. (OECD Test Guideline 301D) 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Very toxic to aquatic life with long lasting effects. |
DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. |
TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 1547 IMDG: 1547 IATA: 1547 14.2 UN proper shipping name ADR/RID: ANILINE IMDG: ANILINE IATA: Aniline 14.3 Transport hazard class(es) ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: no 14.6 Special precautions for user No data available |
REGULATORY INFORMATION | This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No data available 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |