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2,3-Dibromopropanoic acid Solution (Solvent: tert-Butyl methyl ether)

Item number690717
CAS600-05-5
FormulaC3H4Br2O2
Molecular weight231,87 g/mol
Quantity 1X1ML
Concentration1000 µg/ml
Solventtert-Butyl methyl ether
storage conditions4 °C
CoA / MSDSRetrieve CoA
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2,3-Dibromopropanoic acid

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2,3-Dibromopropanoic acid

2,3-Dibromopropanoic acid

690716
600-05-5

1X250MG

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2,3-Dibromopropanoic acid solution
Concentration: 1000 µg/ml
Solvent: tert-Butyl methyl ether

2,3-Dibromopropanoic acid solution

690717
600-05-5

1X1ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 27.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:2,3-Dibromopropanoic acid
Catalog No.:690717
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 2), H225
Skin irritation (Category 2), H315 Classification according to EU Directives 67/548/EEC or 1999/45/EC
F Highly flammable R11
Xi Irritant R38
Label elements
Pictogramflamme
flamme
GHS07 exclam
exclam
Signal word Danger
Hazard statement(s)
H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
Precautionary statement(s)
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Supplemental Hazard
Statements
none
2.3 Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Synonyms : MTBE
Methyl tert-butyl ether
Formula : C5H12O
Molecular weight : 88,15 g/mol
CAS-No. : 1634-04-4
EC-No. : 216-653-1
Index-No. : 603-181-00-X
Registration number : 01-2119452786-27-XXXX
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classification Concentration
tert-Butyl methyl ether
CAS-No.
EC-No.
Index-No.
1634-04-4
216-653-1
603-181-00-X
Flam. Liq. 2; Skin Irrit. 2;
H225, H315
<= 100 %
Hazardous ingredients according to Directive 1999/45/EC
Component Classification Concentration
tert-Butyl methyl ether
CAS-No.
EC-No.
Index-No.
1634-04-4
216-653-1
603-181-00-X
F, Xi, R11 - R38 <= 100 %
FormulaC3H4Br2O2
Molecular Weight (g/mol)231.87
CAS-No.600-05-5
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
Use water spray to cool unopened containers
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation.
Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to
form explosive concentrations. Vapours can accumulate in low areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
place in container for disposal according to local regulations (see section 13).
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands. Body Protection
impervious clothing, Flame retardant antistatic protective clothing., The type of protective
equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup
to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing
point
No data available
f) Initial boiling point and
boiling range
55 - 56 °C - lit.
g) Flash point -33,0 °C - closed cup
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
Upper explosion limit: 15,1 %(V)
Lower explosion limit: 1,6 %(V)
k) Vapour pressure 1.018,7 hPa at 55,0 °C
279,2 hPa at 20,0 °C l) Vapour density No data available
m) Relative density 0,74 g/cm3 at 25 °C
n) Water solubility No data available
o) Partition coefficient: noctanol/
water
log Pow: 1,77log Pow: 0,94
p) Auto-ignition
temperature
374,0 °C
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
10.5 Incompatible materials
Oxidizing agents, Strong acids
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 4.000 mg/kg
LC50 Inhalation - Rat - 4 h - 23576 ppm
Skin corrosion/irritation
Skin - Rabbit
Result: Skin irritation
Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye irritation
Respiratory or skin sensitisation
Will not occur
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (tert-Butyl methyl ether) Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: KN5250000
Nausea, Vomiting, Dizziness, Central nervous system depression, Aspiration or inhalation may cause
chemical pneumonitis., MTBE (methyl-tert-butyl ether) is reported to metabolize to tert-butyl alcohol and
formaldehyde by microsomal demethylation, MTBE (methyl-tert-butyl ether) should be considered a
"potential human carcinogen" due to an increase in leydig interstitial cell tumors of testes in male rats and
an increase in lymphomas, leukemias, and uterine sarcomas in female rats., In another unpublished study
MTBE was shown to be carcinogenic due to "increased incidence of a rare type of kidney tumor" in male
rats and an "increase in the incidence of hepatocellular adenomas" in female mice., To the best of our
knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Central nervous system -
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 672,00 mg/l - 96 h
LC50 - other fish - > 1.000,00 mg/l - 96 h
Toxicity to daphnia and
other aquatic
invertebrates
EC50 - Daphnia magna (Water flea) - 472 mg/l - 48 h
Toxicity to algae EC50 - Pseudokirchneriella subcapitata (green algae) - 491 mg/l - 96 h
12.2 Persistence and degradability
Biodegradability Result: 0 % - Not readily biodegradable.
(OECD Test Guideline 301D)
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
company.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 2398 IMDG: 2398 IATA: 2398
14.2 UN proper shipping name
ADR/RID: METHYL tert-BUTYL ETHER
IMDG: METHYL tert-BUTYL ETHER
IATA: Methyl tert-butyl ether
14.3 Transport hazard class(es)
ADR/RID: 3 IMDG: 3 IATA: 3
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
No data available
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!