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ISO 17034 Certified Reference Material
Item number | 685622 |
CAS | 120068-37-3 |
Formula | C12H4Cl2F6N4OS |
Molecular weight | 437,20 g/mol |
Quantity | 1X50MG |
storage conditions | 20 °C |
CoA / MSDS | Retrieve CoA Retrieve MSDS |
Product | Catalog No./ CAS No. | Quantity | Price | |
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13C4-Fipronil solution | 681587 | 1X1ML | Please log in. | |
Fipronil solution | 673934 | 1X10ML | Please log in. | |
ISO 17034 Reference Material | 685621 | 1X100MG | Please log in. | |
ISO 17034 Certified Reference Material | 685622 | 1X50MG | Please log in. | |
ISO 17034 Reference Material Fipronil solution | 685623 | 1X5ML | Please log in. | |
ISO 17034 Reference Material Fipronil solution | 685624 | 1X10ML | ||
ISO 17034 Certified Reference Material Fipronil solution | 685625 | 1X1ML | Please log in. |
Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 30.11.2024 |
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
Product name: | Fipronil |
Catalog No.: | 685622 |
Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Acute toxicity, Inhalation (Category 3) Acute toxicity, Dermal (Category 3) Acute toxicity, Oral (Category 3) Specific target organ toxicity - repeated exposure (Category 1) Acute aquatic toxicity (Category 1) Chronic aquatic toxicity (Category 1) Classification according to EU Directives 67/548/EEC or 1999/45/EC Toxic by inhalation, in contact with skin and if swallowed. Toxic: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
Label elements | |
Pictogram | GHS06 skull skull GHS08 silhouete silhouete GHS09 Aquatic-pollut-red Aquatic-pollut-red |
Signal word Danger Hazard statement(s) H301 Toxic if swallowed. H311 Toxic in contact with skin. H331 Toxic if inhaled. H372 Causes damage to organs through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. Precautionary statement(s) P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P311 Call a POISON CENTER or doctor/ physician. P501 Dispose of contents/ container to an approved waste disposal plant. Supplemental Hazard Statements None R-phrase(s) R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S28 After contact with skin, wash immediately with plenty of soap and water. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/ Safety data sheets. 2.3 Other hazards - none | |
COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Formula : C12H4Cl2F6N4OS Molecular Weight : 437,15 g/mol Component Concentration Fipronil CAS-No. EC-No. Index-No. 120068-37-3 424-610-5 608-055-00-8 - |
Formula | C12H4Cl2F6N4OS |
Molecular Weight (g/mol) | 437.20 |
CAS-No. | 120068-37-3 |
FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed Chronic exposure damages the brain and the central nervous system. 4.3 Indication of any immediate medical attention and special treatment needed no data available |
FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, nitrogen oxides (NOx), Sulphur oxides, Hydrogen chloride gas, Hydrogen fluoride 5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. 5.4 Further information no data available |
ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13. |
HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. 7.3 Specific end uses no data available |
EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: powder Colour: yellow b) Odour no data available c) Odour Threshold no data available d) pH 5,9 - 6,1 at 10 g/l at 20 °C e) Melting point/freezing point no data available f) Initial boiling point and boiling range no data available g) Flash point no data available h) Evaporation rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits no data available k) Vapour pressure no data available l) Vapour density no data available m) Relative density 1,550 g/cm3 n) Water solubility insoluble o) Partition coefficient: noctanol/ water log Pow: 4 p) Autoignition temperature no data available q) Decomposition temperature no data available r) Viscosity no data available s) Explosive properties no data available t) Oxidizing properties no data available 9.2 Other safety information no data available |
STABILITY AND REACTIVITY | 10.1 Reactivity no data available 10.2 Chemical stability no data available 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid no data available 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products Other decomposition products - no data available |
TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - rat - 97 mg/kg LC50 Inhalation - rat - 4 h - 680 mg/m3 LD50 Dermal - rabbit - 354 mg/kg Skin corrosion/irritation Skin - rabbit - Mild skin irritation Serious eye damage/eye irritation Eyes - rabbit - Moderate eye irritation Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure Ingestion - Causes damage to organs through prolonged or repeated exposure. Aspiration hazard no data available Potential health effects Inhalation Toxic if inhaled. May cause respiratory tract irritation. Ingestion Toxic if swallowed. Skin Toxic if absorbed through skin. May cause skin irritation. Eyes Causes serious eye irritation. Signs and Symptoms of Exposure Chronic exposure damages the brain and the central nervous system. Additional Information RTECS: UQ4430250 |
ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 0,25 mg/l - 96,0 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 0,19 mg/l - 48 h Toxicity to algae EC50 - Desmodesmus subspicatus (green algae) - 0,07 mg/l - 96 h 12.2 Persistence and degradability no data available 12.3 Bioaccumulative potential no data available 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment no data available 12.6 Other adverse effects Very toxic to aquatic life with long lasting effects. |
DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging Dispose of as unused product. |
TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 2811 IMDG: 2811 IATA: 2811 14.2 UN proper shipping name ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (Fipronil) IMDG: TOXIC SOLID, ORGANIC, N.O.S. (Fipronil) IATA: Toxic solid, organic, n.o.s. (Fipronil) 14.3 Transport hazard class(es) ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: no 14.6 Special precautions for user no data available |
REGULATORY INFORMATION | This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture no data available 15.2 Chemical Safety Assessment no data available |
OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |