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Biphenyl
ISO 17034 Reference Material
| Item number | 688703 |
| CAS | 92-52-4 |
| Formula | C12H10 |
| Molecular weight | 154,21 g/mol |
| Quantity | 1X250MG |
| storage conditions | 20 °C |
| CoA / MSDS | Retrieve CoA Retrieve MSDS |
Price | Please log in. |
Part of Product groups:
Product Variations:
Product | Catalog No./ CAS No. | Quantity | Price | |
|---|---|---|---|---|
Biphenyl solution |  | 674050 | 1X5ML | Please log in. |
Biphenyl solution |  | 685784 | 1X1ML | Please log in. |
Biphenyl solution | 688572 | 1X5ML | Please log in. | |
ISO 17034 Reference Material |  | 688703 | 1X250MG | Please log in. |
ISO 17034 Certified Reference Material |  | 688704 | 1X100MG | Please log in. |
 | 675793 | 1X100MG | Please log in. | |
D10-Biphenyl solution |  | 680836 | 1X1ML | Please log in. |
| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 27.12.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | Biphenyl |
| Catalog No.: | 688703 |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
| Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Skin irritation (Category 2) Eye irritation (Category 2) Specific target organ toxicity - single exposure (Category 3) Acute aquatic toxicity (Category 1) Chronic aquatic toxicity (Category 1) Classification according to EU Directives 67/548/EEC or 1999/45/EC Irritating to eyes, respiratory system and skin. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Label elements | |
| Pictogram | GHS07 exclam exclam GHS09 Aquatic-pollut-red Aquatic-pollut-red |
| Signal word Warning Hazard statement(s) H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P261 Avoid breathing dust. P273 Avoid release to the environment. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P501 Dispose of contents/ container to an approved waste disposal plant. Supplemental Hazard Statements None R-phrase(s) R36/37/38 Irritating to eyes, respiratory system and skin. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S23 Do not breathe gas/fumes/vapour/spray. S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/ Safety data sheets. 2.3 Other hazards - none | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Formula : C12H10 Molecular Weight : 154,21 g/mol Component Concentration Biphenyl CAS-No. EC-No. Index-No. 92-52-4 202-163-5 601-042-00-8 - |
| Formula | C12H10 |
| Molecular Weight (g/mol) | 154.21 |
| CAS-No. | 92-52-4 |
| FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed Liver injury may occur., Gastrointestinal disturbance 4.3 Indication of any immediate medical attention and special treatment needed no data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 Further information no data available |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13. |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 7.3 Specific end use(s) no data available |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry Hands The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Full contact Material: Fluorinated rubber Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) Splash protection Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 30 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: crystalline Colour: light yellow b) Odour characteristic c) Odour Threshold no data available d) pH 5,5 e) Melting point/freezing point Melting point/range: 68 - 70 °C - lit. f) Initial boiling point and boiling range 255 °C - lit. g) Flash point 110 °C - closed cup h) Evaporation rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits Upper explosion limit: 5,8 %(V) Lower explosion limit: 0,6 %(V) k) Vapour pressure 0,04 hPa at 20 °C 5,5 hPa at 100 °C 12,6 hPa at 115 °C 95,7 hPa at 166 °C l) Vapour density no data available m) Relative density 0,992 g/cm3 n) Water solubility 0,0075 g/l at 15 °C o) Partition coefficient: noctanol/ water no data available p) Auto-ignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available 9.2 Other safety information no data available |
| STABILITY AND REACTIVITY | 10.1 Reactivity no data available 10.2 Chemical stability no data available 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid no data available 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products Other decomposition products - no data available |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - rat - 2.140 mg/kg Remarks: Behavioral:Somnolence (general depressed activity). Behavioral:Muscle weakness. Gastrointestinal disturbance Inhalation: no data available LD50 Dermal - rabbit - > 5.010 mg/kg Skin corrosion/irritation Skin - rabbit - Irritating to skin. - 24 h - Draize Test Serious eye damage/eye irritation Eyes - rabbit - Mild eye irritation - Draize Test Respiratory or skin sensitization guinea pig - Remarks: Did not cause sensitization on laboratory animals. Germ cell mutagenicity Genotoxicity in vitro - mouse - lymphocyte DNA damage Genotoxicity in vitro - mouse - lymphocyte Mutation in mammalian somatic cells. Genotoxicity in vitro - Hamster - Lungs Mutation in microorganisms Genotoxicity in vitro - Hamster - fibroblast Sister chromatid exchange Genotoxicity in vivo - rat - Oral Unscheduled DNA synthesis Genotoxicity in vivo - mouse - Oral DNA damage Carcinogenicity Carcinogenicity - mouse - Oral Tumorigenic:Equivocal tumorigenic agent by RTECS criteria. Lungs, Thorax, or Respiration:Tumors. Blood:Tumors. Carcinogenicity - mouse - Subcutaneous Tumorigenic:Neoplastic by RTECS criteria. Lungs, Thorax, or Respiration:Tumors. Liver:Tumors. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure May cause respiratory irritation. Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation May be harmful if inhaled. Causes respiratory tract irritation. Ingestion May be harmful if swallowed. Skin May be harmful if absorbed through skin. Causes skin irritation. Eyes Causes serious eye irritation. Signs and Symptoms of Exposure Liver injury may occur., Gastrointestinal disturbance Additional Information RTECS: DU8050000 |
| ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1,45 mg/l - 96,0 h LC0 - Danio rerio (zebra fish) - 38 mg/l - 96,0 h LC50 - Salmo gairdneri - 1,5 mg/l - 96,0 h LC50 - Lepomis macrochirus (Bluegill) - 4,7 mg/l - 96,0 h Toxicity to daphnia and other aquatic invertebrates LC50 - Daphnia magna (Water flea) - 0,36 mg/l - 48 h 12.2 Persistence and degradability Biodegradability Method: Closed Bottle test Remarks: According to the results of tests of biodegradability this product is considered as being readily biodegradable. 12.3 Bioaccumulative potential Bioaccumulation Leuciscus idus (Golden orfe) - 3 d -50 μg/l Bioconcentration factor (BCF): 281 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment no data available 12.6 Other adverse effects Very toxic to aquatic life. no data available |
| DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 3077 IMDG: 3077 IATA: 3077 14.2 UN proper shipping name ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Biphenyl) IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Biphenyl) IATA: Environmentally hazardous substance, solid, n.o.s. (Biphenyl) 14.3 Transport hazard class(es) ADR/RID: 9 IMDG: 9 IATA: 9 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: yes IMDG Marine Pollutant: yes IATA: yes 14.6 Special precautions for user no data available |
| REGULATORY INFORMATION | This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture no data available 15.2 Chemical Safety Assessment no data available |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |