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3-Chlorophenol

Item number684760
CAS108-43-0
FormulaC6H5ClO
Molecular weight128,56 g/mol
Quantity 1X500MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
Retrieve MSDS
3-Chlorophenol

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Part of Product groups:
Product Variations:

Product

Catalog No./ CAS No.

Quantity

Price

2-Chlorophenol

2-Chlorophenol

679246
95-57-8

1X500MG

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2-Chlorophenol solution
Concentration: 10.0 µg/ml
Solvent: Methanol

10 µg/ml Methanol

2-Chlorophenol solution

681565
95-57-8

1X10ML

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2-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Methanol

2-Chlorophenol solution

681684
95-57-8

1X5ML

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3-Chlorophenol

3-Chlorophenol

684760
108-43-0

1X500MG

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3-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Methanol

3-Chlorophenol solution

689360
108-43-0

1X5ML

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4-Chlorophenol

4-Chlorophenol

673138
106-48-9

1X500MG

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4-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Methanol

100 µg/ml Methanol

4-Chlorophenol solution

675393
106-48-9

1X5ML

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D4-2-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Acetone

D4-2-Chlorophenol solution

675981
93951-73-6

1X1ML

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D4-2-Chlorophenol

D4-2-Chlorophenol

680097
93951-73-6

1X25MG

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D4-2-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Methanol

D4-2-Chlorophenol solution

684771
93951-73-6

1X1ML

On request

D4-4-Chlorophenol

D4-4-Chlorophenol

684774
285132-91-4

1X10MG

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D4-4-Chlorophenol solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

D4-4-Chlorophenol solution

684775
285132-91-4

1X1ML

On request

Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 23.11.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:3-Chlorophenol
Catalog No.:684760
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H312 Harmful in contact with skin.
Acute Tox. 4 H332 Harmful if inhaled.
Label elements
PictogramGHS05 acid
acid
GHS07 exclam
exclam
GHS09 Aquatic-pollut-red
Aquatic-pollut-red
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation
Hazard pictograms
Signal word Warning
Hazard statements
H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves / protective clothing.
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P321 Specific treatment (see on this label).
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Chemical characterisation: Substances
CAS No. Description
108-43-0 3-Chlorophenol
Identification number(s) None
EC number: 203-582-6
Index number: 604-008-00-0
RTECS: SK 2450000
Additional information: For the wording of the listed hazard phrases refer to section 16
FormulaC6H5ClO
Molecular Weight (g/mol)128.56
CAS-No.108-43-0
FIRST AID MEASURES4.1 Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48
hours after the accident is recommended.
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient in recovery position for transport
Seek medical treatment.
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Seek medical treatment.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing:
Rinse mouth. Do not induce vomiting.
Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
FIRE-FIGHTING MEASURES 5.1 Extinguishing media
Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.
5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
5.3 Advice for firefighters
Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Avoid formation of dust.
6.2 Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
HANDLING AND STORAGE7.1 Precautions for safe handling
Ensure good ventilation extraction at the workplace.
Remove dust thoroughly.
Store in cool, dry place in tightly closed receptacles.
Information about fire and explosion protection: No special measures required.
7.2 Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:
Please refer to the manufacturers certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
Information about storage in one common storage facility: Store away from foodstuffs.
Further information about storage conditions: Keep container tightly sealed.
7.3 Specific end use(s) No further relevant information available.
EXPOSURE CONTROLS/PERSONAL PROTECTIONAdditional information about design of technical facilities: No further data; see item 7.
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace: Not required.
Additional information: Lists used were valid at the time of SDS preparation.
8.2 Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
Material of gloves Fluorocarbon rubber (Viton)
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection: Safety glasses
PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Solid
Colour: Yellow
Odour: Phenol-like
Odour threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/freezing point: 33 °C
Initial boiling point and boiling range: 214 °C
Flash point: 112 °C
Flammability (solid, gas): Not determined.
Ignition temperature: 415 °C
Decomposition temperature: Not determined.
Auto-ignition temperature: Not determined.
Explosive properties: Not determined.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapour pressure at 20 °C: 0.23 hPa
Density at 20 °C: 1.268 g/cm³
Relative density Not determined.
Vapour density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with
water at 20 °C: 26 g/l
Partition coefficient: n-octanol/water: 2.5
Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
9.2 Other information No further relevant information available
STABILITY AND REACTIVITY 10.1 Reactivity Stable under normal conditions.
10.2 Chemical stability Stable under normal conditions
Thermal decomposition / conditions to be avoided:
Formation of toxic gases is possible during heating or in case of fire.
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid Heat.
10.5 Incompatible materials: Strong oxidizing agents.
10.6 Hazardous decomposition products:
Formation of toxic gases is possible during heating or in case of fire.
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
Harmful if swallowed, in contact with skin or if inhaled
LD/LC50 values relevant for classification:
Oral LD50 570 mg/kg (rat)
LD 50 (Intraperitoneal) 355 mg/kg (rat)
Primary irritant effect:
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/irritation Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.
ECOLOGICAL INFORMATION 12.1 Toxicity
Aquatic toxicity:
EC50/96h 29 mg/l (Algae)
LC50/96 h 4.24 mg/l (fish)
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Ecotoxicological effects:
Remark: Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (German Regulation) (Assessment by list): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
European waste catalogue
Waste disposal key numbers from EWC have to be assigned depending on origin and processing.
Uncleaned packaging:
Recommendation: Dispose of in accordance with national regulations.
TRANSPORT INFORMATION 14.1 UN-Number
ADR, IMDG, IATA UN2020
ADR 2020 CHLOROPHENOLS, SOLID, ENVIRONMENTALLY
HAZARDOUS
IMDG CHLOROPHENOLS, SOLID, MARINE POLLUTANT
IATA CHLOROPHENOLS, SOLID
14.3 Transport hazard class(es)
ADR, IMDG
Class 6.1 Toxic substances.
Label 6.1
IATA
Class 6.1 Toxic substances.
Label 6.1
14.4 Packing group
ADR, IMDG, IATA III
14.5 Environmental hazards: Environmentally hazardous substance, solid; Marine
Pollutant
Marine pollutant: Symbol (fish and tree)
Special marking (ADR): Symbol (fish and tree)
14.6 Special precautions for user Warning: Toxic substances.
Danger code (Kemler): 60
EMS Number: F-A,S-A
Stowage Category A
14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
Transport/Additional information:
ADR
Limited quantities (LQ) 5 kg
Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 1000 g
Transport category 2
Tunnel restriction code E
UN "Model Regulation": UN 2020 CHLOROPHENOLS, SOLID, 6.1, I I I ,
ENVIRONMENTALLY HAZARDOUS
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Directive 2012/18/EU
Named dangerous substances - ANNEX I Substance is not listed.
Seveso category E2 Hazardous to the Aquatic Environment
Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t
Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!