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Item number | 687999 |
CAS | 78-90-0 |
Formula | C3H10N2 |
Molecular weight | 74,12 g/mol |
Quantity | 1X1000MG |
storage conditions | 4 °C |
CoA / MSDS | Retrieve CoA Retrieve MSDS |
Product | Catalog No./ CAS No. | Quantity | Price | |
---|---|---|---|---|
687999 | 1X1000MG | Please log in. | ||
688000 | 1X10MG | Please log in. |
Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 13.11.2024 |
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
Product name: | 1,2-Diaminopropane |
Catalog No.: | 687999 |
Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 3), H226 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Dermal (Category 3), H311 Skin corrosion (Sub-category 1A), H314 Respiratory sensitization (Category 1), H334 Skin sensitization (Category 1), H317 |
Label elements | |
Pictogram | flamme flamme GHS05 acid acid GHS06 skull skull GHS08 silhouete silhouete |
2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H226 Flammable liquid and vapor. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Precautionary statement(s) P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher | |
COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : 1,2-Propanediamine Propylenediamine Formula : C3H10N2 Molecular weight : 74,12 g/mol CAS-No. : 78-90-0 EC-No. : 201-155-9 Index-No. : 612-100-00-7 Component Classification Concentration Propylenediamine Flam. Liq. 3; Acute Tox. 4; Acute Tox. 3; Skin Corr. 1A; Resp. Sens. 1; Skin <= 100 % Sens. 1; H226, H302, H311, H314, H334, H317 |
Formula | C3H10N2 |
Molecular Weight (g/mol) | 74.12 |
CAS-No. | 78-90-0 |
FIRST AID MEASURES | 4.1 Description of first-aid measures General advice Consult a physician. Show this material safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Dry powder Dry sand Unsuitable extinguishing media Do NOT use water jet. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx) 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers |
ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). 6.4 Reference to other sections For disposal see section 13 |
HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place. strongly hygroscopic Handle and store under inert gas. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Color: colorless b) Odor pungent c) Odor Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/freezing point: -36,6 °C f) Initial boiling point and boiling range 119 - 120 °C - lit. g) Flash point 34 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, No data available gas) j) Upper/lower flammability or explosive limits Upper explosion limit: 11,1 %(V) Lower explosion limit: 1,9 %(V) k) Vapor pressure 19 hPa at 20 °C l) Vapor density 2,56 - (Air = 1.0) m) Relative density 0,87 g/cm3 at 25 °C n) Water solubility 1.000 g/l at 20 °C - soluble o) Partition coefficient: n-octanol/water log Pow: -1,8 p) Autoignition temperature 360 °C at 1.013,25 hPa q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Relative vapor density 2,56 - (Air = 1.0) |
STABILITY AND REACTIVITY | 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx) Other decomposition products - No data available In the event of fire: see section 5 |
TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - male and female - 1.300 mg/kg LD50 Dermal - Rabbit - male - 430 mg/kg Skin corrosion/irritation Skin - Rabbit Result: Causes severe burns. Serious eye damage/eye irritation Eyes - Rabbit Result: Severe eye irritation Respiratory or skin sensitization No data available Germ cell mutagenicity Ames test S. typhimurium Result: negative Carcinogenicity IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS: TX6650000 Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea |
ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.010 mg/l - 96 h 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 20 d Result: 0 % - Not biodegradable. (OECD Test Guideline 301D) 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects No data available |
DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. Contaminated packaging Dispose of as unused product. |
TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 2258 IMDG: 2258 IATA: 2258 14.2 UN proper shipping name ADR/RID: 1,2-PROPYLENEDIAMINE IMDG: 1,2-PROPYLENEDIAMINE IATA: 1,2-Propylenediamine 14.3 Transport hazard class(es) ADR/RID: 8 (3) IMDG: 8 (3) IATA: 8 (3) 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available |
REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |