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Item number | 689562 |
CAS | 87-86-5 |
Formula | C6HCl5O |
Molecular weight | 266,34 g/mol |
Quantity | 1X100MG |
storage conditions | 20 °C |
CoA / MSDS | Retrieve CoA Retrieve MSDS |
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13C6-Pentachlorophenol solution | 683599 | 1X1ML | Please log in. | |
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689562 | 1X100MG | Please log in. |
Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 27.12.2024 |
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
Product name: | Pentachlorophenol |
Catalog No.: | 689562 |
Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Carcinogenicity (Category 2), H351 Acute toxicity, Inhalation (Category 2), H330 Acute toxicity, Dermal (Category 3), H311 Acute toxicity, Oral (Category 3), H301 Eye irritation (Category 2), H319 Specific target organ toxicity - single exposure (Category 3), H335 Skin irritation (Category 2), H315 Acute aquatic toxicity (Category 1), H400 Chronic aquatic toxicity (Category 1), H410 Classification according to EU Directives 67/548/EEC or 1999/45/EC R40 T+ Very toxic R26 T Toxic R24/25 Xi Irritant R36/37/38 N Dangerous for the R50/53 environment |
Label elements | |
Pictogram | GHS06 skull skull GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red |
2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H301 Toxic if swallowed. H311 Toxic in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H330 Fatal if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing. P284 Wear respiratory protection. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplemental Hazard Statements None 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. | |
COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Formula : C6HCl5O Molecular weight : 266,34 g/mol CAS-No. : 87-86-5 EC-No. : 201-778-6 Index-No. : 604-002-00-8 Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Classification Concentration Pentachlorophenol CAS-No. EC-No. Index-No. 87-86-5 201-778-6 604-002-00-8 Acute Tox. 3; Acute Tox. 2; Acute Tox. 3; Skin Irrit. 2; Eye Irrit. 2; Carc. 2; STOT SE 3; Aquatic Acute 1; Aquatic Chronic 1; H301 + H311, H315, H319, H330, H335, H351, H410 <= 100 % Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration Pentachlorophenol CAS-No. EC-No. Index-No. 87-86-5 201-778-6 604-002-00-8 T+, N, Carc.Cat.3, R24/25 - R26 - R36/37/38 - R40 - R50/53 <= 100 % |
Formula | C6HCl5O |
Molecular Weight (g/mol) | 266.34 |
CAS-No. | 87-86-5 |
FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Hydrogen chloride gas 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information No data available |
ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13. |
HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided |
PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: crystalline Colour: light red b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/range: 165 - 180 °C f) Initial boiling point and boiling range 310 °C g) Flash point No data available h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits No data available k) Vapour pressure 53,3 hPa at 211,2 °C l) Vapour density No data available m) Relative density 1,978 g/mL at 25 °C n) Water solubility No data available o) Partition coefficient: noctanol/ water log Pow: 5,12 p) Auto-ignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available |
STABILITY AND REACTIVITY | 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid No data available 10.5 Incompatible materials Strong oxidizing agents, Strong bases 10.6 Hazardous decomposition products Other decomposition products - No data available In the event of fire: see section 5 |
TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 27 mg/kg Remarks: Vascular:BP elevation not charactertized in autonomic section. Endocrine:Hyperglycemia. Nutritional and Gross Metabolic:Changes in:Body temperature increase. LC50 Inhalation - Rat - 355 mg/m3 Remarks: Behavioral:Excitement. Behavioral:Muscle contraction or spasticity. Lungs, Thorax, or Respiration:Dyspnea. LD50 Dermal - Rat - 96,0 mg/kg Remarks: Behavioral:Excitement. Behavioral:Muscle contraction or spasticity. Lungs, Thorax, or Respiration:Dyspnea. Skin corrosion/irritation Skin - Rabbit Result: Open irritation test - 24,00 h Serious eye damage/eye irritation Eyes - Rabbit Result: Mild eye irritation - 24,00 h Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity The evidence for carcinogenicity of pentachlorophenol (PCP) is based on assays that utilized less than pure PCP. Contaminants of PCP include: tri- or tetra- chlorophenol, hexachlorobenzene, polychlorinated dibenzo-p-dioxins, or polychlorinated dibenzofurans. Indications are that positive evidence for carcinogenicity is from the contaminant(s) and not the PCP. This product is or contains a component that has been reported to be possibly carcinogenic based on its IARC, ACGIH, NTP, or EPA classification. Limited evidence of carcinogenicity in animal studies IARC: 2B - Group 2B: Possibly carcinogenic to humans (Pentachlorophenol) Reproductive toxicity Overexposure may cause reproductive disorder(s) based on tests with laboratory animals. Specific target organ toxicity - single exposure May cause respiratory irritation. Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS: Not available Convulsions Kidney - |
ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Cyprinodon variegatus (sheepshead minnow) - 0,16 - 0,5 mg/l - 96,0 h LC50 - Carassius auratus (goldfish) - 0,16 - 0,38 mg/l - 96,0 h LC50 - Oncorhynchus mykiss (rainbow trout) - 0,075 mg/l - 96,0 h NOEC - other fish - 0,01 mg/l - 24,0 h LOEC - other fish - 0,1 mg/l - 24,0 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 0,30 - 1,30 mg/l - 48 h Toxicity to algae EC50 - No information available. - 0,36 mg/l - 10 d EC50 - Chlorella vulgaris (Fresh water algae) - 10,30 mg/l - 96 h Growth inhibition EC50 - Scenedesmus quadricauda (Green algae) - 0,08 mg/l - 96 h 12.2 Persistence and degradability Biodegradability Result: 99 % - Biodegradable 12.3 Bioaccumulative potential Bioaccumulation Oncorhynchus mykiss (rainbow trout) - 144 h - 0,0912 mg/l Bioconcentration factor (BCF): 482 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Very toxic to aquatic life with long lasting effects |
DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. |
TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 3155 IMDG: 3155 IATA: 3155 14.2 UN proper shipping name ADR/RID: PENTACHLOROPHENOL IMDG: PENTACHLOROPHENOL IATA: Pentachlorophenol 14.3 Transport hazard class(es) ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: no 14.6 Special precautions for user No data available |
REGULATORY INFORMATION | This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Pentachlorophenol CAS-No.: 87-86-5 REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) Shall not be placed on the market, or used, as a substance or in mixtures See Annex XVII to Regulation (EC) no 1907/2006 for Conditions of restriction Pentachlorophenol CAS-No.: 87-86-5 REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) Shall not be placed on the market, or used, as a substance or in mixtures See Annex XVII to Regulation (EC) no 1907/2006 for Conditions of restriction Pentachlorophenol CAS-No.: 87-86-5 Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and import of dangerous chemicals Countries for which no notification is required: Please refer to PIC circular at www.pic.int/ Pentachlorophenol CAS-No.: 87-86-5 Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and import of dangerous chemicals Countries for which no notification is required: Please refer to PIC circular at www.pic.int/ Pentachlorophenol CAS-No.: 87-86-5 Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and import of dangerous chemicals Countries for which no notification is required: Please refer to PIC circular at www.pic.int/ 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |