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Item number | 685228 |
CAS | 76-22-2 |
Formula | C10H16O |
Molecular weight | 152,23 g/mol |
Quantity | 1X100MG |
storage conditions | 4 °C |
CoA / MSDS | Retrieve CoA Retrieve MSDS |
Product | Catalog No./ CAS No. | Quantity | Price | |
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685228 | 1X100MG | Please log in. | ||
690146 | 1X100MG | Please log in. |
Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 27.12.2024 |
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
Product name: | Camphor |
Catalog No.: | 685228 |
Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
Uses advised against: | HPC Standards GmbH Am Wieseneck 7 04451 Cunnersdorf Deutschland Tel. +49 34291 3372-36 Fax. +49 34291 3372-39 contact@hpc-standards.com |
Emergency telephone number | HPC Standards Tel. +49 34291 3372-36 This number is only available during office hours. |
HAZARDS IDENTIFICATION | Acute Tox. 4 H302 Harmful if swallowed. Acute Tox. 4 H332 Harmful if inhaled. |
Label elements | |
Pictogram | flamme flamme GHS07 exclam exclam GHS08 silhouete silhouete |
Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. Signal word Danger Hazard statements H228 Flammable solid. H302+H332 Harmful if swallowed or if inhaled. H370 Causes damage to organs. Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 Use explosion-proof electrical/ventilating/lighting equipment. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 Other hazards Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. | |
COMPOSITION/INFORMATION ON INGREDIENTS | Chemical characterisation: Substances CAS No. Description 76-22-2 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one Identification number(s) None EC number: 200-945-0 RTECS: EX1225000 |
Formula | C10H16O |
Molecular Weight (g/mol) | 152.23 |
CAS-No. | 76-22-2 |
FIRST AID MEASURES | 4.1 Description of first aid measures General information: Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48 hours after the accident is recommended. After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient in recovery position for transport. Seek medical treatment. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: Rinse mouth. Do not induce vomiting. Seek medical treatment. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. |
FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 5.2 Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. 5.3 Advice for firefighters Protective equipment: Mouth respiratory protective device. Wear self-contained respiratory protective device. |
ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. Avoid formation of dust. 6.2 Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up: Dispose of contaminated material as waste according to item 13. Ensure adequate ventilation. 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. |
HANDLING AND STORAGE | |
EXPOSURE CONTROLS/PERSONAL PROTECTION | Additional information about design of technical facilities: No further data; see item 7. 8.1 Control parameters Ingredients with limit values that require monitoring at the workplace: 76-22-2 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one WEL Short-term value: 19 mg/m³, 3 ppm Long-term value: 13 mg/m³, 2 ppm Additional information: Lists used were valid at the time of SDS preparation. 8.2 Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374 Protective gloves Material of gloves Nitrile rubber, NBR Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Safety glasses |
PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties General Information Appearance: Form: Crystalline Colour: White Odour: Strong Odour threshold: Not determined. pH-value: Not applicable. Change in condition Melting point/freezing point: 176-179 °C Initial boiling point and boiling range: 209 °C Flash point: 66 °C Flammability (solid, gas): Not determined. Ignition temperature: 460 °C Decomposition temperature: Not determined. Auto-ignition temperature: Not determined. Explosive properties: Product is not explosive. However, formation of explosive air/vapour mixtures is possible. Explosion limits: Lower: 0.6 Vol % Upper: 4.5 Vol % Vapour pressure: Not applicable. Density at 20 °C: 1 g/cm³ Relative density Not determined. Vapour density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with Chloroform, Ethyl acetate water at 20 °C: 1.5 g/l Partition coefficient: n-octanol/water: 2.38 logP Viscosity: Dynamic: Not applicable. Kinematic: Not applicable. 9.2 Other information No further relevant information available. |
STABILITY AND REACTIVITY | 10.1 Reactivity Stable under normal conditions. 10.2 Chemical stability Stable under normal conditions. Thermal decomposition / conditions to be avoided: Formation of toxic gases is possible during heating or in case of fire. 10.3 Possibility of hazardous reactions Flammable. 10.4 Conditions to avoid Sources of ignition Heat. 10.5 Incompatible materials: Strong oxidizing agents. 10.6 Hazardous decomposition products: Formation of toxic gases is possible during heating or in case of fire. Carbon monoxide and carbon dioxide |
TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity Harmful if swallowed or if inhaled. LD/LC50 values relevant for classification: Oral LD50 1,310 mg/kg (mouse) LD 50 (Intraperitoneal) 3,000 mg/kg (mouse) Primary irritant effect: Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/irritation Based on available data, the classification criteria are not met. Respiratory or skin sensitisation Based on available data, the classification criteria are not met. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Causes damage to organs. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. |
ECOLOGICAL INFORMATION | 12.1 Toxicity Aquatic toxicity: LC50/96 h 17 mg/l (fish) 12.2 Persistence and degradability No further relevant information available. 12.3 Bioaccumulative potential No further relevant information available. 12.4 Mobility in soil No further relevant information available. Ecotoxicological effects: Remark: Harmful to fish Additional ecological information: General notes: Water hazard class 1 (German Regulation) (Assessment by list): slightly hazardous for water Do not allow undiluted product to reach ground water, water course or sewage system. Harmful to aquatic organisms 12.5 Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. 12.6 Other adverse effects No further relevant information available. |
DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. European waste catalogue Waste disposal key numbers from EWC have to be assigned depending on origin and processing. Uncleaned packaging: Recommendation: Dispose of in accordance with national regulations. |
TRANSPORT INFORMATION | 14.1 UN-Number ADR, IMDG, IATA UN2717 ADR 2717 CAMPHOR IMDG, IATA CAMPHOR 14.3 Transport hazard class(es) ADR, IMDG, IATA Class 4.1 Flammable solids, self-reactive substances and solid desensitised explosives. Label 4.1 14.4 Packing group ADR, IMDG, IATA III 14.5 Environmental hazards: Not applicable. 14.6 Special precautions for user Warning: Flammable solids, self-reactive substances and solid desensitised explosives. Danger code (Kemler): 40 EMS Number: F-A,S-I Stowage Category A 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable. Transport/Additional information: ADR Limited quantities (LQ) 5 kg Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 g Maximum net quantity per outer packaging: 1000 g Transport category 3 Tunnel restriction code E UN "Model Regulation": UN 2717 CAMPHOR, 4.1, III |
REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Directive 2012/18/EU Named dangerous substances - ANNEX I Substance is not listed. Qualifying quantity (tonnes) for the application of lower-tier requirements 50 t Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 40 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out. |
OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |