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Karanjin

Item number688191
CAS521-88-0
FormulaC18H12O4
Molecular weight292,29 g/mol
Quantity 1X10MG
storage conditions20 °C
CoA / MSDSRetrieve CoA
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Karanjin

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Karanjin

Karanjin

688191
521-88-0

1X10MG

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Karanjin solution
Concentration: 100 µg/ml
Solvent: Acetonitrile

Karanjin solution

688192
521-88-0

1X1ML

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 08.09.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Karanjin
Catalog No.:688191
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H312 Harmful in contact with skin.
Acute Tox. 4 H332 Harmful if inhaled.
Eye Irrit. 2 H319 Causes serious eye irritation
Label elements
Pictogramflamme
flamme
GHS07 exclam
exclam
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS07
· Signal word Danger
· Hazard-determining components of labelling:
Acetonitrile
· Hazard statements
H225 Highly flammable liquid and vapour.
H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled.
H319 Causes serious eye irritation · Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable
COMPOSITION/INFORMATION ON INGREDIENTS· 3.2 Chemical characterisation: Mixtures
· Description: Mixture: consisting of the following components.
· Dangerous components:
CAS: 75-05-8
EINECS: 200-835-2
RTECS: AL 7700000
Acetonitrile
Flam. Liq. 2, H225; Acute Tox. 4, H302; Acute Tox. 4, H312; Acute
Tox. 4, H332; Eye Irrit. 2, H319
>99%
CAS: 521-88-0
EINECS: 208-319-9
RTECS: LV1430000
Karanjin <0.1%
· Additional information: For the wording of the listed hazard phrases refer to section 16.
FormulaC18H12O4
Molecular Weight (g/mol)292.29
CAS-No.521-88-0
FIRST AID MEASURES· 4.1 Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48
hours after the accident is recommended.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness place patient in recovery position for transport.
Seek medical treatment.
· After skin contact:
Immediately wash with water and soap and rinse thoroughly.
Seek medical treatment.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Rinse mouth. Do not induce vomiting.
Seek medical treatment.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available
FIRE-FIGHTING MEASURES· 5.1 Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
· 5.3 Advice for firefighters
· Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device
ACCIDENTAL RELEASE MEASURES· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
HANDLING AND STORAGE· 7.1 Precautions for safe handling
Ensure good ventilation/extraction at the workplace.
Store in cool, dry place in tightly closed receptacles.
Prevent formation of aerosols.
· Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturers certificate for specific storage and transport temperature conditions.
Store only in the original receptacle.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles
7.3 Specific end use(s) No further relevant information available.
EXPOSURE CONTROLS/PERSONAL PROTECTION· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
75-05-8 Acetonitrile
WEL Short-term value: 102 mg/m³, 60 ppm
Long-term value: 68 mg/m³, 40 ppm
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Butyl rubber, BR
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
PHYSICAL AND CHEMICAL PROPERTIES· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Colour: Colourless
· Odour: Aromatic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/freezing point: -46 °C
Initial boiling point and boiling range: 81 °C
· Flash point: 5 °C
· Flammability (solid, gas): Not determined.
· Ignition temperature: 525 °C
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of explosive air/
vapour mixtures is possible.
· Explosion limits:
Lower: 4.4 Vol %
Upper: 16 Vol %
· Vapour pressure at 20 °C: 97 hPa
· Density at 20 °C: 0.7822 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
water at 25 °C: 74 g/l
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic at 20 °C: 0.39 mPas
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.
STABILITY AND REACTIVITY· 10.1 Reactivity Stable under normal conditions.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:
Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions Forms explosive gas mixture with air.
· 10.4 Conditions to avoid
Sources of ignition
Heat.
· 10.5 Incompatible materials:
Strong oxidizing agents.
Strong acids.
· 10.6 Hazardous decomposition products:
Formation of toxic gases is possible during heating or in case of fire
TOXICOLOGICAL INFORMATION· 11.1 Information on toxicological effects
· Acute toxicity
Harmful if swallowed, in contact with skin or if inhaled.
· LD/LC50 values relevant for classification:
75-05-8 Acetonitrile
Oral (LD50) 2,460 mg/kg (rat)
· Primary irritant effect:
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation
Causes serious eye irritation.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met
ECOLOGICAL INFORMATION· 12.1 Toxicity
· Aquatic toxicity:
75-05-8 Acetonitrile
EC50/48 h 3,600 mg/l (daphnia)
LC50/96 h 1,640 mg/l (fish)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
DISPOSAL CONSIDERATIONS· 13.1 Waste treatment methods
· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogue
Waste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:
· Recommendation: Dispose of in accordance with national regulations
· Recommended cleansing agents: Water, if necessary together with cleansing agents
TRANSPORT INFORMATION· 14.1 UN-Number
· ADR, IMDG, IATA UN1648
· ADR 1648 ACETONITRILE mixture
· IMDG, IATA ACETONITRILE mixture
· 14.3 Transport hazard class(es)
· ADR, IMDG, IATA
· Class 3 Flammable liquids.
· Label 3
· 14.4 Packing group
· ADR, IMDG, IATA II
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 33
· EMS Number: F-E,S-D
· Stowage Category B
· Stowage Code SW2 Clear of living quarters.
· 14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
· Tunnel restriction code D/E
· UN "Model Regulation": UN 1648 ACETONITRILE MIXTURE, 3, II
REGULATORY INFORMATION· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Philippines Inventory of Chemicals and Chemical Substances
75-05-8 Acetonitrile
· Australian Inventory of Chemical Substances
75-05-8 Acetonitrile
· Standard for the Uniform Scheduling of Medicines and Poisons
None of the ingredients is listed.
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!