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Butyl acetate

Item number681845
CAS123-86-4
FormulaC6H12O2
Molecular weight116,16 g/mol
Quantity 1X5ML
storage conditions20 °C
CoA / MSDSRetrieve CoA
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Butyl acetate

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Butyl acetate

Butyl acetate

681845
123-86-4

1X5ML

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tert-Butyl acetate

tert-Butyl acetate

679636
540-88-5

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 27.12.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Butyl acetate
Catalog No.:681845
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Am Wieseneck 7

04451 Cunnersdorf
Deutschland


Tel. +49 34291 3372-36
Fax. +49 34291 3372-39
contact@hpc-standards.com
Emergency telephone numberHPC Standards Tel. +49 34291 3372-36
This number is only available during office hours.
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 3), H226
Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336
Label elements
Pictogramflamme
flamme
GHS07 exclam
exclam
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram Signal word Warning
Hazard statement(s)
H226 Flammable liquid and vapour H336 May cause drowsiness or dizziness.
Precautionary statement(s)
P210 Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
Supplemental Hazard information (EU)
EUH066 Repeated exposure may cause skin dryness or cracking.
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
Formula : C6H12O2
Molecular weight : 116,16 g/mol
CAS-No. : 123-86-4
EC-No. : 204-658-1
Index-No. : 607-025-00-1
No components need to be disclosed according to the applicable regulations
FormulaC6H12O2
Molecular Weight (g/mol)116.16
CAS-No.123-86-4
FIRST AID MEASURES4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media
Suitable extinguishing media
Dry powder Dry sand
Unsuitable extinguishing media
Do NOT use water jet.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
Use water spray to cool unopened containers
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Remove all sources of ignition. Beware of vapours accumulating to
form explosive concentrations. Vapours can accumulate in low areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13).
6.4 Reference to other sections
For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling
Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of
electrostatic charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
Colour: colourless, clear
b) Odour fruity
c) Odour Threshold No data available
d) pH 6,2 at 5,3 g/l at 20 °C
e) Melting
point/freezing point
Melting point/range: -78 °C - lit.
f) Initial boiling point
and boiling range
124 - 126 °C - lit.
g) Flash point 27 °C - closed cup - Regulation (EC) No. 440/2008, Annex, A.9
h) Evaporation rate No data available
i) Flammability (solid,
gas)
No data available
j) Upper/lower
flammability or
explosive limits
Upper explosion limit: 7,6 %(V)
Lower explosion limit: 1,7 %(V)
k) Vapour pressure 11,2 hPa at 20 °C - Regulation (EC) No. 440/2008, Annex, A.4
l) Vapour density 4,01 - (Air = 1.0)
m) Relative density 0,88 g/mL at 25 °C - lit.
n) Water solubility 5,3 g/l at 20 °C - OECD Test Guideline 105 - soluble
o) Partition coefficient:
n-octanol/water
log Pow: 2,3 at 25 °C - OECD Test Guideline 117 -
Bioaccumulation is not expected.
p) Auto-ignition
temperature
415 °C
at 1.010 hPa - DIN 51794
q) Decomposition
temperature
No data available r) Viscosity 0,83 mm2/s at 20 °C - ASTM D 445 - 0,66 mm2/s at 40 °C -
ASTM D 445 -
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
Conductivity < 0,2 μS/cm
Surface tension 61,3 mN/m at 1g/l at 20 °C
- OECD Test Guideline 115
Relative vapour
density
4,01 - (Air = 1.0)
STABILITY AND REACTIVITY10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
Strong oxidizing agents, Strong reducing agents, Strong bases
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides
Other decomposition products - No data available
In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - female - 10.760 mg/kg
(OECD Test Guideline 423)
LD50 Dermal - Rabbit - male and female - 14.112 mg/kg
(OECD Test Guideline 402)
Skin corrosion/irritation
Skin - Rabbit
Result: No skin irritation - 4 h
(OECD Test Guideline 404)
Drying-out effect resulting in rough and chapped skin.
Serious eye damage/eye irritation
Eyes - Rabbit
Result: No eye irritation
(OECD Test Guideline 405)
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
Ames test
Escherichia coli/Salmonella typhimurium
Result: negative
OECD Test Guideline 474
Mouse - male and female - Red blood cells (erythrocytes)
Result: negative
Carcinogenicity
This product is or contains a component that is not classifiable as to its carcinogenicity
based on its IARC, ACGIH, NTP, or EPA classification.
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
May cause drowsiness or dizziness. - Central nervous system
Acute oral toxicity - Risk of aspiration upon vomiting., Aspiration may cause pulmonary
oedema and pneumonitis.
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
Repeated dose toxicity - Rat - male and female - Oral - 13 Weeks - No observed adverse
effect level - 125 mg/kg - Lowest observed adverse effect level - 500 mg/kg
RTECS: AF7350000
Drowsiness
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
After absorption of large quantities:
somnolence, Drowsiness, narcosis
Handle in accordance with good industrial hygiene and safety practice
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish flow-through test LC50 - Pimephales promelas (fathead minnow) - 18
mg/l - 96 h
(OECD Test Guideline 203)
Toxicity to daphnia
and other aquatic
invertebrates
static test EC50 - Daphnia magna (Water flea) - 44 mg/l - 48 h
(OECD Test Guideline 202)
Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata (green algae) -
397 mg/l - 72 h
(OECD Test Guideline 201)
Remarks: (in analogy to similar products)
Toxicity to bacteria static test IC50 - Tetrahymena pyriformis - 356 mg/l - 40 h
Remarks: (ECHA)
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 83 % - Readily biodegradable.
(OECD Test Guideline 301D)
Theoretical oxygen
demand
2.207 mg/g
Remarks: (Lit.)
Ratio BOD/ThBOD 7 - 46 %
Remarks: (Lit.) 12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
12.6 Other adverse effects
Harmful to aquatic life.
Discharge into the environment must be avoided.
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material
must be disposed of in accordance with the Directive on waste 2008/98/EC as well as
other national and local regulations. Leave chemicals in original containers. No mixing
with other waste. Handle uncleaned containers like the product itself.
Contaminated packaging
Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number
ADR/RID: 1123 IMDG: 1123 IATA: 1123
14.2 UN proper shipping name
ADR/RID: BUTYL ACETATES
IMDG: BUTYL ACETATES
IATA: Butyl acetates
14.3 Transport hazard class(es)
ADR/RID: 3 IMDG: 3 IATA: 3
14.4 Packaging group
ADR/RID: III IMDG: III IATA: III
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
REACH - Restrictions on the manufacture, : placing on the market and use of certain
dangerous substances, preparations and articles
(Annex XVII)
REACH - Restrictions on the manufacture,
placing on the market and use of certain
dangerous substances, preparations and articles
(Annex XVII)
:
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!