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Ametryn

ISO 17034 Reference Material

Item number672810
CAS834-12-8
FormulaC9H17N5S
Molecular weight227,30 g/mol
Quantity 1X250MG
storage conditions4 °C
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ISO 17034 Reference Material

Ametryn

Ametryn

672810
834-12-8

1X250MG

On request

Ametryn solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Ametryn solution

673195
834-12-8

1X5ML

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ISO 17034 Certified Reference Material

Ametryn

Ametryn

691781
834-12-8

1X100MG

On request

Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 27.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Ametryn
Catalog No.:672810
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
N Dangerous for the
environment
R50/53
Xn Harmful R22
Label elements
PictogramGHS07 exclam
exclam
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
Signal word Warning
Hazard statement(s)
H302 Harmful if swallowed.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P273 Avoid release to the environment.
P501 Dispose of contents/ container to an approved waste disposal plant.
Supplemental Hazard
Statements
none
2.3 Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : 2-Ethylamino-4-isopropylamino-6-methylthio-1,3,5-triazine
Formula : C9H17N5S
Molecular Weight : 227,33 g/mol
CAS-No. : 834-12-8
EC-No. : 212-634-7
Index-No. : 613-010-00-0
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
2-Ethylamino-4-isopropylamino-6-methylthio-1,3,5-triazine
CAS-No.
EC-No.
Index-No.
834-12-8
212-634-7
613-010-00-0
Acute Tox. 4; Aquatic Acute 1;
Aquatic Chronic 1; H302,
H410
<= 100 %
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
2-Ethylamino-4-isopropylamino-6-methylthio-1,3,5-triazine
CAS-No.
EC-No.
Index-No.
834-12-8
212-634-7
613-010-00-0
Xn, N, R22 - R50/53 <= 100 %
FormulaC9H17N5S
Molecular Weight (g/mol)227.30
CAS-No.834-12-8
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx), Sulphur oxides
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
Use respirators and components tested and approved under appropriate government standards
such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: powder
Colour: white
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing
point
Melting point/range: 83 - 87 °C at 1.013 hPa - OECD Test Guideline 102
f) Initial boiling point and
boiling range
346 °C at 1.013,250 hPa - OECD Test Guideline 103
g) Flash point no data available
h) Evapouration rate no data available
i) Flammability (solid, gas) The product is not flammable.
j) Upper/lower
flammability or
explosive limits
no data available
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density 1.180 kg/m3 at 22 °C
n) Water solubility 0,191 g/l at 20 °C - OECD Test Guideline 105
o) Partition coefficient: noctanol/
water
log Pow: 3 at 20 °C
p) Auto-ignition
temperature
> 450 °C at 1.013 hPa
q) Decomposition
temperature
no data available
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties The product has been shown not to be oxidising in a test following Directive
67/548/EEC (Method A17, oxidising properties).
9.2 Other safety information
Surface tension 53,7 mN/m at 21 °C
Dissociation constant 4,07 at 20 °C
STABILITY AND REACTIVITY10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - rat - male and female - 1.626 mg/kg
(OECD Test Guideline 401)
LC50 Inhalation - rat - male and female - 4 h - > 2,22 mg/l
(OECD Test Guideline 403)
LD50 Dermal - rabbit - 8.160 mg/kg
Skin corrosion/irritation
Skin - rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
Serious eye damage/eye irritation
Eyes - rabbit
Result: No eye irritation
(OECD Test Guideline 405)
Respiratory or skin sensitisation
Maximisation Test - guinea pig
Result: Does not cause skin sensitisation.
(Directive 67/548/EEC, Annex V, B.6.)
Germ cell mutagenicity
Ames test
S. typhimurium
Result: negative
OECD Test Guideline 486
rat - male
Result: negative
DNA damage DNA repair
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Reproductive toxicity - rat - Oral
Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of
implants). Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus). Effects on Embryo
or Fetus: Other effects to embryo.
Reproductive toxicity - mouse - Oral
Effects on Fertility: Post-implantation mortality (e.g., dead and/or resorbed implants per total number of
implants). Effects on Embryo or Fetus: Extra embryonic structures (e.g., placenta, umbilical cord). Effects
on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted fetus).
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: XY9100000
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish static test LC50 - Pimephales promelas (fathead minnow) - 16 mg/l - 96 h
Toxicity to daphnia and
other aquatic
invertebrates
static test EC50 - Daphnia magna (Water flea) - 28 mg/l - 48 h
Toxicity to algae static test EC50 - Desmodesmus subspicatus (Scenedesmus subspicatus) -
0,0032 mg/l - 72 h
(OECD Test Guideline 201)
Toxicity to bacteria Growth inhibition EC50 - Sludge Treatment - > 1.000 mg/l - 3 h
(OECD Test Guideline 209)
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 5,89 % - Not readily biodegradable.
(OECD Test Guideline 301B)
12.3 Bioaccumulative potential
Bioaccumulation Lepomis macrochirus (Bluegill) - 38 d
Bioconcentration factor (BCF): 61
(OECD Test Guideline 305)
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
Very toxic to aquatic life with long lasting effects.
no data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 3077 IMDG: 3077 IATA: 3077
14.2 UN proper shipping name
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-Ethylamino-4-
isopropylamino-6-methylthio-1,3,5-triazine)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2-Ethylamino-4-
isopropylamino-6-methylthio-1,3,5-triazine)
IATA: Environmentally hazardous substance, solid, n.o.s. (2-Ethylamino-4-isopropylamino-6-
methylthio-1,3,5-triazine)
14.3 Transport hazard class(es)
ADR/RID: 9 IMDG: 9 IATA: 9
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes
14.6 Special precautions for user
Further information
EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination
packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!