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2,4-Dinitrophenylhydrazine

Item number	687703
CAS	119-26-6
Formula	C6H6N4O4
Molecular weight	198,14 g/mol
Quantity	1X100MG
storage conditions	4 °C
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Product		Catalog No./ CAS No.	Quantity	Price
2,4-Dinitrophenylhydrazine		687703 119-26-6	1X100MG	Please log in.
2,4-Dinitrophenylhydrazine		692447 119-26-6	1X5G	Please log in.

Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 23.11.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	2,4-Dinitrophenylhydrazine
Catalog No.:	687703
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com
Emergency telephone number	HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours.
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Desensitized explosives (Category 1), H206 Acute toxicity, Oral (Category 4), H302
Label elements
Pictogram	flamme flamme GHS07 exclam exclam
	2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H206 Fire, blast or projection hazard; increased risk of explosion if desensitizing agent is reduced. H302 Harmful if swallowed. Precautionary statement(s) P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P212 Avoid heating under confinement or reduction of the desensitizing agent. P230 Keep wetted with water. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. P501 Dispose of contents/ container to an approved waste disposal plant. Supplemental Hazard information (EU) EUH044 Risk of explosion if heated under confinement. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Desensitized explosive
COMPOSITION/INFORMATION ON INGREDIENTS	3.1 Substances EC-No. : 204-309-3 Component Classification Concentration 2,4-Dinitrophenylhydrazine Expl. 1.1; Acute Tox. 4; H201, H302 >= 50 - < 70 %
Formula	C6H6N4O4
Molecular Weight (g/mol)	198.14
CAS-No.	119-26-6
FIRST AID MEASURES	4.1 Description of first-aid measures General advice Show this material safety data sheet to the doctor in attendance. If inhaled After inhalation: fresh air. In case of skin contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. In case of eye contact After eye contact: rinse out with plenty of water. Remove contact lenses. If swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES	5.1 Extinguishing media Suitable extinguishing media Water Foam Carbon dioxide (CO2) Dry powder Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx) Explosive decomposition possible on heating. Combustible. Development of hazardous combustion gases or vapours possible in the event of fire. 5.3 Advice for firefighters In the event of fire, wear self-contained breathing apparatus. 5.4 Further information Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. 6.2 Environmental precautions Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE	7.1 Precautions for safe handling Keep away from open flames, hot surfaces and sources of ignition. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Tightly closed and away from sources of ignition and heat. Observe national regulations. Light sensitive. Store under inert gas. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION	8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Change contaminated clothing. Preventive skin protection recommended. Wash hands after working with substance. Personal protective equipment Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses Skin protection This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L Body Protection protective clothing Respiratory protection required when dusts are generated Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Control of environmental exposure Do not let product enter drains.
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties a) Appearance Form: solid b) Odor: Odorless c) Odor Threshold No data available d) pH No data available e) Melting point/freezing point Melting point: 194 °C f) Initial boiling point and boiling range No data available g) Flash point Not applicable h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits No data available k) Vapor pressure No data available l) Vapor density No data available m) Relative density No data available n) Water solubility No data available o) Partition coefficient: n-octanol/water No data available p) Autoignition temperature No data available q) Decomposition temperature >160°C r) Viscosity No data available s) Explosive properties Explosive when dry., Risk of explosion if heated under confinement. t) Oxidizing properties No data available 9.2 Other safety information No data available
STABILITY AND REACTIVITY	10.1 Reactivity Risk of explosion if heated under confinement. The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed. 10.2 Chemical stability The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): water (35 %) 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid May be shock-sensitive if dry. no information available 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx) Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity No data available Skin corrosion/irritation No data available Serious eye damage/eye irritation No data available Respiratory or skin sensitization No data available Germ cell mutagenicity No data available Carcinogenicity IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available (2,4-Dinitrophenylhydrazine) Additional Information RTECS: MV3325000 The absorption of this product into the body may lead to the formation of methaemoglobine that, in sufficient concentration, causes cyanosis. (2,4-Dinitrophenylhydrazine) To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. (2,4-Dinitrophenylhydrazine)
ECOLOGICAL INFORMATION	12.1 Toxicity No data available 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available (2,4-Dinitrophenylhydrazine) 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects No data available
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods Product See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions
TRANSPORT INFORMATION	14.1 UN number ADR/RID: 3380 IMDG: 3380 IATA: 3380 14.2 UN proper shipping name ADR/RID: DESENSITIZED EXPLOSIVE, SOLID, N.O.S. (2,4-Dinitrophenylhydrazine) IMDG: DESENSITIZED EXPLOSIVE, SOLID, N.O.S. (2,4-Dinitrophenylhydrazine) IATA: Desensitized explosive, solid, n.o.s. (2,4-Dinitrophenylhydrazine) Passenger Aircraft: Not permitted for transport Cargo Aircraft: Not permitted for transport 14.3 Transport hazard class(es) ADR/RID: 4.1 IMDG: 4.1 IATA: 4.1 14.4 Packaging group ADR/RID: I IMDG: I IATA: - 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION	15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!